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Polycarbonate and Chlorine: Chemical Resistance

Polycarbonate

Rating

Concentration20 °C50 °CRemark
10 % wetBC
97 %DD

Material comparison at 20 °C

Chlorine: Material comparison at 20 °CPolycarbonate: D (highlighted); FEP: A; Viton (FPM): A; PTFE: A; PVDF: A; SS 304: A.FEP: AViton (FPM): APTFE: APVDF: ASS 304: ASS 316: AAluminium: CEPDM: DHDPE: DLDPE: DNBR: DNylon (PA): DPolycarbonate: DPCPETG: DPMP: DAcetal (POM): DPP: DPolystyrene: DPolysulfone: DPVC Rigid: DPVC Flexible: DSAN: DECTFE/ETFE: –Silicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

The resistance of Polycarbonate to Chlorine is concentration-dependent. Across the 2 tested concentrations (10 % wet, 97 %), the 20 °C rating ranges from B at lower concentrations to D at higher ones. This means engineers must verify which concentration their process actually involves before relying on a single rating. However, at 50 °C the resistance rating drops, indicating that temperature must be factored into the design. For heated applications, additional testing under actual service conditions is strongly recommended.

Application context

Chlorine is commonly encountered in pulp and paper and chemical processing. Polycarbonate (Polycarbonate) is a thermoplastic typically used for tanks, piping, containers and liners. The compatibility between these two is therefore an important consideration for engineers and procurement teams selecting containment, transfer, or processing equipment.

Practical recommendation

Polycarbonate is not recommended for use with Chlorine. The D rating indicates that the material will suffer rapid and severe degradation, which may include cracking, dissolution, severe swelling, or complete structural failure. Using this combination risks equipment damage, leaks, and potential safety incidents. Consider using FEP, PTFE, PVDF instead, which are rated A for this chemical and offer reliable long-term performance.

Did you know?

The chemical resistance of Polycarbonate depends not only on the chemical concentration but also on exposure time, mechanical stress, and the presence of other chemicals in the mixture.

Materials rated A or B at 20 °C

Based on the row for 97 %, 20 °C.

Fluoropolymers
PTFE A, PVDF A, FEP A
Elastomers
Viton (FPM) A
Metals
SS 316 A, SS 304 A

About Polycarbonate

Polycarbonate is attacked by alkalis, amines, ketones, esters and many organic solvents, and it stress-cracks under load in contact with them.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.