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PTFE and Fluorine: Chemical Resistance

Polytetrafluoroethylene

Rating

Concentration20 °C50 °CRemark
concentration not statedAB

Material comparison at 20 °C

Fluorine: Material comparison at 20 °CPTFE: A (highlighted); ECTFE/ETFE: A; FEP: A; PVC Rigid: A; Viton (FPM): C; PMP: C.ECTFE/ETFE: AFEP: APTFE: APTFEPVC Rigid: AViton (FPM): CPMP: CAluminium: DEPDM: DHDPE: DLDPE: DNBR: DNylon (PA): DPolycarbonate: DPETG: DAcetal (POM): DPP: DPolystyrene: DPolysulfone: DPVDF: DSAN: DSS 304: DSS 316: DPVC Flexible: –Silicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

PTFE shows very good resistance (A) to Fluorine at 20 °C, meaning the material remains essentially unaffected by this chemical under standard laboratory test conditions. However, at 50 °C the resistance rating drops, indicating that temperature must be factored into the design. For heated applications, additional testing under actual service conditions is strongly recommended.

Application context

Fluorine is commonly encountered in surface cleaning and laboratory work. PTFE (Polytetrafluoroethylene) is a fluoropolymer typically used for seals, gaskets, valve seats and lined equipment. Because Fluorine is classified as corrosive, the choice of containment material is especially critical to prevent leaks, equipment damage, and safety hazards.

Practical recommendation

PTFE can be used with confidence for Fluorine containment and handling. The A rating indicates that the material shows no significant change in weight, dimensions, or mechanical properties after prolonged contact under test conditions. At elevated temperatures (50 °C), some reduction in resistance occurs, so periodic inspection is advisable for heated applications. Always verify performance under actual operating conditions before committing to a design.

Did you know?

When choosing between fluoropolymers for Fluorine service, engineers consider not just the resistance rating but also factors such as permeation rate, creep resistance, and weldability.

Materials rated A or B at 20 °C

Thermoplastics
PVC Rigid A
Fluoropolymers
FEP A, ECTFE/ETFE A

About PTFE

PTFE is resistant to almost every chemical in this list. The known exceptions are molten alkali metals, elemental fluorine and some fluorinating agents at elevated temperature.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.