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NBR and Hydrofluoric Acid: Chemical Resistance

Nitrile butadiene rubber

Rating

Concentration20 °C50 °CRemark
4 %B*–disputed, see below
50 %CD
70 %DD
100 %DD

* estimated rating, given in the source without a temperature

Corrected and disputed values

Source values use the scale 1 (very good) to 4 (not resistant); 1 = A, 4 = D.

Material comparison at 20 °C

Hydrofluoric Acid: Material comparison at 20 °CNBR: D (highlighted); FEP: A; LDPE: A; PP: A; PTFE: A; PVC Rigid: A.FEP: ALDPE: APP: APTFE: APVC Rigid: APVDF: AEPDM: CViton (FPM): CPVC Flexible: CAluminium: DNBR: DNBRNylon (PA): DPolycarbonate: DPETG: DAcetal (POM): DPolystyrene: DPolysulfone: DSS 304: DSS 316: DECTFE/ETFE: –HDPE: –PMP: –SAN: –Silicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

The resistance of NBR to Hydrofluoric Acid is concentration-dependent. Across the 4 tested concentrations (4 %, 50 %, 70 %, 100 %), the 20 °C rating ranges from B at lower concentrations to D at higher ones. This means engineers must verify which concentration their process actually involves before relying on a single rating. However, at 50 °C the resistance rating drops, indicating that temperature must be factored into the design. For heated applications, additional testing under actual service conditions is strongly recommended.

Application context

Hydrofluoric Acid is commonly encountered in laboratory work and chemical processing. NBR (Nitrile butadiene rubber) is an elastomer typically used for seals, O-rings, hoses and flexible connections. Because Hydrofluoric Acid is classified as corrosive, the choice of containment material is especially critical to prevent leaks, equipment damage, and safety hazards.

Practical recommendation

NBR is not recommended for use with Hydrofluoric Acid. The D rating indicates that the material will suffer rapid and severe degradation, which may include cracking, dissolution, severe swelling, or complete structural failure. Using this combination risks equipment damage, leaks, and potential safety incidents. Consider using LDPE, PP, PVC Rigid instead, which are rated A for this chemical and offer reliable long-term performance.

Did you know?

The ratings shown here apply to pure Hydrofluoric Acid in contact with the base elastomer. In real-world applications, additives, pigments, and fillers in the material can shift resistance in either direction.

Materials rated A or B at 20 °C

Based on the row for 70 %, 20 °C.

Thermoplastics
PP A, PVC Rigid A, LDPE A
Fluoropolymers
PTFE A, PVDF A, FEP A

About NBR

Nitrile rubber resists mineral oils and fuels. Ketones, esters, chlorinated solvents, strong oxidisers and ozone attack it.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.