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PTFE and Methyl Methacrylate (MMA): Chemical Resistance

Polytetrafluoroethylene

Rating

Concentration20 °C50 °CRemark
100 %AA

Material comparison at 20 °C

Methyl Methacrylate (MMA): Material comparison at 20 °CPTFE: A (highlighted); Aluminium: A; FEP: A; SS 304: A; SS 316: A; Nylon (PA): B.Aluminium: AFEP: APTFE: APTFESS 304: ASS 316: ANylon (PA): BAcetal (POM): BPP: BPVDF: CEPDM: DViton (FPM): DNBR: DPolycarbonate: DPETG: DPMP: DPolystyrene: DPVC Rigid: DPVC Flexible: DECTFE/ETFE: –HDPE: –LDPE: –Polysulfone: –SAN: –Silicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

PTFE shows very good resistance (A) to Methyl Methacrylate (MMA) at 100 % at 20 °C, meaning the material remains essentially unaffected by this chemical under standard laboratory test conditions. The rating remains stable between 20 °C and 50 °C, which means this material can also handle moderately elevated process temperatures without additional risk.

Application context

Methyl Methacrylate (MMA) is commonly encountered in pharmaceutical manufacturing and coatings and paints. PTFE (Polytetrafluoroethylene) is a fluoropolymer typically used for seals, gaskets, valve seats and lined equipment. Since Methyl Methacrylate (MMA) is flammable, material selection must also consider the risk of static charge buildup and the need for proper grounding in storage and transfer systems.

Practical recommendation

PTFE can be used with confidence for Methyl Methacrylate (MMA) containment and handling. The A rating indicates that the material shows no significant change in weight, dimensions, or mechanical properties after prolonged contact under test conditions. This holds true at both 20 °C and 50 °C, giving a good safety margin for typical process environments.

Did you know?

When choosing between fluoropolymers for Methyl Methacrylate (MMA) service, engineers consider not just the resistance rating but also factors such as permeation rate, creep resistance, and weldability.

Materials rated A or B at 20 °C

Based on the row for 100 %, 20 °C.

Thermoplastics
PP B, Nylon (PA) B, Acetal (POM) B
Fluoropolymers
FEP A
Metals
SS 316 A, SS 304 A, Aluminium A

About PTFE

PTFE is resistant to almost every chemical in this list. The known exceptions are molten alkali metals, elemental fluorine and some fluorinating agents at elevated temperature.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.