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Polystyrene and Acetic Anhydride: Chemical Resistance

Polystyrene

Rating

Concentration20 °C50 °CRemark
technical gradeDD

Material comparison at 20 °C

Acetic Anhydride: Material comparison at 20 °CPolystyrene: D (highlighted); FEP: A; PP: A; PTFE: A; SS 304: A; SS 316: A.FEP: APP: APTFE: ASS 304: ASS 316: AAluminium: BAcetal (POM): BEPDM: CLDPE: CNylon (PA): CViton (FPM): DHDPE: DNBR: DPolycarbonate: DPMP: DPolystyrene: DPSPolysulfone: DPVC Rigid: DPVC Flexible: DPVDF: DECTFE/ETFE: –PETG: –SAN: –Silicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

Polystyrene is not resistant (D) to Acetic Anhydride at technical grade and should not be used in direct contact. The chemical is expected to cause rapid degradation, which can include dissolution, cracking, severe swelling, or complete structural failure of the material.

Application context

Acetic Anhydride is commonly encountered in laboratory work and chemical processing. Polystyrene (Polystyrene) is a thermoplastic typically used for tanks, piping, containers and liners. Because Acetic Anhydride is classified as corrosive, the choice of containment material is especially critical to prevent leaks, equipment damage, and safety hazards.

Practical recommendation

Polystyrene is not recommended for use with Acetic Anhydride. The D rating indicates that the material will suffer rapid and severe degradation, which may include cracking, dissolution, severe swelling, or complete structural failure. Using this combination risks equipment damage, leaks, and potential safety incidents. Consider using PP, FEP, PTFE instead, which are rated A for this chemical and offer reliable long-term performance.

Did you know?

The chemical resistance of Polystyrene depends not only on the chemical concentration but also on exposure time, mechanical stress, and the presence of other chemicals in the mixture.

Materials rated A or B at 20 °C

Based on the row for technical grade, 20 °C.

Thermoplastics
PP A, Acetal (POM) B
Fluoropolymers
PTFE A, FEP A
Metals
SS 316 A, SS 304 A, Aluminium B

About Polystyrene

Polystyrene is attacked by most organic solvents, including ketones, esters, aromatic and chlorinated hydrocarbons. It is used for dilute aqueous solutions.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.