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Acetic Anhydride Chemical Resistance

Resistance ratings for 24 plastics, elastomers and metals at 20 °C and 50 °C.

At a glance

Based on the row for technical grade, 20 °C.

Rated A, very good resistance
PTFE, PP, SS 316, SS 304, FEP (5)
Rated B, good resistance
Aluminium, Acetal (POM) (2)
Rated C, limited resistance
EPDM, LDPE, Nylon (PA) (3)
Rated D, not resistant
HDPE, PVDF, PVC Rigid, Viton (FPM), NBR, Polycarbonate, PVC Flexible, Polystyrene, Polysulfone, PMP (10)
No data in the source
ECTFE/ETFE, Silicone, PETG, SAN
Rated lower at 50 °C than at 20 °C
PP (A → C)

Based on the row for technical grade, 20 °C.

Rating profile by material family

Acetic Anhydride: Rating profile by material familyThermoplastics: 1 A, 1 B, 2 C, 7 D, 2 no data. Fluoropolymers: 2 A, 1 D, 1 no data. Elastomers: 1 C, 2 D, 1 no data. Metals: 2 A, 1 B.Thermoplastics (13)Thermoplastics: 1 × A, very good resistance (PP)Thermoplastics: 1 × B, good resistance (Acetal (POM))Thermoplastics: 2 × C, limited resistance (LDPE, Nylon (PA))C 2Thermoplastics: 7 × D, not resistant (HDPE, PVC Rigid, PVC Flexible, PMP, Polystyrene, Polycarbonate, Polysulfone)D 7Thermoplastics: 2 × no data (SAN, PETG)– 2Fluoropolymers (4)Fluoropolymers: 2 × A, very good resistance (PTFE, FEP)A 2Fluoropolymers: 1 × D, not resistant (PVDF)D 1Fluoropolymers: 1 × no data (ECTFE/ETFE)– 1Elastomers (4)Elastomers: 1 × C, limited resistance (EPDM)C 1Elastomers: 2 × D, not resistant (Viton (FPM), NBR)D 2Elastomers: 1 × no data (Silicone)– 1Metals (3)Metals: 2 × A, very good resistance (SS 316, SS 304)A 2Metals: 1 × B, good resistance (Aluminium)B 1
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Number of materials in each family with each rating at 20 °C.

Effect of temperature, 20 °C to 50 °C

Acetic Anhydride: Effect of temperature, 20 °C to 50 °CPP A → C.ABCDPP: A at 20 °C, C at 50 °CPP
20 °C50 °C
Materials whose rating differs between 20 °C and 50 °C. Materials not shown keep their rating or have no 50 °C value.

Substance

CAS number
108-24-7
Formula
C4H6O3
Hazard symbols in the source
C (corrosive) (pre-GHS European symbols; check the current safety data sheet)
Flammable
yes
Concentrations listed
technical grade
Name in the source (German)
Essigsäureanhydrid

Resistance table: Acetic Anhydride, technical grade

Material20 °C50 °CRemark
Thermoplastics
HDPEDD
LDPECC
PPAC
PVC RigidDD
PVC FlexibleDD
PMPDD
PolystyreneDD
PolycarbonateDD
Acetal (POM)B*–
Nylon (PA)CC
PolysulfoneDD
Fluoropolymers
PTFEAA
FEPA–
PVDFDD
Elastomers
EPDMC–
Viton (FPM)DD
NBRDD
Metals
SS 316AA
SS 304AA
AluminiumB*–

* estimated rating, given in the source without a temperature

Not rated in the source, so not in the table: SAN, PETG, ECTFE/ETFE, Silicone

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

Frequently Asked Questions

Which materials resist Acetic Anhydride at high concentrations?

The materials with an A rating (resistant) for Acetic Anhydride at 20 °C are: PTFE, PP, SS 316, SS 304, FEP. These can generally be used in direct contact.

Which materials should be avoided with Acetic Anhydride?

Materials rated D (not resistant) for Acetic Anhydride are: HDPE, PVDF, PVC Rigid, Viton (FPM), NBR, Polycarbonate, PVC Flexible, Polystyrene. These should not be used in contact with Acetic Anhydride.

Does temperature affect chemical resistance to Acetic Anhydride?

Yes. 1 of 16 tested materials show a worse rating at 50 °C than at 20 °C for Acetic Anhydride. Materials affected include: PP.

Is PTFE safe for Acetic Anhydride?

PTFE is rated A for Acetic Anhydride at 20 °C. A rating of A means resistant, B means limited resistance, C means partly resistant, and D means not resistant.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.

Chemicals with a similar resistance profile

Same 20 °C rating on the share of materials shown.