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PVDF and Ammonium Hydroxide (Ammonia Solution): Chemical Resistance

Polyvinylidene fluoride

Rating

Concentration20 °C50 °CRemark
5 %B*–
30 %B*–
concentration not statedAC

* estimated rating, given in the source without a temperature

Material comparison at 20 °C

Ammonium Hydroxide (Ammonia Solution): Material comparison at 20 °CPVDF: B (highlighted); Aluminium: A; ECTFE/ETFE: A; EPDM: A; FEP: A; HDPE: A.Aluminium: AECTFE/ETFE: AEPDM: AFEP: AHDPE: ALDPE: APMP: AAcetal (POM): APP: APTFE: APVC Rigid: ASS 304: ASS 316: ANBR: BPETG: BPolystyrene: BPolysulfone: BPVDF: BPVDFViton (FPM): CNylon (PA): CPolycarbonate: DPVC Flexible: –SAN: –Silicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

The resistance of PVDF to Ammonium Hydroxide (Ammonia Solution) is concentration-dependent. Across the 3 tested concentrations (5 %, 30 %), the 20 °C rating ranges from A at lower concentrations to C at higher ones. This means engineers must verify which concentration their process actually involves before relying on a single rating. However, at 50 °C the resistance rating drops, indicating that temperature must be factored into the design. For heated applications, additional testing under actual service conditions is strongly recommended.

Application context

Ammonium Hydroxide (Ammonia Solution) is commonly encountered in cleaning and sanitation and textile processing. PVDF (Polyvinylidene fluoride) is a fluoropolymer typically used for seals, gaskets, valve seats and lined equipment. Because Ammonium Hydroxide (Ammonia Solution) is classified as corrosive, the choice of containment material is especially critical to prevent leaks, equipment damage, and safety hazards.

Practical recommendation

PVDF is suitable for use with Ammonium Hydroxide (Ammonia Solution) under normal conditions, but some minor effects on the material are expected over time. Periodic monitoring for swelling, softening, or weight change is recommended, especially for long-service components. Avoid prolonged exposure at elevated temperatures, as the resistance decreases further at 50 °C. For safety-critical or long-life applications, consider HDPE, LDPE, PMP instead, which are rated A for this chemical.

Did you know?

In industrial practice, PVDF components exposed to Ammonium Hydroxide (Ammonia Solution) are typically inspected for swelling, discoloration, or loss of mechanical strength as early indicators of chemical attack.

Materials rated A or B at 20 °C

Based on the row for 30 %, 20 °C.

Thermoplastics
HDPE A, PP A, PVC Rigid A, LDPE A, Acetal (POM) A, Polystyrene B, Polysulfone B, PETG B, PMP A
Fluoropolymers
PTFE A, FEP A, ECTFE/ETFE A
Elastomers
EPDM A, NBR B
Metals
SS 316 A, SS 304 A, Aluminium A

About PVDF

PVDF resists acids, halogens and hydrocarbons. Strong bases, amines, ketones and esters attack it. Service temperature is up to about 150 °C.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.