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SAN and Bromine: Chemical Resistance

Styrene-acrylonitrile

Rating

Concentration20 °C50 °CRemark
concentration not statedDD

Material comparison at 20 °C

Bromine: Material comparison at 20 °CSAN: D (highlighted); ECTFE/ETFE: A; FEP: A; PTFE: A; PVDF: A; PVC Rigid: B.ECTFE/ETFE: AFEP: APTFE: APVDF: APVC Rigid: BViton (FPM): CAluminium: DEPDM: DHDPE: DLDPE: DNBR: DNylon (PA): DPolycarbonate: DPETG: DPMP: DAcetal (POM): DPP: DPolystyrene: DPolysulfone: DPVC Flexible: DSAN: DSANSS 304: DSS 316: DSilicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

SAN is not resistant (D) to Bromine and should not be used in direct contact. The chemical is expected to cause rapid degradation, which can include dissolution, cracking, severe swelling, or complete structural failure of the material.

Application context

Bromine is commonly encountered in chemical processing and pulp and paper. SAN (Styrene-acrylonitrile) is a thermoplastic typically used for tanks, piping, containers and liners. Because Bromine is classified as corrosive, the choice of containment material is especially critical to prevent leaks, equipment damage, and safety hazards.

Practical recommendation

SAN is not recommended for use with Bromine. The D rating indicates that the material will suffer rapid and severe degradation, which may include cracking, dissolution, severe swelling, or complete structural failure. Using this combination risks equipment damage, leaks, and potential safety incidents. Consider using ECTFE/ETFE, FEP, PTFE instead, which are rated A for this chemical and offer reliable long-term performance.

Did you know?

In industrial practice, SAN components exposed to Bromine are typically inspected for swelling, discoloration, or loss of mechanical strength as early indicators of chemical attack.

Materials rated A or B at 20 °C

Thermoplastics
PVC Rigid B
Fluoropolymers
PTFE A, PVDF A, FEP A, ECTFE/ETFE A

About SAN

Styrene-acrylonitrile resists oils and dilute acids better than polystyrene, but ketones, esters and aromatic and chlorinated solvents still attack it.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.