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Bromine Chemical Resistance

Resistance ratings for 24 plastics, elastomers and metals at 20 °C and 50 °C.

At a glance

Ratings at 20 °C.

Rated A, very good resistance
PTFE, PVDF, FEP, ECTFE/ETFE (4)
Rated B, good resistance
PVC Rigid (1)
Rated C, limited resistance
Viton (FPM) (1)
Rated D, not resistant
HDPE, PP, EPDM, NBR, SS 316, SS 304, Aluminium, LDPE, Nylon (PA), Acetal (POM), Polycarbonate, PVC Flexible, Polystyrene, Polysulfone, PETG, PMP, SAN (17)
No data in the source
Silicone
Rated lower at 50 °C than at 20 °C
PTFE (A → C), PVC Rigid (B → D), ECTFE/ETFE (A → B)

Rating profile by material family

Bromine: Rating profile by material familyThermoplastics: 1 B, 12 D. Fluoropolymers: 4 A. Elastomers: 1 C, 2 D, 1 no data. Metals: 3 D.Thermoplastics (13)Thermoplastics: 1 × B, good resistance (PVC Rigid)Thermoplastics: 12 × D, not resistant (HDPE, LDPE, PP, PVC Flexible, PMP, Polystyrene, SAN, Polycarbonate, PETG, Acetal (POM), Nylon (PA), Polysulfone)D 12Fluoropolymers (4)Fluoropolymers: 4 × A, very good resistance (PTFE, FEP, PVDF, ECTFE/ETFE)A 4Elastomers (4)Elastomers: 1 × C, limited resistance (Viton (FPM))C 1Elastomers: 2 × D, not resistant (EPDM, NBR)D 2Elastomers: 1 × no data (Silicone)– 1Metals (3)Metals: 3 × D, not resistant (SS 316, SS 304, Aluminium)D 3
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Number of materials in each family with each rating at 20 °C.

Effect of temperature, 20 °C to 50 °C

Bromine: Effect of temperature, 20 °C to 50 °CPVC Rigid B → D; PTFE A → C; ECTFE/ETFE A → B.ABCDPVC Rigid: B at 20 °C, D at 50 °CPVC RigidPTFE: A at 20 °C, C at 50 °CPTFEECTFE/ETFE: A at 20 °C, B at 50 °CECTFE/ETFE
20 °C50 °C
Materials whose rating differs between 20 °C and 50 °C. Materials not shown keep their rating or have no 50 °C value.

Substance

CAS number
7726-95-6
Formula
Br2
Hazard symbols in the source
T+ (very toxic), C (corrosive) (pre-GHS European symbols; check the current safety data sheet)
Name in the source (German)
Brom

Resistance table

Material20 °C50 °CRemark
Thermoplastics
HDPEDD
LDPEDD
PPDD
PVC RigidBD
PVC FlexibleDD
PMPDD
PolystyreneDD
SANDD
PolycarbonateDD
PETGDD
Acetal (POM)DD
Nylon (PA)DD
PolysulfoneDD
Fluoropolymers
PTFEAC
FEPAA
PVDFAA
ECTFE/ETFEAB
Elastomers
EPDMDD
Viton (FPM)B–C*–
NBRDD
Metals
SS 316DD
SS 304DD
AluminiumD*–

* estimated rating, given in the source without a temperature

Not rated in the source, so not in the table: Silicone

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

Frequently Asked Questions

Which materials resist Bromine at high concentrations?

The materials with an A rating (resistant) for Bromine at 20 °C are: PTFE, PVDF, FEP, ECTFE/ETFE. These can generally be used in direct contact.

Which materials should be avoided with Bromine?

Materials rated D (not resistant) for Bromine are: HDPE, PP, EPDM, NBR, SS 316, SS 304, Aluminium, LDPE. These should not be used in contact with Bromine.

Does temperature affect chemical resistance to Bromine?

Yes. 3 of 21 tested materials show a worse rating at 50 °C than at 20 °C for Bromine. Materials affected include: PTFE, PVC Rigid, ECTFE/ETFE.

Is PTFE safe for Bromine?

PTFE is rated A for Bromine at 20 °C (C at 50 °C). A rating of A means resistant, B means limited resistance, C means partly resistant, and D means not resistant.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.

Chemicals with a similar resistance profile

Same 20 °C rating on the share of materials shown.