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PVDF and Chlorine Dioxide: Chemical Resistance

Polyvinylidene fluoride

Rating

Concentration20 °C50 °CRemark
concentration not statedB*–

* estimated rating, given in the source without a temperature

Material comparison at 20 °C

Chlorine Dioxide: Material comparison at 20 °CPVDF: B (highlighted); Viton (FPM): A; PTFE: A; Aluminium: C; Polycarbonate: C; Acetal (POM): C.Viton (FPM): APTFE: APVDF: BPVDFAluminium: CPolycarbonate: CAcetal (POM): CPP: CSS 304: CSS 316: CEPDM: DNBR: DNylon (PA): DECTFE/ETFE: –FEP: –HDPE: –LDPE: –PETG: –PMP: –Polystyrene: –Polysulfone: –PVC Rigid: –PVC Flexible: –SAN: –Silicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

PVDF shows good but limited resistance (B) to Chlorine Dioxide at 20 °C. The material can be used in contact with this chemical, but minor effects such as slight swelling or a small reduction in mechanical properties may occur over extended exposure periods. Regular inspection of components in service is advisable. The rating remains stable between 20 °C and 50 °C, which means this material can also handle moderately elevated process temperatures without additional risk.

Application context

Chlorine Dioxide is commonly encountered in water disinfection and pulp and paper. PVDF (Polyvinylidene fluoride) is a fluoropolymer typically used for seals, gaskets, valve seats and lined equipment. The compatibility between these two is therefore an important consideration for engineers and procurement teams selecting containment, transfer, or processing equipment.

Practical recommendation

PVDF is suitable for use with Chlorine Dioxide under normal conditions, but some minor effects on the material are expected over time. Periodic monitoring for swelling, softening, or weight change is recommended, especially for long-service components. For safety-critical or long-life applications, consider PTFE, Viton (FPM) instead, which are rated A for this chemical.

Did you know?

Polyvinylidene fluoride was first developed in the 1960s and remains one of the most widely used fluoropolymers in chemical handling equipment.

Materials rated A or B at 20 °C

Fluoropolymers
PTFE A
Elastomers
Viton (FPM) A

About PVDF

PVDF resists acids, halogens and hydrocarbons. Strong bases, amines, ketones and esters attack it. Service temperature is up to about 150 °C.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.