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Chlorine Dioxide Chemical Resistance

Resistance ratings for 24 plastics, elastomers and metals at 20 °C and 50 °C.

At a glance

Ratings at 20 °C.

Rated A, very good resistance
PTFE, Viton (FPM) (2)
Rated B, good resistance
PVDF (1)
Rated C, limited resistance
PP, SS 316, SS 304, Aluminium, Acetal (POM), Polycarbonate (6)
Rated D, not resistant
EPDM, NBR, Nylon (PA) (3)
No data in the source
HDPE, PVC Rigid, LDPE, FEP, ECTFE/ETFE, Silicone, PVC Flexible, Polystyrene, Polysulfone, PETG, PMP, SAN
Rated lower at 50 °C than at 20 °C
SS 316 (C → D), SS 304 (C → D), Aluminium (C → D)

Rating profile by material family

Chlorine Dioxide: Rating profile by material familyThermoplastics: 3 C, 1 D, 9 no data. Fluoropolymers: 1 A, 1 B, 2 no data. Elastomers: 1 A, 2 D, 1 no data. Metals: 3 C.Thermoplastics (13)Thermoplastics: 3 × C, limited resistance (PP, Polycarbonate, Acetal (POM))C 3Thermoplastics: 1 × D, not resistant (Nylon (PA))Thermoplastics: 9 × no data (HDPE, LDPE, PVC Rigid, PVC Flexible, PMP, Polystyrene, SAN, PETG, Polysulfone)– 9Fluoropolymers (4)Fluoropolymers: 1 × A, very good resistance (PTFE)A 1Fluoropolymers: 1 × B, good resistance (PVDF)B 1Fluoropolymers: 2 × no data (FEP, ECTFE/ETFE)– 2Elastomers (4)Elastomers: 1 × A, very good resistance (Viton (FPM))A 1Elastomers: 2 × D, not resistant (EPDM, NBR)D 2Elastomers: 1 × no data (Silicone)– 1Metals (3)Metals: 3 × C, limited resistance (SS 316, SS 304, Aluminium)C 3
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Number of materials in each family with each rating at 20 °C.

Effect of temperature, 20 °C to 50 °C

Chlorine Dioxide: Effect of temperature, 20 °C to 50 °CSS 316 C → D; SS 304 C → D; Aluminium C → D.ABCDSS 316: C at 20 °C, D at 50 °CSS 316SS 304: C at 20 °C, D at 50 °CSS 304Aluminium: C at 20 °C, D at 50 °CAluminium
20 °C50 °C
Materials whose rating differs between 20 °C and 50 °C. Materials not shown keep their rating or have no 50 °C value.

Substance

CAS number
10049-04-4
Formula
ClO2
Hazard symbols in the source
E (explosive), T (toxic) (pre-GHS European symbols; check the current safety data sheet)
Name in the source (German)
Chlordioxid

Resistance table

Material20 °C50 °CRemark
Thermoplastics
PPC*–
PolycarbonateC*–
Acetal (POM)C*–
Nylon (PA)DD
Fluoropolymers
PTFEA–
PVDFB*–
Elastomers
EPDMDD
Viton (FPM)A–
NBRDD
Metals
SS 316CD
SS 304CD
AluminiumCD

* estimated rating, given in the source without a temperature

Not rated in the source, so not in the table: HDPE, LDPE, PVC Rigid, PVC Flexible, PMP, Polystyrene, SAN, PETG, Polysulfone, FEP, ECTFE/ETFE, Silicone

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

Frequently Asked Questions

Which materials resist Chlorine Dioxide at high concentrations?

The materials with an A rating (resistant) for Chlorine Dioxide at 20 °C are: PTFE, Viton (FPM). These can generally be used in direct contact.

Which materials should be avoided with Chlorine Dioxide?

Materials rated D (not resistant) for Chlorine Dioxide are: EPDM, NBR, Nylon (PA). These should not be used in contact with Chlorine Dioxide.

Does temperature affect chemical resistance to Chlorine Dioxide?

Yes. 3 of 6 tested materials show a worse rating at 50 °C than at 20 °C for Chlorine Dioxide. Materials affected include: SS 316, SS 304, Aluminium.

Is PTFE safe for Chlorine Dioxide?

PTFE is rated A for Chlorine Dioxide at 20 °C. A rating of A means resistant, B means limited resistance, C means partly resistant, and D means not resistant.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.

Chemicals with a similar resistance profile

Same 20 °C rating on the share of materials shown.