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PTFE and Chlorine Gas: Chemical Resistance

Polytetrafluoroethylene

Rating

Concentration20 °C50 °CRemark
concentration not statedA–

Material comparison at 20 °C

Chlorine Gas: Material comparison at 20 °CPTFE: A (highlighted); FEP: A; Viton (FPM): A; PVDF: A; SS 304: A; SS 316: A.FEP: AViton (FPM): APTFE: APTFEPVDF: ASS 304: ASS 316: AAluminium: CEPDM: DHDPE: DLDPE: DNBR: DNylon (PA): DPolycarbonate: DPETG: DPMP: DAcetal (POM): DPP: DPolystyrene: DPolysulfone: DPVC Rigid: DPVC Flexible: DSAN: DECTFE/ETFE: –Silicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

PTFE shows very good resistance (A) to Chlorine Gas at 20 °C, meaning the material remains essentially unaffected by this chemical under standard laboratory test conditions. The rating remains stable between 20 °C and 50 °C, which means this material can also handle moderately elevated process temperatures without additional risk.

Application context

Chlorine Gas is commonly encountered in water disinfection and chemical processing. PTFE (Polytetrafluoroethylene) is a fluoropolymer typically used for seals, gaskets, valve seats and lined equipment. The compatibility between these two is therefore an important consideration for engineers and procurement teams selecting containment, transfer, or processing equipment.

Practical recommendation

PTFE can be used with confidence for Chlorine Gas containment and handling. The A rating indicates that the material shows no significant change in weight, dimensions, or mechanical properties after prolonged contact under test conditions. This holds true at both 20 °C and 50 °C, giving a good safety margin for typical process environments.

Did you know?

In industrial practice, PTFE components exposed to Chlorine Gas are typically inspected for swelling, discoloration, or loss of mechanical strength as early indicators of chemical attack.

Materials rated A or B at 20 °C

Fluoropolymers
PVDF A, FEP A
Elastomers
Viton (FPM) A
Metals
SS 316 A, SS 304 A

About PTFE

PTFE is resistant to almost every chemical in this list. The known exceptions are molten alkali metals, elemental fluorine and some fluorinating agents at elevated temperature.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.