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Chlorine Gas Chemical Resistance

Resistance ratings for 24 plastics, elastomers and metals at 20 °C and 50 °C.

At a glance

Ratings at 20 °C.

Rated A, very good resistance
PTFE, PVDF, Viton (FPM), SS 316, SS 304, FEP (6)
Rated B, good resistance
none (0)
Rated C, limited resistance
Aluminium (1)
Rated D, not resistant
HDPE, PP, PVC Rigid, EPDM, NBR, LDPE, Nylon (PA), Acetal (POM), Polycarbonate, PVC Flexible, Polystyrene, Polysulfone, PETG, PMP, SAN (15)
No data in the source
ECTFE/ETFE, Silicone

Rating profile by material family

Chlorine Gas: Rating profile by material familyThermoplastics: 13 D. Fluoropolymers: 3 A, 1 no data. Elastomers: 1 A, 2 D, 1 no data. Metals: 2 A, 1 C.Thermoplastics (13)Thermoplastics: 13 × D, not resistant (HDPE, LDPE, PP, PVC Rigid, PVC Flexible, PMP, Polystyrene, SAN, Polycarbonate, PETG, Acetal (POM), Nylon (PA), Polysulfone)D 13Fluoropolymers (4)Fluoropolymers: 3 × A, very good resistance (PTFE, FEP, PVDF)A 3Fluoropolymers: 1 × no data (ECTFE/ETFE)– 1Elastomers (4)Elastomers: 1 × A, very good resistance (Viton (FPM))A 1Elastomers: 2 × D, not resistant (EPDM, NBR)D 2Elastomers: 1 × no data (Silicone)– 1Metals (3)Metals: 2 × A, very good resistance (SS 316, SS 304)A 2Metals: 1 × C, limited resistance (Aluminium)C 1
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Number of materials in each family with each rating at 20 °C.

Effect of temperature, 20 °C to 50 °C

No material with a rating at both temperatures changes grade between 20 °C and 50 °C.

Substance

CAS number
7782-50-5
Formula
Cl2
Hazard symbols in the source
T (toxic) (pre-GHS European symbols; check the current safety data sheet)
Name in the source (German)
Chlorgas

Resistance table

Material20 °C50 °CRemark
Thermoplastics
HDPEDD
LDPEDD
PPDD
PVC RigidDD
PVC FlexibleDD
PMPDD
PolystyreneDD
SANDD
PolycarbonateDD
PETGDD
Acetal (POM)DD
Nylon (PA)DD
PolysulfoneDD
Fluoropolymers
PTFEA–
FEPAA
PVDFAA
Elastomers
EPDMDD
Viton (FPM)AA
NBRDD
Metals
SS 316A–
SS 304A–
AluminiumC*–

* estimated rating, given in the source without a temperature

Not rated in the source, so not in the table: ECTFE/ETFE, Silicone

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

Frequently Asked Questions

Which materials resist Chlorine Gas at high concentrations?

The materials with an A rating (resistant) for Chlorine Gas at 20 °C are: PTFE, PVDF, Viton (FPM), SS 316, SS 304, FEP. These can generally be used in direct contact.

Which materials should be avoided with Chlorine Gas?

Materials rated D (not resistant) for Chlorine Gas are: HDPE, PP, PVC Rigid, EPDM, NBR, LDPE, Nylon (PA), Acetal (POM). These should not be used in contact with Chlorine Gas.

Does temperature affect chemical resistance to Chlorine Gas?

For Chlorine Gas, all tested materials maintain the same rating at both 20 °C and 50 °C.

Is PTFE safe for Chlorine Gas?

PTFE is rated A for Chlorine Gas at 20 °C. A rating of A means resistant, B means limited resistance, C means partly resistant, and D means not resistant.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.

Chemicals with a similar resistance profile

Same 20 °C rating on the share of materials shown.