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PVC Rigid and Chlorine Water: Chemical Resistance

Rigid (unplasticised) polyvinyl chloride

Rating

Concentration20 °C50 °CRemark
concentration not statedCC

Material comparison at 20 °C

Chlorine Water: Material comparison at 20 °CPVC Rigid: C (highlighted); ECTFE/ETFE: A; FEP: A; Viton (FPM): A; PTFE: A; PVDF: A.ECTFE/ETFE: AFEP: AViton (FPM): APTFE: APVDF: ASS 304: BSS 316: BEPDM: CHDPE: CPP: CPVC Rigid: CPVC-UPVC Flexible: CSAN: CAluminium: DNBR: DNylon (PA): DPolycarbonate: DPETG: DPMP: DAcetal (POM): DPolystyrene: DLDPE: –Polysulfone: –Silicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

PVC Rigid has limited resistance (C) to Chlorine Water at 20 °C. This indicates that the chemical has a noticeable effect on the material, which may include visible swelling, softening, or a measurable loss of tensile strength. Use is generally limited to short-term or intermittent contact where full structural integrity is not required. The rating remains stable between 20 °C and 50 °C, which means this material can also handle moderately elevated process temperatures without additional risk.

Application context

Chlorine Water is commonly encountered in bleaching and pulp and paper. PVC Rigid (Rigid (unplasticised) polyvinyl chloride) is a thermoplastic typically used for tanks, piping, containers and liners. The compatibility between these two is therefore an important consideration for engineers and procurement teams selecting containment, transfer, or processing equipment.

Practical recommendation

PVC Rigid has limited resistance to Chlorine Water and should only be used for short-term or intermittent contact at ambient temperature. The C rating means the material undergoes noticeable changes — swelling, loss of strength, or surface degradation — that make it unsuitable for permanent installations. For prolonged or continuous exposure, ECTFE/ETFE, FEP, PTFE offer significantly better resistance and are rated A.

Did you know?

In industrial practice, PVC Rigid components exposed to Chlorine Water are typically inspected for swelling, discoloration, or loss of mechanical strength as early indicators of chemical attack.

Materials rated A or B at 20 °C

Fluoropolymers
PTFE A, PVDF A, FEP A, ECTFE/ETFE A
Elastomers
Viton (FPM) A
Metals
SS 316 B, SS 304 B

About PVC Rigid

Rigid PVC resists acids, alkalis and salt solutions well. Ketones, esters, aromatic and chlorinated solvents dissolve or swell it. Service temperature is limited to about 60 °C.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.