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PVC Rigid and Formic Acid: Chemical Resistance

Rigid (unplasticised) polyvinyl chloride

Rating

Concentration20 °C50 °CRemark
3 %BC
50 %BC
98-100 %CD

Material comparison at 20 °C

Formic Acid: Material comparison at 20 °CPVC Rigid: C (highlighted); Aluminium: A; ECTFE/ETFE: A; FEP: A; HDPE: A; LDPE: A.Aluminium: AECTFE/ETFE: AFEP: AHDPE: ALDPE: APMP: APP: APTFE: APVC Flexible: APVDF: ASS 304: ASS 316: AEPDM: CPolycarbonate: CPolystyrene: CPolysulfone: CPVC Rigid: CPVC-USAN: CViton (FPM): DNBR: DNylon (PA): DAcetal (POM): DPETG: –Silicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

The resistance of PVC Rigid to Formic Acid is concentration-dependent. Across the 3 tested concentrations (3 %, 50 %, 98-100 %), the 20 °C rating ranges from B at lower concentrations to D at higher ones. This means engineers must verify which concentration their process actually involves before relying on a single rating. However, at 50 °C the resistance rating drops, indicating that temperature must be factored into the design. For heated applications, additional testing under actual service conditions is strongly recommended.

Application context

Formic Acid is commonly encountered in metal finishing and water treatment. PVC Rigid (Rigid (unplasticised) polyvinyl chloride) is a thermoplastic typically used for tanks, piping, containers and liners. Because Formic Acid is classified as corrosive, the choice of containment material is especially critical to prevent leaks, equipment damage, and safety hazards.

Practical recommendation

PVC Rigid has limited resistance to Formic Acid and should only be used for short-term or intermittent contact at ambient temperature. The C rating means the material undergoes noticeable changes — swelling, loss of strength, or surface degradation — that make it unsuitable for permanent installations. For prolonged or continuous exposure, HDPE, LDPE, PMP offer significantly better resistance and are rated A.

Did you know?

Temperature is often the deciding factor when selecting materials for Formic Acid: even materials rated A at 20 °C may lose performance at elevated temperatures.

Materials rated A or B at 20 °C

Based on the row for 98-100 %, 20 °C.

Thermoplastics
HDPE A, PP A, LDPE A, PVC Flexible A, PMP A
Fluoropolymers
PTFE A, PVDF A, FEP A, ECTFE/ETFE A
Metals
SS 316 A, SS 304 A, Aluminium A

About PVC Rigid

Rigid PVC resists acids, alkalis and salt solutions well. Ketones, esters, aromatic and chlorinated solvents dissolve or swell it. Service temperature is limited to about 60 °C.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.