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Polystyrene and Hydrogen Peroxide: Chemical Resistance

Polystyrene

Rating

Concentration20 °C50 °CRemark
3 %AB
30 %AB
90 %AB
100 %DD

Material comparison at 20 °C

Hydrogen Peroxide: Material comparison at 20 °CPolystyrene: A (highlighted); ECTFE/ETFE: A; FEP: A; Viton (FPM): A; HDPE: A; LDPE: A.ECTFE/ETFE: AFEP: AViton (FPM): AHDPE: ALDPE: APolycarbonate: APMP: APP: APolystyrene: APSPolysulfone: APTFE: APVC Rigid: APVDF: ASS 304: ASS 316: AAluminium: CEPDM: CNBR: DNylon (PA): DAcetal (POM): DPETG: –PVC Flexible: –SAN: –Silicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

The resistance of Polystyrene to Hydrogen Peroxide is concentration-dependent. Across the 4 tested concentrations (3 %, 30 %, 90 %, 100 %), the 20 °C rating ranges from A at lower concentrations to D at higher ones. This means engineers must verify which concentration their process actually involves before relying on a single rating. However, at 50 °C the resistance rating drops, indicating that temperature must be factored into the design. For heated applications, additional testing under actual service conditions is strongly recommended.

Application context

Hydrogen Peroxide is commonly encountered in bleaching and pulp and paper. Polystyrene (Polystyrene) is a thermoplastic typically used for tanks, piping, containers and liners. Because Hydrogen Peroxide is classified as corrosive, the choice of containment material is especially critical to prevent leaks, equipment damage, and safety hazards.

Practical recommendation

Polystyrene can be used with confidence for Hydrogen Peroxide containment and handling. The A rating indicates that the material shows no significant change in weight, dimensions, or mechanical properties after prolonged contact under test conditions. At elevated temperatures (50 °C), some reduction in resistance occurs, so periodic inspection is advisable for heated applications. Always verify performance under actual operating conditions before committing to a design.

Did you know?

Polystyrene was first developed in the 1930s and remains one of the most widely used thermoplastics in chemical handling equipment.

Materials rated A or B at 20 °C

Based on the row for 90 %, 20 °C.

Thermoplastics
HDPE A, PP A, PVC Rigid A, LDPE A, Polycarbonate A, Polysulfone A, PMP A
Fluoropolymers
PTFE A, PVDF A, FEP A, ECTFE/ETFE A
Elastomers
Viton (FPM) A
Metals
SS 316 A, SS 304 A

About Polystyrene

Polystyrene is attacked by most organic solvents, including ketones, esters, aromatic and chlorinated hydrocarbons. It is used for dilute aqueous solutions.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.