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HDPE and Perchloric Acid: Chemical Resistance

High-density polyethylene

Rating

Concentration20 °C50 °CRemark
20 %––
70 %BD

Material comparison at 20 °C

Perchloric Acid: Material comparison at 20 °CHDPE: B (highlighted); ECTFE/ETFE: A; FEP: A; Viton (FPM): A; PTFE: A; PVDF: A.ECTFE/ETFE: AFEP: AViton (FPM): APTFE: APVDF: AHDPE: BHDPEPMP: BPolystyrene: BEPDM: CLDPE: CPVC Rigid: CAluminium: DNBR: DNylon (PA): DPolycarbonate: DPETG: DAcetal (POM): DPP: DPolysulfone: DPVC Flexible: DSAN: –Silicone: –SS 304: –SS 316: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

HDPE shows good but limited resistance (B) to Perchloric Acid at 70 % at 20 °C. The material can be used in contact with this chemical, but minor effects such as slight swelling or a small reduction in mechanical properties may occur over extended exposure periods. Regular inspection of components in service is advisable. However, at 50 °C the resistance rating drops, indicating that temperature must be factored into the design. For heated applications, additional testing under actual service conditions is strongly recommended.

Application context

Perchloric Acid is commonly encountered in laboratory work and surface cleaning. HDPE (High-density polyethylene) is a thermoplastic typically used for tanks, piping, containers and liners. Because Perchloric Acid is classified as corrosive, the choice of containment material is especially critical to prevent leaks, equipment damage, and safety hazards.

Practical recommendation

HDPE is suitable for use with Perchloric Acid under normal conditions, but some minor effects on the material are expected over time. Periodic monitoring for swelling, softening, or weight change is recommended, especially for long-service components. Avoid prolonged exposure at elevated temperatures, as the resistance decreases further at 50 °C. For safety-critical or long-life applications, consider ECTFE/ETFE, FEP, PTFE instead, which are rated A for this chemical.

Did you know?

High-density polyethylene was first developed in the 1950s and remains one of the most widely used thermoplastics in chemical handling equipment.

Materials rated A or B at 20 °C

Based on the row for 70 %, 20 °C.

Thermoplastics
Polystyrene B, PMP B
Fluoropolymers
PTFE A, PVDF A, FEP A, ECTFE/ETFE A
Elastomers
Viton (FPM) A

About HDPE

High-density polyethylene resists most aqueous acids, alkalis and salt solutions. Strong oxidising acids, chlorinated solvents and aromatic hydrocarbons attack or swell it. Continuous service is usually limited to about 80 °C.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.