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SS 316 and Trichloroacetic Acid (TCA): Chemical Resistance

Stainless steel 1.4401 (AISI 316)

Rating

Concentration20 °C50 °CRemark
concentration not statedB–

Material comparison at 20 °C

Trichloroacetic Acid (TCA): Material comparison at 20 °CSS 316: B (highlighted); Aluminium: A; FEP: A; HDPE: A; PP: A; PTFE: A.Aluminium: AFEP: AHDPE: APP: APTFE: APVDF: ASS 316: B316EPDM: CLDPE: CSS 304: CViton (FPM): DNBR: DNylon (PA): DPolycarbonate: DPETG: DAcetal (POM): DPolystyrene: DPVC Rigid: DPVC Flexible: DECTFE/ETFE: –PMP: –Polysulfone: –SAN: –Silicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

SS 316 shows good but limited resistance (B) to Trichloroacetic Acid (TCA) at 20 °C. The material can be used in contact with this chemical, but minor effects such as slight swelling or a small reduction in mechanical properties may occur over extended exposure periods. Regular inspection of components in service is advisable. The rating remains stable between 20 °C and 50 °C, which means this material can also handle moderately elevated process temperatures without additional risk.

Application context

Trichloroacetic Acid (TCA) is commonly encountered in laboratory work and water treatment. SS 316 (Stainless steel 1.4401 (AISI 316)) is a metal typically used for vessels, heat exchangers, fittings and structural components. Because Trichloroacetic Acid (TCA) is classified as corrosive, the choice of containment material is especially critical to prevent leaks, equipment damage, and safety hazards.

Practical recommendation

SS 316 is suitable for use with Trichloroacetic Acid (TCA) under normal conditions, but some minor effects on the material are expected over time. Periodic monitoring for swelling, softening, or weight change is recommended, especially for long-service components. For safety-critical or long-life applications, consider HDPE, PP, FEP instead, which are rated A for this chemical.

Did you know?

When choosing between metals for Trichloroacetic Acid (TCA) service, engineers consider not just the resistance rating but also factors such as permeation rate, creep resistance, and weldability.

Materials rated A or B at 20 °C

Thermoplastics
HDPE A, PP A
Fluoropolymers
PTFE A, PVDF A, FEP A
Metals
Aluminium A

About SS 316

Stainless steel 316 (1.4401) contains molybdenum, which improves resistance to chlorides over 304. Hydrochloric acid and other halide acids still cause pitting.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.