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HDPE and Sulfuric Acid: Chemical Resistance

High-density polyethylene

Rating

Concentration20 °C50 °CRemark
1-6 %AA
20 %AA
40 %AA
60 %AC
80 %AA
95 %CD
fumingDD

Material comparison at 20 °C

Sulfuric Acid: Material comparison at 20 °CHDPE: C (highlighted); ECTFE/ETFE: A; FEP: A; Viton (FPM): A; PTFE: A; PVDF: A.ECTFE/ETFE: AFEP: AViton (FPM): APTFE: APVDF: ASS 304: ASS 316: APMP: BPVC Rigid: BHDPE: CHDPELDPE: CPP: CAluminium: DEPDM: DNBR: DNylon (PA): DPolycarbonate: DPETG: DAcetal (POM): DPolystyrene: DPolysulfone: DSAN: DPVC Flexible: –Silicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

The resistance of HDPE to Sulfuric Acid is concentration-dependent. Across the 7 tested concentrations (1-6 %, 20 %, 40 %, 60 %, 80 %, 95 %, fuming), the 20 °C rating ranges from A at lower concentrations to D at higher ones. This means engineers must verify which concentration their process actually involves before relying on a single rating. However, at 50 °C the resistance rating drops, indicating that temperature must be factored into the design. For heated applications, additional testing under actual service conditions is strongly recommended.

Application context

Sulfuric Acid is commonly encountered in water treatment and surface cleaning. HDPE (High-density polyethylene) is a thermoplastic typically used for tanks, piping, containers and liners. Because Sulfuric Acid is classified as corrosive, the choice of containment material is especially critical to prevent leaks, equipment damage, and safety hazards.

Practical recommendation

HDPE has limited resistance to Sulfuric Acid and should only be used for short-term or intermittent contact at ambient temperature. The C rating means the material undergoes noticeable changes — swelling, loss of strength, or surface degradation — that make it unsuitable for permanent installations. For prolonged or continuous exposure, ECTFE/ETFE, FEP, PTFE offer significantly better resistance and are rated A.

Did you know?

The ratings shown here apply to pure Sulfuric Acid in contact with the base thermoplastic. In real-world applications, additives, pigments, and fillers in the material can shift resistance in either direction.

Materials rated A or B at 20 °C

Based on the row for 95 %, 20 °C.

Thermoplastics
PVC Rigid B, PMP B
Fluoropolymers
PTFE A, PVDF A, FEP A, ECTFE/ETFE A
Elastomers
Viton (FPM) A
Metals
SS 316 A, SS 304 A

About HDPE

High-density polyethylene resists most aqueous acids, alkalis and salt solutions. Strong oxidising acids, chlorinated solvents and aromatic hydrocarbons attack or swell it. Continuous service is usually limited to about 80 °C.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.