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SAN and Acetaldehyde: Chemical Resistance

Styrene-acrylonitrile

Rating

Concentration20 °C50 °CRemark
40 %DD
technical gradeDD

Material comparison at 20 °C

Acetaldehyde: Material comparison at 20 °CSAN: D (highlighted); Aluminium: A; FEP: A; PTFE: A; SS 304: A; SS 316: A.Aluminium: AFEP: APTFE: ASS 304: ASS 316: AECTFE/ETFE: BLDPE: BNylon (PA): BPMP: BAcetal (POM): BEPDM: CHDPE: CPP: CViton (FPM): DNBR: DPolycarbonate: DPETG: DPolystyrene: DPolysulfone: DPVC Rigid: DPVDF: DSAN: DSANPVC Flexible: –Silicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

SAN maintains a consistent rating of D across all 2 tested concentrations (40 %, technical grade) of Acetaldehyde at 20 °C. The fact that the rating does not change with concentration within the tested range simplifies material selection, though the boundary conditions beyond this range remain untested. The rating remains stable between 20 °C and 50 °C, which means this material can also handle moderately elevated process temperatures without additional risk.

Application context

Acetaldehyde is commonly encountered in coatings and paints and pharmaceutical manufacturing. SAN (Styrene-acrylonitrile) is a thermoplastic typically used for tanks, piping, containers and liners. Since Acetaldehyde is flammable, material selection must also consider the risk of static charge buildup and the need for proper grounding in storage and transfer systems.

Practical recommendation

SAN is not recommended for use with Acetaldehyde. The D rating indicates that the material will suffer rapid and severe degradation, which may include cracking, dissolution, severe swelling, or complete structural failure. Using this combination risks equipment damage, leaks, and potential safety incidents. Consider using FEP, PTFE, Aluminium instead, which are rated A for this chemical and offer reliable long-term performance.

Did you know?

Styrene-acrylonitrile was first developed in the 1940s and remains one of the most widely used thermoplastics in chemical handling equipment.

Materials rated A or B at 20 °C

Based on the row for 40 %, 20 °C.

Thermoplastics
LDPE B, Nylon (PA) B, Acetal (POM) B, PMP B
Fluoropolymers
PTFE A, FEP A, ECTFE/ETFE B
Metals
SS 316 A, SS 304 A, Aluminium A

About SAN

Styrene-acrylonitrile resists oils and dilute acids better than polystyrene, but ketones, esters and aromatic and chlorinated solvents still attack it.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.