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SAN and Acetic Acid: Chemical Resistance

Styrene-acrylonitrile

Rating

Concentration20 °C50 °CRemark
5 %AA
10 %AC
50 %––
90 %DD
100 %––

Material comparison at 20 °C

Acetic Acid: Material comparison at 20 °CSAN: D (highlighted); Aluminium: A; ECTFE/ETFE: A; FEP: A; HDPE: A; LDPE: A.Aluminium: AECTFE/ETFE: AFEP: AHDPE: ALDPE: APMP: APP: APTFE: APVC Rigid: APVDF: ASS 304: ASS 316: APolysulfone: CEPDM: DViton (FPM): DNBR: DNylon (PA): DPolycarbonate: DPETG: DAcetal (POM): DPolystyrene: DPVC Flexible: DSAN: DSANSilicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

The resistance of SAN to Acetic Acid is concentration-dependent. Across the 3 tested concentrations (5 %, 10 %, 90 %), the 20 °C rating ranges from A at lower concentrations to D at higher ones. This means engineers must verify which concentration their process actually involves before relying on a single rating. However, at 50 °C the resistance rating drops, indicating that temperature must be factored into the design. For heated applications, additional testing under actual service conditions is strongly recommended.

Application context

Acetic Acid is commonly encountered in laboratory work and chemical processing. SAN (Styrene-acrylonitrile) is a thermoplastic typically used for tanks, piping, containers and liners. Because Acetic Acid is classified as corrosive, the choice of containment material is especially critical to prevent leaks, equipment damage, and safety hazards.

Practical recommendation

SAN is not recommended for use with Acetic Acid. The D rating indicates that the material will suffer rapid and severe degradation, which may include cracking, dissolution, severe swelling, or complete structural failure. Using this combination risks equipment damage, leaks, and potential safety incidents. Consider using HDPE, LDPE, PMP instead, which are rated A for this chemical and offer reliable long-term performance.

Did you know?

In industrial practice, SAN components exposed to Acetic Acid are typically inspected for swelling, discoloration, or loss of mechanical strength as early indicators of chemical attack.

Materials rated A or B at 20 °C

Based on the row for 90 %, 20 °C.

Thermoplastics
HDPE A, PP A, PVC Rigid A, LDPE A, PMP A
Fluoropolymers
PTFE A, PVDF A, FEP A, ECTFE/ETFE A
Metals
SS 316 A, SS 304 A, Aluminium A

About SAN

Styrene-acrylonitrile resists oils and dilute acids better than polystyrene, but ketones, esters and aromatic and chlorinated solvents still attack it.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.