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PVDF and Calcium Hypochlorite: Chemical Resistance

Polyvinylidene fluoride

Rating

Concentration20 °C50 °CRemark
aqueousAA
saturatedAC

Material comparison at 20 °C

Calcium Hypochlorite: Material comparison at 20 °CPVDF: A (highlighted); ECTFE/ETFE: A; FEP: A; HDPE: A; LDPE: A; Nylon (PA): A.ECTFE/ETFE: AFEP: AHDPE: ALDPE: ANylon (PA): APMP: AAcetal (POM): APP: APolysulfone: APTFE: APVDF: APVDFSAN: AEPDM: BViton (FPM): BPolystyrene: BPVC Rigid: BSS 316: BPolycarbonate: CPETG: CPVC Flexible: CSS 304: CAluminium: DNBR: DSilicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

PVDF shows excellent resistance to Calcium Hypochlorite across all 2 tested concentrations (aqueous, saturated) at 20 °C, making it a reliable choice for storage, transfer, and handling applications involving this chemical at any of the tested strengths. However, at 50 °C the resistance rating drops, indicating that temperature must be factored into the design. For heated applications, additional testing under actual service conditions is strongly recommended.

Application context

Calcium Hypochlorite is commonly encountered in water disinfection and chemical processing. PVDF (Polyvinylidene fluoride) is a fluoropolymer typically used for seals, gaskets, valve seats and lined equipment. Because Calcium Hypochlorite is classified as corrosive, the choice of containment material is especially critical to prevent leaks, equipment damage, and safety hazards.

Practical recommendation

PVDF can be used with confidence for Calcium Hypochlorite containment and handling. The A rating indicates that the material shows no significant change in weight, dimensions, or mechanical properties after prolonged contact under test conditions. At elevated temperatures (50 °C), some reduction in resistance occurs, so periodic inspection is advisable for heated applications. Always verify performance under actual operating conditions before committing to a design.

Did you know?

Temperature is often the deciding factor when selecting materials for Calcium Hypochlorite: even materials rated A at 20 °C may lose performance at elevated temperatures.

Materials rated A or B at 20 °C

Based on the row for saturated, 20 °C.

Thermoplastics
HDPE A, PP A, PVC Rigid B, LDPE A, Nylon (PA) A, Acetal (POM) A, Polystyrene B, Polysulfone A, PMP A, SAN A
Fluoropolymers
PTFE A, FEP A, ECTFE/ETFE A
Elastomers
EPDM B, Viton (FPM) B
Metals
SS 316 B

About PVDF

PVDF resists acids, halogens and hydrocarbons. Strong bases, amines, ketones and esters attack it. Service temperature is up to about 150 °C.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.