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PVC Rigid and Dichlorodifluoromethane (R-12): Chemical Resistance

Rigid (unplasticised) polyvinyl chloride

Rating

Concentration20 °C50 °CRemark
technical gradeB–
concentration not statedB–

Material comparison at 20 °C

Dichlorodifluoromethane (R-12): Material comparison at 20 °CPVC Rigid: B (highlighted); Nylon (PA): A; Acetal (POM): A; Polysulfone: A; PTFE: A; Aluminium: C.Nylon (PA): AAcetal (POM): APolysulfone: APTFE: APVC Rigid: BPVC-UAluminium: CEPDM: CFEP: CViton (FPM): CLDPE: CNBR: CPVDF: CSAN: CHDPE: DPolycarbonate: DPP: DPolystyrene: DPVC Flexible: DECTFE/ETFE: –PETG: –PMP: –Silicone: –SS 304: –SS 316: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

PVC Rigid maintains a consistent rating of B across all 2 tested concentrations (technical grade) of Dichlorodifluoromethane (R-12) at 20 °C. The fact that the rating does not change with concentration within the tested range simplifies material selection, though the boundary conditions beyond this range remain untested. The rating remains stable between 20 °C and 50 °C, which means this material can also handle moderately elevated process temperatures without additional risk.

Application context

Dichlorodifluoromethane (R-12) is commonly encountered in chemical processing and water disinfection. PVC Rigid (Rigid (unplasticised) polyvinyl chloride) is a thermoplastic typically used for tanks, piping, containers and liners. The compatibility between these two is therefore an important consideration for engineers and procurement teams selecting containment, transfer, or processing equipment.

Practical recommendation

PVC Rigid is suitable for use with Dichlorodifluoromethane (R-12) under normal conditions, but some minor effects on the material are expected over time. Periodic monitoring for swelling, softening, or weight change is recommended, especially for long-service components. For safety-critical or long-life applications, consider Nylon (PA), Acetal (POM), Polysulfone instead, which are rated A for this chemical.

Did you know?

Chemical resistance testing according to DIN and ISO standards typically evaluates weight change, dimensional change, and retention of tensile strength after immersion.

Materials rated A or B at 20 °C

Based on the row for technical grade, 20 °C.

Thermoplastics
Nylon (PA) A, Acetal (POM) A, Polysulfone A
Fluoropolymers
PTFE A

About PVC Rigid

Rigid PVC resists acids, alkalis and salt solutions well. Ketones, esters, aromatic and chlorinated solvents dissolve or swell it. Service temperature is limited to about 60 °C.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.