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Dichlorodifluoromethane (R-12) Chemical Resistance

Resistance ratings for 24 plastics, elastomers and metals at 20 °C and 50 °C. Listed at 2 concentrations, because the rating depends on it.

At a glance

Based on the row for technical grade, 20 °C.

Rated A, very good resistance
PTFE, Nylon (PA), Acetal (POM), Polysulfone (4)
Rated B, good resistance
PVC Rigid (1)
Rated C, limited resistance
PVDF, EPDM, Viton (FPM), NBR, Aluminium, LDPE, FEP, SAN (8)
Rated D, not resistant
HDPE, PP, Polycarbonate, PVC Flexible, Polystyrene (5)
No data in the source
SS 316, SS 304, ECTFE/ETFE, Silicone, PETG, PMP
Rated lower at 50 °C than at 20 °C
PVDF (C → D), LDPE (C → D)

Based on the row for technical grade, 20 °C.

Rating profile by material family

Dichlorodifluoromethane (R-12): Rating profile by material familyThermoplastics: 3 A, 1 B, 2 C, 5 D, 2 no data. Fluoropolymers: 1 A, 2 C, 1 no data. Elastomers: 3 C, 1 no data. Metals: 1 C, 2 no data.Thermoplastics (13)Thermoplastics: 3 × A, very good resistance (Acetal (POM), Nylon (PA), Polysulfone)A 3Thermoplastics: 1 × B, good resistance (PVC Rigid)Thermoplastics: 2 × C, limited resistance (LDPE, SAN)C 2Thermoplastics: 5 × D, not resistant (HDPE, PP, PVC Flexible, Polystyrene, Polycarbonate)D 5Thermoplastics: 2 × no data (PMP, PETG)– 2Fluoropolymers (4)Fluoropolymers: 1 × A, very good resistance (PTFE)A 1Fluoropolymers: 2 × C, limited resistance (FEP, PVDF)C 2Fluoropolymers: 1 × no data (ECTFE/ETFE)– 1Elastomers (4)Elastomers: 3 × C, limited resistance (EPDM, Viton (FPM), NBR)C 3Elastomers: 1 × no data (Silicone)– 1Metals (3)Metals: 1 × C, limited resistance (Aluminium)C 1Metals: 2 × no data (SS 316, SS 304)– 2
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Number of materials in each family with each rating at 20 °C.

Effect of temperature, 20 °C to 50 °C

Dichlorodifluoromethane (R-12): Effect of temperature, 20 °C to 50 °CLDPE C → D; PVDF C → D.ABCDLDPE: C at 20 °C, D at 50 °CLDPEPVDF: C at 20 °C, D at 50 °CPVDF
20 °C50 °C
Materials whose rating differs between 20 °C and 50 °C. Materials not shown keep their rating or have no 50 °C value.

Substance

CAS number
75-71-8
Formula
CCl2F2
Hazard symbols in the source
N (dangerous for the environment) (pre-GHS European symbols; check the current safety data sheet)
Concentrations listed
technical grade; concentration not stated
Also listed as
Freon 12 (R-12); Freon 12 (CFC-12); Frigen 12 (CFC-12)
Name in the source (German)
Dichlordifluormethan

Rating by concentration

Dichlorodifluoromethane (R-12): Rating by concentrationHDPE: technical grade D, concentration not stated D. LDPE: technical grade C→D, concentration not stated C→D. PP: technical grade D, concentration not stated D. PVC Rigid: technical grade B, concentration not stated B. PVC Flexible: technical grade D, concentration not stated D. Polystyrene: technical grade D, concentration not stated D. SAN: technical grade C, concentration not stated C. Polycarbonate: technical grade D, concentration not stated D. Acetal (POM): technical grade A, concentration not stated A. Nylon (PA): technical grade A, concentration not stated A. Polysulfone: technical grade A, concentration not stated A. PTFE: technical grade A, concentration not stated A. FEP: technical grade C, concentration not stated C. PVDF: technical grade C→D, concentration not stated C→D. EPDM: technical grade C, concentration not stated C. Viton (FPM): technical grade C, concentration not stated C. NBR: technical grade C, concentration not stated C. Aluminium: technical grade C*, concentration not stated C*.technical gradeconcentrationnot statedTHERMOPLASTICSHDPEHDPE, technical grade: D at 20 °C, D at 50 °CDHDPE, concentration not stated: D at 20 °C, D at 50 °CDLDPELDPE, technical grade: C at 20 °C, D at 50 °CC→DLDPE, concentration not stated: C at 20 °C, D at 50 °CC→DPPPP, technical grade: D at 20 °C, D at 50 °CDPP, concentration not stated: D at 20 °C, D at 50 °CDPVC RigidPVC Rigid, technical grade: B at 20 °CBPVC Rigid, concentration not stated: B at 20 °CBPVC FlexiblePVC Flexible, technical grade: D at 20 °C, D at 50 °CDPVC Flexible, concentration not stated: D at 20 °C, D at 50 °CDPolystyrenePolystyrene, technical grade: D at 20 °C, D at 50 °CDPolystyrene, concentration not stated: D at 20 °C, D at 50 °CDSANSAN, technical grade: C at 20 °C, C at 50 °CCSAN, concentration not stated: C at 20 °C, C at 50 °CCPolycarbonatePolycarbonate, technical grade: D at 20 °C, D at 50 °CDPolycarbonate, concentration not stated: D at 20 °C, D at 50 °CDAcetal (POM)Acetal (POM), technical grade: A at 20 °CAAcetal (POM), concentration not stated: A at 20 °CANylon (PA)Nylon (PA), technical grade: A at 20 °CANylon (PA), concentration not stated: A at 20 °CAPolysulfonePolysulfone, technical grade: A at 20 °CAPolysulfone, concentration not stated: A at 20 °CAFLUOROPOLYMERSPTFEPTFE, technical grade: A at 20 °CAPTFE, concentration not stated: A at 20 °CAFEPFEP, technical grade: C at 20 °C, C at 50 °CCFEP, concentration not stated: C at 20 °C, C at 50 °CCPVDFPVDF, technical grade: C at 20 °C, D at 50 °CC→DPVDF, concentration not stated: C at 20 °C, D at 50 °CC→DELASTOMERSEPDMEPDM, technical grade: C at 20 °CCEPDM, concentration not stated: C at 20 °CCViton (FPM)Viton (FPM), technical grade: C at 20 °CCViton (FPM), concentration not stated: C at 20 °CCNBRNBR, technical grade: C at 20 °C, C at 50 °CCNBR, concentration not stated: C at 20 °C, C at 50 °CCMETALSAluminiumAluminium, technical grade: C at 20 °C (estimate)C*Aluminium, concentration not stated: C at 20 °C (estimate)C*
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each cell shows the rating at 20 °C. Where the rating at 50 °C differs, it follows the arrow. * marks an estimate in the source.
Show as a table
Materialtechnical gradeconcentration not stated
Thermoplastics
HDPEDD
LDPECC
PPDD
PVC RigidBB
PVC FlexibleDD
PMP––
PolystyreneDD
SANCC
PolycarbonateDD
PETG––
Acetal (POM)AA
Nylon (PA)AA
PolysulfoneAA
Fluoropolymers
PTFEAA
FEPCC
PVDFCC
ECTFE/ETFE––
Elastomers
EPDMCC
Viton (FPM)CC
NBRCC
Silicone––
Metals
SS 316––
SS 304––
AluminiumC*C*

* estimated rating, given in the source without a temperature

Resistance table: Dichlorodifluoromethane (R-12), technical grade

Material20 °C50 °CRemark
Thermoplastics
HDPEDD
LDPECD
PPDD
PVC RigidB–
PVC FlexibleDD
PolystyreneDD
SANCC
PolycarbonateDD
Acetal (POM)A–
Nylon (PA)A–
PolysulfoneA–
Fluoropolymers
PTFEA–
FEPCC
PVDFCD
Elastomers
EPDMC–
Viton (FPM)C–
NBRCC
Metals
AluminiumC*–

* estimated rating, given in the source without a temperature

Not rated in the source, so not in the table: PMP, PETG, ECTFE/ETFE, Silicone, SS 316, SS 304

Resistance table: Dichlorodifluoromethane (R-12), concentration not stated

Material20 °C50 °CRemark
Thermoplastics
HDPEDD
LDPECD
PPDD
PVC RigidB–
PVC FlexibleDD
PolystyreneDD
SANCC
PolycarbonateDD
Acetal (POM)A–
Nylon (PA)A–
PolysulfoneA–
Fluoropolymers
PTFEA–
FEPCC
PVDFCD
Elastomers
EPDMC–
Viton (FPM)C–
NBRCC
Metals
AluminiumC*–

* estimated rating, given in the source without a temperature

Not rated in the source, so not in the table: PMP, PETG, ECTFE/ETFE, Silicone, SS 316, SS 304

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.

Chemicals with a similar resistance profile

Same 20 °C rating on the share of materials shown.