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PP and Perchloric Acid: Chemical Resistance

Polypropylene

Rating

Concentration20 °C50 °CRemark
20 %AC
70 %DD

Material comparison at 20 °C

Perchloric Acid: Material comparison at 20 °CPP: D (highlighted); ECTFE/ETFE: A; FEP: A; Viton (FPM): A; PTFE: A; PVDF: A.ECTFE/ETFE: AFEP: AViton (FPM): APTFE: APVDF: AHDPE: BPMP: BPolystyrene: BEPDM: CLDPE: CPVC Rigid: CAluminium: DNBR: DNylon (PA): DPolycarbonate: DPETG: DAcetal (POM): DPP: DPPPolysulfone: DPVC Flexible: DSAN: –Silicone: –SS 304: –SS 316: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

The resistance of PP to Perchloric Acid is concentration-dependent. Across the 2 tested concentrations (20 %, 70 %), the 20 °C rating ranges from A at lower concentrations to D at higher ones. This means engineers must verify which concentration their process actually involves before relying on a single rating. However, at 50 °C the resistance rating drops, indicating that temperature must be factored into the design. For heated applications, additional testing under actual service conditions is strongly recommended.

Application context

Perchloric Acid is commonly encountered in metal finishing and chemical processing. PP (Polypropylene) is a thermoplastic typically used for tanks, piping, containers and liners. Because Perchloric Acid is classified as corrosive, the choice of containment material is especially critical to prevent leaks, equipment damage, and safety hazards.

Practical recommendation

PP is not recommended for use with Perchloric Acid. The D rating indicates that the material will suffer rapid and severe degradation, which may include cracking, dissolution, severe swelling, or complete structural failure. Using this combination risks equipment damage, leaks, and potential safety incidents. Consider using ECTFE/ETFE, FEP, PTFE instead, which are rated A for this chemical and offer reliable long-term performance.

Did you know?

Temperature is often the deciding factor when selecting materials for Perchloric Acid: even materials rated A at 20 °C may lose performance at elevated temperatures.

Materials rated A or B at 20 °C

Based on the row for 70 %, 20 °C.

Thermoplastics
HDPE B, Polystyrene B, PMP B
Fluoropolymers
PTFE A, PVDF A, FEP A, ECTFE/ETFE A
Elastomers
Viton (FPM) A

About PP

Polypropylene resists most acids, alkalis and salt solutions. Concentrated oxidising acids, chlorinated solvents and aromatic hydrocarbons attack it, and it turns brittle below about 0 °C.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.