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PETG and Sodium Hydroxide (Caustic Soda): Chemical Resistance

Polyethylene terephthalate glycol (co-polyester)

Rating

Concentration20 °C50 °CRemark
1 %C*–
30 %DD
45 %DD
50 %DD
60 %DD
concentratedDD

* estimated rating, given in the source without a temperature

Material comparison at 20 °C

Sodium Hydroxide (Caustic Soda): Material comparison at 20 °CPETG: D (highlighted); EPDM: A; HDPE: A; LDPE: A; Nylon (PA): A; PMP: A.EPDM: AHDPE: ALDPE: ANylon (PA): APMP: APP: APolystyrene: APolysulfone: APTFE: ASS 304: ASS 316: ANBR: BViton (FPM): CAcetal (POM): CAluminium: DPolycarbonate: DPETG: DPETGPVDF: DECTFE/ETFE: –FEP: –PVC Rigid: –PVC Flexible: –SAN: –Silicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

The resistance of PETG to Sodium Hydroxide (Caustic Soda) is concentration-dependent. Across the 6 tested concentrations (1 %, 30 %, 45 %, 50 %, 60 %, concentrated), the 20 °C rating ranges from C at lower concentrations to D at higher ones. This means engineers must verify which concentration their process actually involves before relying on a single rating. The rating remains stable between 20 °C and 50 °C, which means this material can also handle moderately elevated process temperatures without additional risk.

Application context

Sodium Hydroxide (Caustic Soda) is commonly encountered in pulp and paper and chemical processing. PETG (Polyethylene terephthalate glycol (co-polyester)) is a thermoplastic typically used for tanks, piping, containers and liners. Because Sodium Hydroxide (Caustic Soda) is classified as corrosive, the choice of containment material is especially critical to prevent leaks, equipment damage, and safety hazards.

Practical recommendation

PETG is not recommended for use with Sodium Hydroxide (Caustic Soda). The D rating indicates that the material will suffer rapid and severe degradation, which may include cracking, dissolution, severe swelling, or complete structural failure. Using this combination risks equipment damage, leaks, and potential safety incidents. Consider using HDPE, LDPE, Nylon (PA) instead, which are rated A for this chemical and offer reliable long-term performance.

Did you know?

In industrial practice, PETG components exposed to Sodium Hydroxide (Caustic Soda) are typically inspected for swelling, discoloration, or loss of mechanical strength as early indicators of chemical attack.

Materials rated A or B at 20 °C

Based on the row for 60 %, 20 °C.

Thermoplastics
HDPE A, PP A, LDPE A, Nylon (PA) A, Polystyrene A, Polysulfone A, PMP A
Fluoropolymers
PTFE A
Elastomers
EPDM A, NBR B
Metals
SS 316 A, SS 304 A

About PETG

PETG is a co-polyester for clear containers. Strong acids and alkalis and most organic solvents attack it.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.