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PVC Rigid and Hydrochloric Acid: Chemical Resistance

Rigid (unplasticised) polyvinyl chloride

Rating

Concentration20 °C50 °CRemark
1-5 %AA
20 %AC
35 %BC
concentratedBC

Material comparison at 20 °C

Hydrochloric Acid: Material comparison at 20 °CPVC Rigid: B (highlighted); ECTFE/ETFE: A; FEP: A; Viton (FPM): A; HDPE: A; LDPE: A.ECTFE/ETFE: AFEP: AViton (FPM): AHDPE: ALDPE: APMP: APP: APolysulfone: APTFE: APVDF: ASAN: APVC Rigid: BPVC-UEPDM: CPolystyrene: CPVC Flexible: CAluminium: DNBR: DNylon (PA): DPolycarbonate: DPETG: DAcetal (POM): DSS 304: DSS 316: DSilicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

The resistance of PVC Rigid to Hydrochloric Acid is concentration-dependent. Across the 4 tested concentrations (1-5 %, 20 %, 35 %, concentrated), the 20 °C rating ranges from A at lower concentrations to C at higher ones. This means engineers must verify which concentration their process actually involves before relying on a single rating. However, at 50 °C the resistance rating drops, indicating that temperature must be factored into the design. For heated applications, additional testing under actual service conditions is strongly recommended.

Application context

Hydrochloric Acid is commonly encountered in chemical processing and water treatment. PVC Rigid (Rigid (unplasticised) polyvinyl chloride) is a thermoplastic typically used for tanks, piping, containers and liners. Because Hydrochloric Acid is classified as corrosive, the choice of containment material is especially critical to prevent leaks, equipment damage, and safety hazards.

Practical recommendation

PVC Rigid is suitable for use with Hydrochloric Acid under normal conditions, but some minor effects on the material are expected over time. Periodic monitoring for swelling, softening, or weight change is recommended, especially for long-service components. Avoid prolonged exposure at elevated temperatures, as the resistance decreases further at 50 °C. For safety-critical or long-life applications, consider HDPE, LDPE, PMP instead, which are rated A for this chemical.

Did you know?

In industrial practice, PVC Rigid components exposed to Hydrochloric Acid are typically inspected for swelling, discoloration, or loss of mechanical strength as early indicators of chemical attack.

Materials rated A or B at 20 °C

Based on the row for 35 %, 20 °C.

Thermoplastics
HDPE A, PP A, LDPE A, Polysulfone A, PMP A, SAN A
Fluoropolymers
PTFE A, PVDF A, FEP A, ECTFE/ETFE A
Elastomers
Viton (FPM) A

About PVC Rigid

Rigid PVC resists acids, alkalis and salt solutions well. Ketones, esters, aromatic and chlorinated solvents dissolve or swell it. Service temperature is limited to about 60 °C.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.