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PVC Rigid and Perchloric Acid: Chemical Resistance

Rigid (unplasticised) polyvinyl chloride

Rating

Concentration20 °C50 °CRemark
20 %AC
70 %CD

Material comparison at 20 °C

Perchloric Acid: Material comparison at 20 °CPVC Rigid: C (highlighted); ECTFE/ETFE: A; FEP: A; Viton (FPM): A; PTFE: A; PVDF: A.ECTFE/ETFE: AFEP: AViton (FPM): APTFE: APVDF: AHDPE: BPMP: BPolystyrene: BEPDM: CLDPE: CPVC Rigid: CPVC-UAluminium: DNBR: DNylon (PA): DPolycarbonate: DPETG: DAcetal (POM): DPP: DPolysulfone: DPVC Flexible: DSAN: –Silicone: –SS 304: –SS 316: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

The resistance of PVC Rigid to Perchloric Acid is concentration-dependent. Across the 2 tested concentrations (20 %, 70 %), the 20 °C rating ranges from A at lower concentrations to D at higher ones. This means engineers must verify which concentration their process actually involves before relying on a single rating. However, at 50 °C the resistance rating drops, indicating that temperature must be factored into the design. For heated applications, additional testing under actual service conditions is strongly recommended.

Application context

Perchloric Acid is commonly encountered in surface cleaning and laboratory work. PVC Rigid (Rigid (unplasticised) polyvinyl chloride) is a thermoplastic typically used for tanks, piping, containers and liners. Because Perchloric Acid is classified as corrosive, the choice of containment material is especially critical to prevent leaks, equipment damage, and safety hazards.

Practical recommendation

PVC Rigid has limited resistance to Perchloric Acid and should only be used for short-term or intermittent contact at ambient temperature. The C rating means the material undergoes noticeable changes — swelling, loss of strength, or surface degradation — that make it unsuitable for permanent installations. For prolonged or continuous exposure, ECTFE/ETFE, FEP, PTFE offer significantly better resistance and are rated A.

Did you know?

Chemical resistance testing according to DIN and ISO standards typically evaluates weight change, dimensional change, and retention of tensile strength after immersion.

Materials rated A or B at 20 °C

Based on the row for 70 %, 20 °C.

Thermoplastics
HDPE B, Polystyrene B, PMP B
Fluoropolymers
PTFE A, PVDF A, FEP A, ECTFE/ETFE A
Elastomers
Viton (FPM) A

About PVC Rigid

Rigid PVC resists acids, alkalis and salt solutions well. Ketones, esters, aromatic and chlorinated solvents dissolve or swell it. Service temperature is limited to about 60 °C.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.