ChemicalResistance
ChemicalResistance.org

SS 316 and Sodium Hypochlorite (Bleach): Chemical Resistance

Stainless steel 1.4401 (AISI 316)

Rating

Concentration20 °C50 °CRemark
12,5 % ClBBpitting risk
15 %BBpitting risk
diluteBBpitting risk
saturatedBBpitting risk

Material comparison at 20 °C

Sodium Hypochlorite (Bleach): Material comparison at 20 °CSS 316: B (highlighted); ECTFE/ETFE: A; FEP: A; Viton (FPM): A; PMP: A; Polystyrene: A.ECTFE/ETFE: AFEP: AViton (FPM): APMP: APolystyrene: APolysulfone: APTFE: APVC Rigid: ASAN: AHDPE: BLDPE: BPolycarbonate: BPP: BSS 316: B316EPDM: CPETG: CPVDF: CSS 304: CAluminium: DNBR: DNylon (PA): DAcetal (POM): DPVC Flexible: –Silicone: –
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Each bar is one material. Taller bars indicate better resistance. The highlighted bar is the current material.

Resistance overview

SS 316 maintains a consistent rating of B across all 4 tested concentrations (12,5 % Cl, 15 %, dilute, saturated) of Sodium Hypochlorite (Bleach) at 20 °C. The fact that the rating does not change with concentration within the tested range simplifies material selection, though the boundary conditions beyond this range remain untested. The rating remains stable between 20 °C and 50 °C, which means this material can also handle moderately elevated process temperatures without additional risk. Note that the source flags a risk of pitting or stress-corrosion cracking for this combination, which is particularly relevant for pressure-bearing or structurally loaded components.

Application context

Sodium Hypochlorite (Bleach) is commonly encountered in waste treatment and bleaching. SS 316 (Stainless steel 1.4401 (AISI 316)) is a metal typically used for vessels, heat exchangers, fittings and structural components. Because Sodium Hypochlorite (Bleach) is classified as corrosive, the choice of containment material is especially critical to prevent leaks, equipment damage, and safety hazards.

Practical recommendation

SS 316 is suitable for use with Sodium Hypochlorite (Bleach) under normal conditions, but some minor effects on the material are expected over time. Periodic monitoring for swelling, softening, or weight change is recommended, especially for long-service components. For safety-critical or long-life applications, consider PMP, Polystyrene, Polysulfone instead, which are rated A for this chemical.

Did you know?

The chemical resistance of SS 316 depends not only on the chemical concentration but also on exposure time, mechanical stress, and the presence of other chemicals in the mixture.

Materials rated A or B at 20 °C

Based on the row for 15 %, 20 °C.

Thermoplastics
HDPE B, PP B, PVC Rigid A, LDPE B, Polycarbonate B, Polystyrene A, Polysulfone A, PMP A, SAN A
Fluoropolymers
PTFE A, FEP A, ECTFE/ETFE A
Elastomers
Viton (FPM) A

About SS 316

Stainless steel 316 (1.4401) contains molybdenum, which improves resistance to chlorides over 304. Hydrochloric acid and other halide acids still cause pitting.

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.