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Hydrogen Sulfide Chemical Resistance

Resistance ratings for 24 plastics, elastomers and metals at 20 °C and 50 °C.

At a glance

Based on the row for saturated, 20 °C.

Rated A, very good resistance
PTFE, HDPE, PP, PVDF, PVC Rigid, EPDM, SS 316, SS 304, Aluminium, LDPE, FEP, Nylon (PA), Acetal (POM), Polycarbonate, Polysulfone, PETG, SAN (17)
Rated B, good resistance
none (0)
Rated C, limited resistance
Viton (FPM), PVC Flexible, Polystyrene (3)
Rated D, not resistant
NBR (1)
No data in the source
ECTFE/ETFE, Silicone, PMP
Rated lower at 50 °C than at 20 °C
PVC Rigid (A → C)

Based on the row for saturated, 20 °C.

Rating profile by material family

Hydrogen Sulfide: Rating profile by material familyThermoplastics: 10 A, 2 C, 1 no data. Fluoropolymers: 3 A, 1 no data. Elastomers: 1 A, 1 C, 1 D, 1 no data. Metals: 3 A.Thermoplastics (13)Thermoplastics: 10 × A, very good resistance (HDPE, LDPE, PP, PVC Rigid, SAN, Polycarbonate, PETG, Acetal (POM), Nylon (PA), Polysulfone)A 10Thermoplastics: 2 × C, limited resistance (PVC Flexible, Polystyrene)C 2Thermoplastics: 1 × no data (PMP)Fluoropolymers (4)Fluoropolymers: 3 × A, very good resistance (PTFE, FEP, PVDF)A 3Fluoropolymers: 1 × no data (ECTFE/ETFE)– 1Elastomers (4)Elastomers: 1 × A, very good resistance (EPDM)A 1Elastomers: 1 × C, limited resistance (Viton (FPM))C 1Elastomers: 1 × D, not resistant (NBR)D 1Elastomers: 1 × no data (Silicone)– 1Metals (3)Metals: 3 × A, very good resistance (SS 316, SS 304, Aluminium)A 3
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Number of materials in each family with each rating at 20 °C.

Effect of temperature, 20 °C to 50 °C

Hydrogen Sulfide: Effect of temperature, 20 °C to 50 °CPVC Rigid A → C.ABCDPVC Rigid: A at 20 °C, C at 50 °CPVC Rigid
20 °C50 °C
Materials whose rating differs between 20 °C and 50 °C. Materials not shown keep their rating or have no 50 °C value.

Substance

CAS number
7783-06-4
Formula
H2S
Hazard symbols in the source
F+ (extremely flammable), T+ (very toxic) (pre-GHS European symbols; check the current safety data sheet)
Flammable
yes
Concentrations listed
saturated
Name in the source (German)
Schwefelwasserstoff

Resistance table: Hydrogen Sulfide, saturated

Material20 °C50 °CRemark
Thermoplastics
HDPEAA
LDPEAA
PPAA
PVC RigidAC
PVC FlexibleCC
PolystyreneC–
SANA–
PolycarbonateA–
PETGA–
Acetal (POM)A–
Nylon (PA)A–
PolysulfoneA–
Fluoropolymers
PTFEAA
FEPA–
PVDFAA
Elastomers
EPDMA–
Viton (FPM)C*–
NBRDD
Metals
SS 316AA
SS 304AA
AluminiumAA

* estimated rating, given in the source without a temperature

Not rated in the source, so not in the table: PMP, ECTFE/ETFE, Silicone

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

Frequently Asked Questions

Which materials resist Hydrogen Sulfide at high concentrations?

The materials with an A rating (resistant) for Hydrogen Sulfide at 20 °C are: PTFE, HDPE, PP, PVDF, PVC Rigid, EPDM, SS 316, SS 304. These can generally be used in direct contact.

Which materials should be avoided with Hydrogen Sulfide?

Materials rated D (not resistant) for Hydrogen Sulfide are: NBR. These should not be used in contact with Hydrogen Sulfide.

Does temperature affect chemical resistance to Hydrogen Sulfide?

Yes. 1 of 11 tested materials show a worse rating at 50 °C than at 20 °C for Hydrogen Sulfide. Materials affected include: PVC Rigid.

Is PTFE safe for Hydrogen Sulfide?

PTFE is rated A for Hydrogen Sulfide at 20 °C. A rating of A means resistant, B means limited resistance, C means partly resistant, and D means not resistant.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.

Chemicals with a similar resistance profile

Same 20 °C rating on the share of materials shown.