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Hydrogen Chloride Gas Chemical Resistance

Resistance ratings for 24 plastics, elastomers and metals at 20 °C and 50 °C.

At a glance

Based on the row for anhydrous, 20 °C.

Rated A, very good resistance
PTFE, HDPE, PP, PVDF, PVC Rigid, EPDM, Viton (FPM), FEP (8)
Rated B, good resistance
SS 316, SS 304 (2)
Rated C, limited resistance
Polycarbonate (1)
Rated D, not resistant
NBR, Aluminium, Nylon (PA), Acetal (POM), PETG (5)
No data in the source
LDPE, ECTFE/ETFE, Silicone, PVC Flexible, Polystyrene, Polysulfone, PMP, SAN
Rated lower at 50 °C than at 20 °C
PVC Rigid (A → C)
Risk of pitting or stress-corrosion cracking
SS 316, SS 304

Based on the row for anhydrous, 20 °C.

Rating profile by material family

Hydrogen Chloride Gas: Rating profile by material familyThermoplastics: 3 A, 1 C, 3 D, 6 no data. Fluoropolymers: 3 A, 1 no data. Elastomers: 2 A, 1 D, 1 no data. Metals: 2 B, 1 D.Thermoplastics (13)Thermoplastics: 3 × A, very good resistance (HDPE, PP, PVC Rigid)A 3Thermoplastics: 1 × C, limited resistance (Polycarbonate)Thermoplastics: 3 × D, not resistant (PETG, Acetal (POM), Nylon (PA))D 3Thermoplastics: 6 × no data (LDPE, PVC Flexible, PMP, Polystyrene, SAN, Polysulfone)– 6Fluoropolymers (4)Fluoropolymers: 3 × A, very good resistance (PTFE, FEP, PVDF)A 3Fluoropolymers: 1 × no data (ECTFE/ETFE)– 1Elastomers (4)Elastomers: 2 × A, very good resistance (EPDM, Viton (FPM))A 2Elastomers: 1 × D, not resistant (NBR)D 1Elastomers: 1 × no data (Silicone)– 1Metals (3)Metals: 2 × B, good resistance (SS 316, SS 304)B 2Metals: 1 × D, not resistant (Aluminium)D 1
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Number of materials in each family with each rating at 20 °C.

Effect of temperature, 20 °C to 50 °C

Hydrogen Chloride Gas: Effect of temperature, 20 °C to 50 °CPVC Rigid A → C.ABCDPVC Rigid: A at 20 °C, C at 50 °CPVC Rigid
20 °C50 °C
Materials whose rating differs between 20 °C and 50 °C. Materials not shown keep their rating or have no 50 °C value.

Substance

CAS number
7647-01-0
Formula
HCl
Hazard symbols in the source
T (toxic), C (corrosive) (pre-GHS European symbols; check the current safety data sheet)
Concentrations listed
anhydrous
Name in the source (German)
Chlorwasserstoff(gas)

Resistance table: Hydrogen Chloride Gas, anhydrous

Material20 °C50 °CRemark
Thermoplastics
HDPEAA
PPAA
PVC RigidAC
PolycarbonateC*–
PETGDD
Acetal (POM)DD
Nylon (PA)DD
Fluoropolymers
PTFEAA
FEPAA
PVDFAA
Elastomers
EPDMA–
Viton (FPM)A–
NBRDD
Metals
SS 316BBpitting risk
SS 304BBpitting risk
AluminiumD*–

* estimated rating, given in the source without a temperature

Not rated in the source, so not in the table: LDPE, PVC Flexible, PMP, Polystyrene, SAN, Polysulfone, ECTFE/ETFE, Silicone

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

Frequently Asked Questions

Which materials resist Hydrogen Chloride Gas at high concentrations?

The materials with an A rating (resistant) for Hydrogen Chloride Gas at 20 °C are: PTFE, HDPE, PP, PVDF, PVC Rigid, EPDM, Viton (FPM), FEP. These can generally be used in direct contact.

Which materials should be avoided with Hydrogen Chloride Gas?

Materials rated D (not resistant) for Hydrogen Chloride Gas are: NBR, Aluminium, Nylon (PA), Acetal (POM), PETG. These should not be used in contact with Hydrogen Chloride Gas.

Does temperature affect chemical resistance to Hydrogen Chloride Gas?

Yes. 1 of 12 tested materials show a worse rating at 50 °C than at 20 °C for Hydrogen Chloride Gas. Materials affected include: PVC Rigid.

Is PTFE safe for Hydrogen Chloride Gas?

PTFE is rated A for Hydrogen Chloride Gas at 20 °C. A rating of A means resistant, B means limited resistance, C means partly resistant, and D means not resistant.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.

Chemicals with a similar resistance profile

Same 20 °C rating on the share of materials shown.