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PVDF vs NBR: Chemical Resistance Compared

Of 940 source rows rated for both materials at 20 °C, 363 (39 %) have the same rating. PVDF is rated better in 553 rows and NBR in 24. A row is one chemical at one concentration.

Summary

PVDF is rated better with
Aromatic hydrocarbons (+93 points); Mineral acids (+74 points); Oxidising agents and halogens (+72 points); Phenols (+71 points); Esters and ethers (+63 points); Amines and nitrogen compounds (+63 points); Organic acids (+57 points); Ketones and aldehydes (+53 points); Alcohols and glycols (+53 points); Halogenated hydrocarbons (+52 points); Fuels, mineral oils and aliphatic hydrocarbons (+38 points); Vegetable and animal oils, fats, essential oils (+19 points); Salts and salt solutions (+17 points)
Within 10 points of each other
Alkalis; Foods and beverages

Points are the difference in the share of rows rated A or B.

The two materials

PVDF

Polyvinylidene fluoride

PVDF resists acids, halogens and hydrocarbons. Strong bases, amines, ketones and esters attack it. Service temperature is up to about 150 °C.

Rated rows: 944. A 73 %, B 15 %, C 10 %, D 2 %

All chemicals for PVDF

NBR

Nitrile butadiene rubber

Nitrile rubber resists mineral oils and fuels. Ketones, esters, chlorinated solvents, strong oxidisers and ozone attack it.

Rated rows: 983. A 36 %, B 9 %, C 19 %, D 36 %

All chemicals for NBR

Share of rows rated A or B, by chemical class

PVDF, NBR: Share of rows rated A or B, by chemical classMineral acids: PVDF 87 %, NBR 13 %. Organic acids: PVDF 94 %, NBR 37 %. Alkalis: PVDF 64 %, NBR 64 %. Salts and salt solutions: PVDF 99 %, NBR 82 %. Oxidising agents and halogens: PVDF 87 %, NBR 15 %. Alcohols and glycols: PVDF 98 %, NBR 45 %. Phenols: PVDF 71 %, NBR 0 %. Ketones and aldehydes: PVDF 62 %, NBR 9 %. Esters and ethers: PVDF 64 %, NBR 1 %. Amines and nitrogen compounds: PVDF 76 %, NBR 13 %. Aromatic hydrocarbons: PVDF 100 %, NBR 7 %. Fuels, mineral oils and aliphatic hydrocarbons: PVDF 97 %, NBR 59 %. Vegetable and animal oils, fats, essential oils: PVDF 88 %, NBR 69 %. Halogenated hydrocarbons: PVDF 72 %, NBR 20 %. Foods and beverages: PVDF 98 %, NBR 93 %.Mineral acidsMineral acids, PVDF: 87 % (61)87 %Mineral acids, NBR: 13 % (63)13 %Organic acidsOrganic acids, PVDF: 94 % (64)94 %Organic acids, NBR: 37 % (63)37 %AlkalisAlkalis, PVDF: 64 % (22)64 %Alkalis, NBR: 64 % (22)64 %Salts and salt solutionsSalts and salt solutions, PVDF: 99 % (198)99 %Salts and salt solutions, NBR: 82 % (198)82 %Oxidising agents and halogensOxidising agents and halogens, PVDF: 87 % (62)87 %Oxidising agents and halogens, NBR: 15 % (62)15 %Alcohols and glycolsAlcohols and glycols, PVDF: 98 % (58)98 %Alcohols and glycols, NBR: 45 % (58)45 %PhenolsPhenols, PVDF: 71 % (14)71 %Phenols, NBR: 0 % (14)0 %Ketones and aldehydesKetones and aldehydes, PVDF: 62 % (34)62 %Ketones and aldehydes, NBR: 9 % (35)9 %Esters and ethersEsters and ethers, PVDF: 64 % (66)64 %Esters and ethers, NBR: 1 % (76)1 %Amines and nitrogen compoundsAmines and nitrogen compounds, PVDF: 76 % (38)76 %Amines and nitrogen compounds, NBR: 13 % (39)13 %Aromatic hydrocarbonsAromatic hydrocarbons, PVDF: 100 % (14)100 %Aromatic hydrocarbons, NBR: 7 % (14)7 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, PVDF: 97 % (72)97 %Fuels, mineral oils and aliphatic hydrocarbons, NBR: 59 % (78)59 %Vegetable and animal oils, fats, essential oilsVegetable and animal oils, fats, essential oils, PVDF: 88 % (48)88 %Vegetable and animal oils, fats, essential oils, NBR: 69 % (48)69 %Halogenated hydrocarbonsHalogenated hydrocarbons, PVDF: 72 % (54)72 %Halogenated hydrocarbons, NBR: 20 % (71)20 %Foods and beveragesFoods and beverages, PVDF: 98 % (46)98 %Foods and beverages, NBR: 93 % (46)93 %
PVDFNBR
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

PVDF, NBR: How often the two ratings agreePVDF A, NBR A: 318; PVDF A, NBR B: 75; PVDF A, NBR C: 120; PVDF A, NBR D: 171; PVDF B, NBR A: 12; PVDF B, NBR B: 12; PVDF B, NBR C: 37; PVDF B, NBR D: 83; PVDF C, NBR A: 5; PVDF C, NBR B: 1; PVDF C, NBR C: 19; PVDF C, NBR D: 67; PVDF D, NBR A: 1; PVDF D, NBR B: 3; PVDF D, NBR C: 2; PVDF D, NBR D: 14.NBRABCDPVDFAPVDF A, NBR A: 318318PVDF A, NBR B: 7575PVDF A, NBR C: 120120PVDF A, NBR D: 171171BPVDF B, NBR A: 1212PVDF B, NBR B: 1212PVDF B, NBR C: 3737PVDF B, NBR D: 8383CPVDF C, NBR A: 55PVDF C, NBR B: 11PVDF C, NBR C: 1919PVDF C, NBR D: 6767DPVDF D, NBR A: 11PVDF D, NBR B: 33PVDF D, NBR C: 22PVDF D, NBR D: 1414
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classPVDF: rated A or BNBR: rated A or B
Mineral acids87 % (61 rows)13 % (63 rows)
Organic acids94 % (64 rows)37 % (63 rows)
Alkalis64 % (22 rows)64 % (22 rows)
Salts and salt solutions99 % (198 rows)82 % (198 rows)
Oxidising agents and halogens87 % (62 rows)15 % (62 rows)
Alcohols and glycols98 % (58 rows)45 % (58 rows)
Phenols71 % (14 rows)0 % (14 rows)
Ketones and aldehydes62 % (34 rows)9 % (35 rows)
Esters and ethers64 % (66 rows)1 % (76 rows)
Amines and nitrogen compounds76 % (38 rows)13 % (39 rows)
Aromatic hydrocarbons100 % (14 rows)7 % (14 rows)
Fuels, mineral oils and aliphatic hydrocarbons97 % (72 rows)59 % (78 rows)
Vegetable and animal oils, fats, essential oils88 % (48 rows)69 % (48 rows)
Halogenated hydrocarbons72 % (54 rows)20 % (71 rows)
Foods and beverages98 % (46 rows)93 % (46 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 383 in total, the first 40 shown.

ChemicalConcentrationPVDFNBR
1,2-DibromoethaneAD
1,2-DichlorobenzeneAD
1,3-ButadieneAD
1,4-DichlorobenzeneAD
1-ChloronaphthaleneAD
Acetic Acid100 %AD
Acetic Acid50 %AD
Acetic Acid90 %AD
AcetonitrileAD
AcetophenoneAD
Acetyl Chloride100 %AD
Allyl Chloride100 %AD
Ammonium Carbonate50 %AD
Ammonium CarbonateaqueousAD
Ammonium Hydroxide (Ammonia Solution)AD
Ammonium PersulfatesaturatedAD
Ammonium PersulfateaqueousAD
Amyl AcetateAD
Amyl ChlorideAD
AnilineAD
Battery Acid38 %AD
BenzaldehydeAD
BenzeneAD
Benzenesulfonic AcidsaturatedAD
Benzoyl Chloride100 %AD
Benzyl AlcoholAD
Bisulfite Liquor with SO2saturatedAD
Bitter Almond OilAD
BromineAD
Bromine VaporsAD
Bromine WatersaturatedAD
BromobenzeneAD
Bromomethanetechnical gradeAD
Butyl Acetate100 %AD
Butyl Acrylate100 %AD
Butyl Stearate100 %AD
Butylphenol100 %AD
Butyric AcidAD
Calcium HypochloriteAD
Calcium HypochloritesaturatedAD

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is PVDF or NBR more chemical-resistant?

Of 940 chemicals rated for both materials at 20 °C, PVDF and NBR share the same rating in 363 rows (39 %). PVDF is rated better in 553 rows and NBR in 24 rows.

How do PVDF and NBR compare for chemical resistance?

Based on 940 chemicals tested for both: PVDF is rated better with Aromatic hydrocarbons, Mineral acids, Oxidising agents and halogens, Phenols. NBR is rated better with –. They perform similarly with Alkalis, Foods and beverages.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.