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Polystyrene vs PVDF: Chemical Resistance Compared

Of 502 source rows rated for both materials at 20 °C, 223 (44 %) have the same rating. Polystyrene is rated better in 28 rows and PVDF in 251. A row is one chemical at one concentration.

Summary

Polystyrene is rated better with
Alkalis (+36 points)
PVDF is rated better with
Aromatic hydrocarbons (+100 points); Fuels, mineral oils and aliphatic hydrocarbons (+73 points); Halogenated hydrocarbons (+72 points); Esters and ethers (+61 points); Ketones and aldehydes (+57 points); Phenols (+49 points); Vegetable and animal oils, fats, essential oils (+40 points); Mineral acids (+36 points); Alcohols and glycols (+34 points); Foods and beverages (+29 points); Amines and nitrogen compounds (+29 points); Organic acids (+20 points); Oxidising agents and halogens (+16 points)
Within 10 points of each other
Salts and salt solutions

Points are the difference in the share of rows rated A or B.

The two materials

Polystyrene

Polystyrene

Polystyrene is attacked by most organic solvents, including ketones, esters, aromatic and chlorinated hydrocarbons. It is used for dilute aqueous solutions.

Rated rows: 504. A 45 %, B 8 %, C 8 %, D 39 %

All chemicals for Polystyrene

PVDF

Polyvinylidene fluoride

PVDF resists acids, halogens and hydrocarbons. Strong bases, amines, ketones and esters attack it. Service temperature is up to about 150 °C.

Rated rows: 944. A 73 %, B 15 %, C 10 %, D 2 %

All chemicals for PVDF

Share of rows rated A or B, by chemical class

Polystyrene, PVDF: Share of rows rated A or B, by chemical classMineral acids: Polystyrene 51 %, PVDF 87 %. Organic acids: Polystyrene 74 %, PVDF 94 %. Alkalis: Polystyrene 100 %, PVDF 64 %. Salts and salt solutions: Polystyrene 100 %, PVDF 99 %. Oxidising agents and halogens: Polystyrene 71 %, PVDF 87 %. Alcohols and glycols: Polystyrene 64 %, PVDF 98 %. Phenols: Polystyrene 22 %, PVDF 71 %. Ketones and aldehydes: Polystyrene 5 %, PVDF 62 %. Esters and ethers: Polystyrene 3 %, PVDF 64 %. Amines and nitrogen compounds: Polystyrene 47 %, PVDF 76 %. Aromatic hydrocarbons: Polystyrene 0 %, PVDF 100 %. Fuels, mineral oils and aliphatic hydrocarbons: Polystyrene 24 %, PVDF 97 %. Vegetable and animal oils, fats, essential oils: Polystyrene 48 %, PVDF 88 %. Halogenated hydrocarbons: Polystyrene 0 %, PVDF 72 %. Foods and beverages: Polystyrene 69 %, PVDF 98 %.Mineral acidsMineral acids, Polystyrene: 51 % (41)51 %Mineral acids, PVDF: 87 % (61)87 %Organic acidsOrganic acids, Polystyrene: 74 % (34)74 %Organic acids, PVDF: 94 % (64)94 %AlkalisAlkalis, Polystyrene: 100 % (17)100 %Alkalis, PVDF: 64 % (22)64 %Salts and salt solutionsSalts and salt solutions, Polystyrene: 100 % (88)100 %Salts and salt solutions, PVDF: 99 % (198)99 %Oxidising agents and halogensOxidising agents and halogens, Polystyrene: 71 % (34)71 %Oxidising agents and halogens, PVDF: 87 % (62)87 %Alcohols and glycolsAlcohols and glycols, Polystyrene: 64 % (36)64 %Alcohols and glycols, PVDF: 98 % (58)98 %PhenolsPhenols, Polystyrene: 22 % (9)22 %Phenols, PVDF: 71 % (14)71 %Ketones and aldehydesKetones and aldehydes, Polystyrene: 5 % (21)5 %Ketones and aldehydes, PVDF: 62 % (34)62 %Esters and ethersEsters and ethers, Polystyrene: 3 % (38)3 %Esters and ethers, PVDF: 64 % (66)64 %Amines and nitrogen compoundsAmines and nitrogen compounds, Polystyrene: 47 % (15)47 %Amines and nitrogen compounds, PVDF: 76 % (38)76 %Aromatic hydrocarbonsAromatic hydrocarbons, Polystyrene: 0 % (13)0 %Aromatic hydrocarbons, PVDF: 100 % (14)100 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, Polystyrene: 24 % (38)24 %Fuels, mineral oils and aliphatic hydrocarbons, PVDF: 97 % (72)97 %Vegetable and animal oils, fats, essential oilsVegetable and animal oils, fats, essential oils, Polystyrene: 48 % (27)48 %Vegetable and animal oils, fats, essential oils, PVDF: 88 % (48)88 %Halogenated hydrocarbonsHalogenated hydrocarbons, Polystyrene: 0 % (36)0 %Halogenated hydrocarbons, PVDF: 72 % (54)72 %Foods and beveragesFoods and beverages, Polystyrene: 69 % (32)69 %Foods and beverages, PVDF: 98 % (46)98 %
PolystyrenePVDF
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

Polystyrene, PVDF: How often the two ratings agreePolystyrene A, PVDF A: 209; Polystyrene A, PVDF B: 10; Polystyrene A, PVDF C: 7; Polystyrene A, PVDF D: 3; Polystyrene B, PVDF A: 27; Polystyrene B, PVDF B: 3; Polystyrene B, PVDF C: 5; Polystyrene B, PVDF D: 3; Polystyrene C, PVDF A: 35; Polystyrene C, PVDF B: 4; Polystyrene C, PVDF C: 2; Polystyrene D, PVDF A: 98; Polystyrene D, PVDF B: 46; Polystyrene D, PVDF C: 41; Polystyrene D, PVDF D: 9.PVDFABCDPolystyreneAPolystyrene A, PVDF A: 209209Polystyrene A, PVDF B: 1010Polystyrene A, PVDF C: 77Polystyrene A, PVDF D: 33BPolystyrene B, PVDF A: 2727Polystyrene B, PVDF B: 33Polystyrene B, PVDF C: 55Polystyrene B, PVDF D: 33CPolystyrene C, PVDF A: 3535Polystyrene C, PVDF B: 44Polystyrene C, PVDF C: 22Polystyrene C, PVDF D: 00DPolystyrene D, PVDF A: 9898Polystyrene D, PVDF B: 4646Polystyrene D, PVDF C: 4141Polystyrene D, PVDF D: 99
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classPolystyrene: rated A or BPVDF: rated A or B
Mineral acids51 % (41 rows)87 % (61 rows)
Organic acids74 % (34 rows)94 % (64 rows)
Alkalis100 % (17 rows)64 % (22 rows)
Salts and salt solutions100 % (88 rows)99 % (198 rows)
Oxidising agents and halogens71 % (34 rows)87 % (62 rows)
Alcohols and glycols64 % (36 rows)98 % (58 rows)
Phenols22 % (9 rows)71 % (14 rows)
Ketones and aldehydes5 % (21 rows)62 % (34 rows)
Esters and ethers3 % (38 rows)64 % (66 rows)
Amines and nitrogen compounds47 % (15 rows)76 % (38 rows)
Aromatic hydrocarbons0 % (13 rows)100 % (14 rows)
Fuels, mineral oils and aliphatic hydrocarbons24 % (38 rows)97 % (72 rows)
Vegetable and animal oils, fats, essential oils48 % (27 rows)88 % (48 rows)
Halogenated hydrocarbons0 % (36 rows)72 % (54 rows)
Foods and beverages69 % (32 rows)98 % (46 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 192 in total, the first 40 shown.

ChemicalConcentrationPolystyrenePVDF
1,2-DibromoethaneDA
1,2-DichlorobenzeneDA
1,3-ButadieneDA
1,4-DichlorobenzeneDA
Acetic Acid90 %DA
AcetonitrileDA
AllspicegroundDA
Amyl AcetateDA
Amyl ChlorideDA
AnilineDA
BenzaldehydeDA
BenzeneDA
Benzyl AlcoholDA
Bitter Almond OilDA
BromineDA
Bromine WatersaturatedDA
BromobenzeneDA
Bromomethanetechnical gradeDA
Butanetechnical gradeDA
Butyl Acetate100 %DA
Butyl Acrylate100 %DA
Butyric AcidDA
CarawaygroundDA
Carbon DisulfideDA
Carbon TetrachlorideDA
CardamomDA
Chlorine97 %DA
Chlorine GasDA
Chlorine WaterDA
ChlorobenzeneDA
Chloroethane (Ethyl Chloride)DA
Chloroform100 %DA
Chloromethane (Methyl Chloride)technical gradeDA
CresolDA
CyclohexaneDA
Cyclohexanonetechnical gradeDA
DecahydronaphthaleneDA
Dibutyl Phthalate (DBP)DA
Dibutyl Sebacatetechnical gradeDA
Dichloroethylenetechnical gradeDA

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is Polystyrene or PVDF more chemical-resistant?

Of 502 chemicals rated for both materials at 20 °C, Polystyrene and PVDF share the same rating in 223 rows (44 %). Polystyrene is rated better in 28 rows and PVDF in 251 rows.

How do Polystyrene and PVDF compare for chemical resistance?

Based on 502 chemicals tested for both: Polystyrene is rated better with Alkalis. PVDF is rated better with Aromatic hydrocarbons, Fuels, mineral oils and aliphatic hydrocarbons, Halogenated hydrocarbons, Esters and ethers. They perform similarly with Salts and salt solutions.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.