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PP vs NBR: Chemical Resistance Compared

Of 973 source rows rated for both materials at 20 °C, 418 (43 %) have the same rating. PP is rated better in 500 rows and NBR in 55. A row is one chemical at one concentration.

Summary

PP is rated better with
Phenols (+79 points); Amines and nitrogen compounds (+66 points); Esters and ethers (+62 points); Organic acids (+60 points); Ketones and aldehydes (+60 points); Oxidising agents and halogens (+57 points); Mineral acids (+57 points); Alcohols and glycols (+48 points); Alkalis (+36 points); Salts and salt solutions (+17 points)
NBR is rated better with
Halogenated hydrocarbons (+16 points)
Within 10 points of each other
Aromatic hydrocarbons; Fuels, mineral oils and aliphatic hydrocarbons; Vegetable and animal oils, fats, essential oils; Foods and beverages

Points are the difference in the share of rows rated A or B.

The two materials

PP

Polypropylene

Polypropylene resists most acids, alkalis and salt solutions. Concentrated oxidising acids, chlorinated solvents and aromatic hydrocarbons attack it, and it turns brittle below about 0 °C.

Rated rows: 978. A 66 %, B 11 %, C 15 %, D 8 %

All chemicals for PP

NBR

Nitrile butadiene rubber

Nitrile rubber resists mineral oils and fuels. Ketones, esters, chlorinated solvents, strong oxidisers and ozone attack it.

Rated rows: 983. A 36 %, B 9 %, C 19 %, D 36 %

All chemicals for NBR

Share of rows rated A or B, by chemical class

PP, NBR: Share of rows rated A or B, by chemical classMineral acids: PP 70 %, NBR 13 %. Organic acids: PP 97 %, NBR 37 %. Alkalis: PP 100 %, NBR 64 %. Salts and salt solutions: PP 99 %, NBR 82 %. Oxidising agents and halogens: PP 72 %, NBR 15 %. Alcohols and glycols: PP 93 %, NBR 45 %. Phenols: PP 79 %, NBR 0 %. Ketones and aldehydes: PP 69 %, NBR 9 %. Esters and ethers: PP 63 %, NBR 1 %. Amines and nitrogen compounds: PP 79 %, NBR 13 %. Aromatic hydrocarbons: PP 14 %, NBR 7 %. Fuels, mineral oils and aliphatic hydrocarbons: PP 63 %, NBR 59 %. Vegetable and animal oils, fats, essential oils: PP 75 %, NBR 69 %. Halogenated hydrocarbons: PP 4 %, NBR 20 %. Foods and beverages: PP 100 %, NBR 93 %.Mineral acidsMineral acids, PP: 70 % (63)70 %Mineral acids, NBR: 13 % (63)13 %Organic acidsOrganic acids, PP: 97 % (64)97 %Organic acids, NBR: 37 % (63)37 %AlkalisAlkalis, PP: 100 % (22)100 %Alkalis, NBR: 64 % (22)64 %Salts and salt solutionsSalts and salt solutions, PP: 99 % (198)99 %Salts and salt solutions, NBR: 82 % (198)82 %Oxidising agents and halogensOxidising agents and halogens, PP: 72 % (61)72 %Oxidising agents and halogens, NBR: 15 % (62)15 %Alcohols and glycolsAlcohols and glycols, PP: 93 % (59)93 %Alcohols and glycols, NBR: 45 % (58)45 %PhenolsPhenols, PP: 79 % (14)79 %Phenols, NBR: 0 % (14)0 %Ketones and aldehydesKetones and aldehydes, PP: 69 % (35)69 %Ketones and aldehydes, NBR: 9 % (35)9 %Esters and ethersEsters and ethers, PP: 63 % (71)63 %Esters and ethers, NBR: 1 % (76)1 %Amines and nitrogen compoundsAmines and nitrogen compounds, PP: 79 % (39)79 %Amines and nitrogen compounds, NBR: 13 % (39)13 %Aromatic hydrocarbonsAromatic hydrocarbons, PP: 14 % (14)14 %Aromatic hydrocarbons, NBR: 7 % (14)7 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, PP: 63 % (78)63 %Fuels, mineral oils and aliphatic hydrocarbons, NBR: 59 % (78)59 %Vegetable and animal oils, fats, essential oilsVegetable and animal oils, fats, essential oils, PP: 75 % (48)75 %Vegetable and animal oils, fats, essential oils, NBR: 69 % (48)69 %Halogenated hydrocarbonsHalogenated hydrocarbons, PP: 4 % (70)4 %Halogenated hydrocarbons, NBR: 20 % (71)20 %Foods and beveragesFoods and beverages, PP: 100 % (46)100 %Foods and beverages, NBR: 93 % (46)93 %
PPNBR
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

PP, NBR: How often the two ratings agreePP A, NBR A: 306; PP A, NBR B: 68; PP A, NBR C: 136; PP A, NBR D: 128; PP B, NBR A: 15; PP B, NBR B: 21; PP B, NBR C: 12; PP B, NBR D: 63; PP C, NBR A: 29; PP C, NBR B: 2; PP C, NBR C: 26; PP C, NBR D: 93; PP D, NBR A: 2; PP D, NBR C: 7; PP D, NBR D: 65.NBRABCDPPAPP A, NBR A: 306306PP A, NBR B: 6868PP A, NBR C: 136136PP A, NBR D: 128128BPP B, NBR A: 1515PP B, NBR B: 2121PP B, NBR C: 1212PP B, NBR D: 6363CPP C, NBR A: 2929PP C, NBR B: 22PP C, NBR C: 2626PP C, NBR D: 9393DPP D, NBR A: 22PP D, NBR B: 00PP D, NBR C: 77PP D, NBR D: 6565
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classPP: rated A or BNBR: rated A or B
Mineral acids70 % (63 rows)13 % (63 rows)
Organic acids97 % (64 rows)37 % (63 rows)
Alkalis100 % (22 rows)64 % (22 rows)
Salts and salt solutions99 % (198 rows)82 % (198 rows)
Oxidising agents and halogens72 % (61 rows)15 % (62 rows)
Alcohols and glycols93 % (59 rows)45 % (58 rows)
Phenols79 % (14 rows)0 % (14 rows)
Ketones and aldehydes69 % (35 rows)9 % (35 rows)
Esters and ethers63 % (71 rows)1 % (76 rows)
Amines and nitrogen compounds79 % (39 rows)13 % (39 rows)
Aromatic hydrocarbons14 % (14 rows)7 % (14 rows)
Fuels, mineral oils and aliphatic hydrocarbons63 % (78 rows)59 % (78 rows)
Vegetable and animal oils, fats, essential oils75 % (48 rows)69 % (48 rows)
Halogenated hydrocarbons4 % (70 rows)20 % (71 rows)
Foods and beverages100 % (46 rows)93 % (46 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 358 in total, the first 40 shown.

ChemicalConcentrationPPNBR
Acetic Acid100 %AD
Acetic Acid50 %AD
Acetic Acid90 %AD
Acetic Anhydridetechnical gradeAD
AcetoneAD
AcetophenoneAD
Allyl Acetate100 %AD
Ammonium Carbonate50 %AD
Ammonium CarbonateaqueousAD
Ammonium Hydroxide (Ammonia Solution)AD
Ammonium PersulfatesaturatedAD
Ammonium PersulfateaqueousAD
Antimony PentachlorideAD
Battery Acid38 %AD
BenzaldehydeAD
Benzyl AcetateAD
Bisulfite Liquor with SO2saturatedAD
Bitter Almond OilAD
Brake FluidAD
Butylphenol100 %AD
Calcium HypochloriteAD
Calcium HypochloritesaturatedAD
Calcium HypochloriteaqueousAD
Calcium Nitrate50 %AD
Camphor OilDA
Chloric Acid20 %AD
Chloroacetic AcidAD
Chloroacetic Acid50 %AD
Chromic Acid10 %AD
Coal Tar Oil100 %AD
Copper(II) NitratesaturatedAD
Crotonaldehydetechnical gradeAD
Dibutyl Sebacatetechnical gradeAD
Dichloroacetic Acid50 %AD
Dichloroacetic Acidtechnical gradeAD
Dicyclohexyl Phthalatetechnical gradeAD
Diethanolamine100 %AD
Diethylaminetechnical gradeAD
Diglycolic Acid30 %AD
Diglycolic AcidaqueousAD

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is PP or NBR more chemical-resistant?

Of 973 chemicals rated for both materials at 20 °C, PP and NBR share the same rating in 418 rows (43 %). PP is rated better in 500 rows and NBR in 55 rows.

How do PP and NBR compare for chemical resistance?

Based on 973 chemicals tested for both: PP is rated better with Phenols, Amines and nitrogen compounds, Esters and ethers, Organic acids. NBR is rated better with Halogenated hydrocarbons. They perform similarly with Aromatic hydrocarbons, Fuels, mineral oils and aliphatic hydrocarbons, Vegetable and animal oils, fats, essential oils, Foods and beverages.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.