ChemicalResistance
ChemicalResistance.org

SAN vs PVDF: Chemical Resistance Compared

Of 359 source rows rated for both materials at 20 °C, 234 (65 %) have the same rating. SAN is rated better in 19 rows and PVDF in 106. A row is one chemical at one concentration.

Summary

SAN is rated better with
Alkalis (+36 points)
PVDF is rated better with
Halogenated hydrocarbons (+67 points); Esters and ethers (+64 points); Phenols (+46 points); Ketones and aldehydes (+41 points); Alcohols and glycols (+28 points); Mineral acids (+26 points); Vegetable and animal oils, fats, essential oils (+20 points); Amines and nitrogen compounds (+20 points); Fuels, mineral oils and aliphatic hydrocarbons (+18 points); Foods and beverages (+16 points); Organic acids (+15 points); Oxidising agents and halogens (+14 points)
Within 10 points of each other
Salts and salt solutions

Points are the difference in the share of rows rated A or B.

The two materials

SAN

Styrene-acrylonitrile

Styrene-acrylonitrile resists oils and dilute acids better than polystyrene, but ketones, esters and aromatic and chlorinated solvents still attack it.

Rated rows: 364. A 67 %, B 0 %, C 9 %, D 24 %

All chemicals for SAN

PVDF

Polyvinylidene fluoride

PVDF resists acids, halogens and hydrocarbons. Strong bases, amines, ketones and esters attack it. Service temperature is up to about 150 °C.

Rated rows: 944. A 73 %, B 15 %, C 10 %, D 2 %

All chemicals for PVDF

Share of rows rated A or B, by chemical class

SAN, PVDF: Share of rows rated A or B, by chemical classMineral acids: SAN 61 %, PVDF 87 %. Organic acids: SAN 79 %, PVDF 94 %. Alkalis: SAN 100 %, PVDF 64 %. Salts and salt solutions: SAN 100 %, PVDF 99 %. Oxidising agents and halogens: SAN 73 %, PVDF 87 %. Alcohols and glycols: SAN 70 %, PVDF 98 %. Phenols: SAN 25 %, PVDF 71 %. Ketones and aldehydes: SAN 21 %, PVDF 62 %. Esters and ethers: SAN 0 %, PVDF 64 %. Amines and nitrogen compounds: SAN 56 %, PVDF 76 %. Fuels, mineral oils and aliphatic hydrocarbons: SAN 79 %, PVDF 97 %. Vegetable and animal oils, fats, essential oils: SAN 68 %, PVDF 88 %. Halogenated hydrocarbons: SAN 5 %, PVDF 72 %. Foods and beverages: SAN 82 %, PVDF 98 %.Mineral acidsMineral acids, SAN: 61 % (18)61 %Mineral acids, PVDF: 87 % (61)87 %Organic acidsOrganic acids, SAN: 79 % (24)79 %Organic acids, PVDF: 94 % (64)94 %AlkalisAlkalis, SAN: 100 % (8)100 %Alkalis, PVDF: 64 % (22)64 %Salts and salt solutionsSalts and salt solutions, SAN: 100 % (80)100 %Salts and salt solutions, PVDF: 99 % (198)99 %Oxidising agents and halogensOxidising agents and halogens, SAN: 73 % (26)73 %Oxidising agents and halogens, PVDF: 87 % (62)87 %Alcohols and glycolsAlcohols and glycols, SAN: 70 % (33)70 %Alcohols and glycols, PVDF: 98 % (58)98 %PhenolsPhenols, SAN: 25 % (8)25 %Phenols, PVDF: 71 % (14)71 %Ketones and aldehydesKetones and aldehydes, SAN: 21 % (19)21 %Ketones and aldehydes, PVDF: 62 % (34)62 %Esters and ethersEsters and ethers, SAN: 0 % (19)0 %Esters and ethers, PVDF: 64 % (66)64 %Amines and nitrogen compoundsAmines and nitrogen compounds, SAN: 56 % (9)56 %Amines and nitrogen compounds, PVDF: 76 % (38)76 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, SAN: 79 % (24)79 %Fuels, mineral oils and aliphatic hydrocarbons, PVDF: 97 % (72)97 %Vegetable and animal oils, fats, essential oilsVegetable and animal oils, fats, essential oils, SAN: 68 % (22)68 %Vegetable and animal oils, fats, essential oils, PVDF: 88 % (48)88 %Halogenated hydrocarbonsHalogenated hydrocarbons, SAN: 5 % (20)5 %Halogenated hydrocarbons, PVDF: 72 % (54)72 %Foods and beveragesFoods and beverages, SAN: 82 % (22)82 %Foods and beverages, PVDF: 98 % (46)98 %
SANPVDF
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

SAN, PVDF: How often the two ratings agreeSAN A, PVDF A: 223; SAN A, PVDF B: 8; SAN A, PVDF C: 9; SAN A, PVDF D: 1; SAN B, PVDF A: 1; SAN C, PVDF A: 20; SAN C, PVDF B: 7; SAN C, PVDF C: 5; SAN C, PVDF D: 1; SAN D, PVDF A: 34; SAN D, PVDF B: 20; SAN D, PVDF C: 24; SAN D, PVDF D: 6.PVDFABCDSANASAN A, PVDF A: 223223SAN A, PVDF B: 88SAN A, PVDF C: 99SAN A, PVDF D: 11BSAN B, PVDF A: 11SAN B, PVDF B: 00SAN B, PVDF C: 00SAN B, PVDF D: 00CSAN C, PVDF A: 2020SAN C, PVDF B: 77SAN C, PVDF C: 55SAN C, PVDF D: 11DSAN D, PVDF A: 3434SAN D, PVDF B: 2020SAN D, PVDF C: 2424SAN D, PVDF D: 66
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classSAN: rated A or BPVDF: rated A or B
Mineral acids61 % (18 rows)87 % (61 rows)
Organic acids79 % (24 rows)94 % (64 rows)
Alkalis100 % (8 rows)64 % (22 rows)
Salts and salt solutions100 % (80 rows)99 % (198 rows)
Oxidising agents and halogens73 % (26 rows)87 % (62 rows)
Alcohols and glycols70 % (33 rows)98 % (58 rows)
Phenols25 % (8 rows)71 % (14 rows)
Ketones and aldehydes21 % (19 rows)62 % (34 rows)
Esters and ethers0 % (19 rows)64 % (66 rows)
Amines and nitrogen compounds56 % (9 rows)76 % (38 rows)
Aromatic hydrocarbons–100 % (14 rows)
Fuels, mineral oils and aliphatic hydrocarbons79 % (24 rows)97 % (72 rows)
Vegetable and animal oils, fats, essential oils68 % (22 rows)88 % (48 rows)
Halogenated hydrocarbons5 % (20 rows)72 % (54 rows)
Foods and beverages82 % (22 rows)98 % (46 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 84 in total, the first 40 shown.

ChemicalConcentrationSANPVDF
1,2-DichlorobenzeneDA
Acetic Acid90 %DA
Amyl AcetateDA
Benzyl AlcoholDA
BromineDA
Butyl Acetate100 %DA
Butyl Acrylate100 %DA
Butyric AcidDA
Carbon DisulfideDA
Carbon TetrachlorideDA
Chlorine97 %DA
Chlorine GasDA
ChlorobenzeneDA
Chloroethane (Ethyl Chloride)DA
Chloroform100 %DA
Chloromethane (Methyl Chloride)technical gradeDA
Cyclohexanonetechnical gradeDA
Dibutyl Sebacatetechnical gradeDA
DichloromethaneDA
Diethyl Ethertechnical gradeDA
Ethyl Glycol100 %DA
EthylbenzeneDA
Ethylene DichlorideDA
FurfuralDA
Methyl Acetatetechnical gradeDA
NitrobenzeneDA
Phenol100 %DA
Propylene OxideDA
PyridineDA
Sodium Hydroxide (Caustic Soda)45 %AD
Sulfuric Acid95 %DA
Tetrachloroethanetechnical gradeDA
TolueneDA
TrichloroethaneDA
XyleneDA
1-PentanethiolDB
Acetylene100 %CA
AllspicegroundCA
Allyl Alcohol96 %DB
Allyl Mustard OilDB

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is SAN or PVDF more chemical-resistant?

Of 359 chemicals rated for both materials at 20 °C, SAN and PVDF share the same rating in 234 rows (65 %). SAN is rated better in 19 rows and PVDF in 106 rows.

How do SAN and PVDF compare for chemical resistance?

Based on 359 chemicals tested for both: SAN is rated better with Alkalis. PVDF is rated better with Halogenated hydrocarbons, Esters and ethers, Phenols, Ketones and aldehydes. They perform similarly with Salts and salt solutions.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.