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LDPE vs PVDF: Chemical Resistance Compared

Of 674 source rows rated for both materials at 20 °C, 476 (71 %) have the same rating. LDPE is rated better in 83 rows and PVDF in 115. A row is one chemical at one concentration.

Summary

LDPE is rated better with
Alkalis (+36 points); Amines and nitrogen compounds (+19 points)
PVDF is rated better with
Aromatic hydrocarbons (+80 points); Halogenated hydrocarbons (+61 points); Fuels, mineral oils and aliphatic hydrocarbons (+31 points); Vegetable and animal oils, fats, essential oils (+25 points); Mineral acids (+16 points); Oxidising agents and halogens (+11 points)
Within 10 points of each other
Organic acids; Salts and salt solutions; Alcohols and glycols; Phenols; Ketones and aldehydes; Esters and ethers; Foods and beverages

Points are the difference in the share of rows rated A or B.

The two materials

LDPE

Low-density polyethylene

Low-density polyethylene has a similar profile to HDPE but is softer and more permeable, so solvents swell it sooner. Continuous service is usually limited to about 60 °C.

Rated rows: 678. A 78 %, B 4 %, C 11 %, D 8 %

All chemicals for LDPE

PVDF

Polyvinylidene fluoride

PVDF resists acids, halogens and hydrocarbons. Strong bases, amines, ketones and esters attack it. Service temperature is up to about 150 °C.

Rated rows: 944. A 73 %, B 15 %, C 10 %, D 2 %

All chemicals for PVDF

Share of rows rated A or B, by chemical class

LDPE, PVDF: Share of rows rated A or B, by chemical classMineral acids: LDPE 71 %, PVDF 87 %. Organic acids: LDPE 93 %, PVDF 94 %. Alkalis: LDPE 100 %, PVDF 64 %. Salts and salt solutions: LDPE 99 %, PVDF 99 %. Oxidising agents and halogens: LDPE 76 %, PVDF 87 %. Alcohols and glycols: LDPE 89 %, PVDF 98 %. Phenols: LDPE 67 %, PVDF 71 %. Ketones and aldehydes: LDPE 63 %, PVDF 62 %. Esters and ethers: LDPE 68 %, PVDF 64 %. Amines and nitrogen compounds: LDPE 95 %, PVDF 76 %. Aromatic hydrocarbons: LDPE 20 %, PVDF 100 %. Fuels, mineral oils and aliphatic hydrocarbons: LDPE 66 %, PVDF 97 %. Vegetable and animal oils, fats, essential oils: LDPE 63 %, PVDF 88 %. Halogenated hydrocarbons: LDPE 11 %, PVDF 72 %. Foods and beverages: LDPE 100 %, PVDF 98 %.Mineral acidsMineral acids, LDPE: 71 % (48)71 %Mineral acids, PVDF: 87 % (61)87 %Organic acidsOrganic acids, LDPE: 93 % (59)93 %Organic acids, PVDF: 94 % (64)94 %AlkalisAlkalis, LDPE: 100 % (22)100 %Alkalis, PVDF: 64 % (22)64 %Salts and salt solutionsSalts and salt solutions, LDPE: 99 % (187)99 %Salts and salt solutions, PVDF: 99 % (198)99 %Oxidising agents and halogensOxidising agents and halogens, LDPE: 76 % (38)76 %Oxidising agents and halogens, PVDF: 87 % (62)87 %Alcohols and glycolsAlcohols and glycols, LDPE: 89 % (46)89 %Alcohols and glycols, PVDF: 98 % (58)98 %PhenolsPhenols, LDPE: 67 % (9)67 %Phenols, PVDF: 71 % (14)71 %Ketones and aldehydesKetones and aldehydes, LDPE: 63 % (19)63 %Ketones and aldehydes, PVDF: 62 % (34)62 %Esters and ethersEsters and ethers, LDPE: 68 % (41)68 %Esters and ethers, PVDF: 64 % (66)64 %Amines and nitrogen compoundsAmines and nitrogen compounds, LDPE: 95 % (19)95 %Amines and nitrogen compounds, PVDF: 76 % (38)76 %Aromatic hydrocarbonsAromatic hydrocarbons, LDPE: 20 % (10)20 %Aromatic hydrocarbons, PVDF: 100 % (14)100 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, LDPE: 66 % (41)66 %Fuels, mineral oils and aliphatic hydrocarbons, PVDF: 97 % (72)97 %Vegetable and animal oils, fats, essential oilsVegetable and animal oils, fats, essential oils, LDPE: 63 % (19)63 %Vegetable and animal oils, fats, essential oils, PVDF: 88 % (48)88 %Halogenated hydrocarbonsHalogenated hydrocarbons, LDPE: 11 % (36)11 %Halogenated hydrocarbons, PVDF: 72 % (54)72 %Foods and beveragesFoods and beverages, LDPE: 100 % (30)100 %Foods and beverages, PVDF: 98 % (46)98 %
LDPEPVDF
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

LDPE, PVDF: How often the two ratings agreeLDPE A, PVDF A: 450; LDPE A, PVDF B: 40; LDPE A, PVDF C: 24; LDPE A, PVDF D: 9; LDPE B, PVDF A: 14; LDPE B, PVDF B: 4; LDPE B, PVDF C: 6; LDPE B, PVDF D: 2; LDPE C, PVDF A: 46; LDPE C, PVDF B: 10; LDPE C, PVDF C: 16; LDPE C, PVDF D: 2; LDPE D, PVDF A: 27; LDPE D, PVDF B: 6; LDPE D, PVDF C: 12; LDPE D, PVDF D: 6.PVDFABCDLDPEALDPE A, PVDF A: 450450LDPE A, PVDF B: 4040LDPE A, PVDF C: 2424LDPE A, PVDF D: 99BLDPE B, PVDF A: 1414LDPE B, PVDF B: 44LDPE B, PVDF C: 66LDPE B, PVDF D: 22CLDPE C, PVDF A: 4646LDPE C, PVDF B: 1010LDPE C, PVDF C: 1616LDPE C, PVDF D: 22DLDPE D, PVDF A: 2727LDPE D, PVDF B: 66LDPE D, PVDF C: 1212LDPE D, PVDF D: 66
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classLDPE: rated A or BPVDF: rated A or B
Mineral acids71 % (48 rows)87 % (61 rows)
Organic acids93 % (59 rows)94 % (64 rows)
Alkalis100 % (22 rows)64 % (22 rows)
Salts and salt solutions99 % (187 rows)99 % (198 rows)
Oxidising agents and halogens76 % (38 rows)87 % (62 rows)
Alcohols and glycols89 % (46 rows)98 % (58 rows)
Phenols67 % (9 rows)71 % (14 rows)
Ketones and aldehydes63 % (19 rows)62 % (34 rows)
Esters and ethers68 % (41 rows)64 % (66 rows)
Amines and nitrogen compounds95 % (19 rows)76 % (38 rows)
Aromatic hydrocarbons20 % (10 rows)100 % (14 rows)
Fuels, mineral oils and aliphatic hydrocarbons66 % (41 rows)97 % (72 rows)
Vegetable and animal oils, fats, essential oils63 % (19 rows)88 % (48 rows)
Halogenated hydrocarbons11 % (36 rows)72 % (54 rows)
Foods and beverages100 % (30 rows)98 % (46 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 114 in total, the first 40 shown.

ChemicalConcentrationLDPEPVDF
1,2-DibromoethaneDA
1,3-ButadieneDA
Amyl ChlorideDA
Benzyl AlcoholDA
BromineDA
Bromine VaporsDA
Bromine WatersaturatedDA
BromobenzeneDA
Bromomethanetechnical gradeDA
Butyric AcidDA
Carbon DisulfideDA
Carbon TetrachlorideDA
Chlorine97 %DA
Chlorine GasDA
Chloroacetic AcidAD
Chloroform100 %DA
CresolDA
Dichloroethylenetechnical gradeDA
DichloromethaneDA
Diethyl Ethertechnical gradeDA
Dimethylformamide (DMF)AD
Ethyl Glycol100 %DA
n-HexaneDA
NitrobenzeneDA
Perchloroethylene (PCE)DA
PropanegaseousDA
Sodium Hydroxide (Caustic Soda)1 %AD
Sodium Hydroxide (Caustic Soda)30 %AD
Sodium Hydroxide (Caustic Soda)45 %AD
Sodium Hydroxide (Caustic Soda)50 %AD
Sodium Hydroxide (Caustic Soda)60 %AD
Sodium Hydroxide (Caustic Soda)concentratedAD
Tetrahydronaphthalenetechnical gradeDA
Trichloroacetaldehyde100 %AD
TrichloroethaneDA
Trichloroethylene (TCE)100 %DA
1,2-DichlorobenzeneCA
1,4-DichlorobenzeneCA
Acetaldehyde40 %BD
Acetaldehydetechnical gradeBD

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is LDPE or PVDF more chemical-resistant?

Of 674 chemicals rated for both materials at 20 °C, LDPE and PVDF share the same rating in 476 rows (71 %). LDPE is rated better in 83 rows and PVDF in 115 rows.

How do LDPE and PVDF compare for chemical resistance?

Based on 674 chemicals tested for both: LDPE is rated better with Alkalis, Amines and nitrogen compounds. PVDF is rated better with Aromatic hydrocarbons, Halogenated hydrocarbons, Fuels, mineral oils and aliphatic hydrocarbons, Vegetable and animal oils, fats, essential oils. They perform similarly with Organic acids, Salts and salt solutions, Alcohols and glycols, Phenols.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.