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Dichloromethane Chemical Resistance

Resistance ratings for 24 plastics, elastomers and metals at 20 °C and 50 °C.

At a glance

Ratings at 20 °C.

Rated A, very good resistance
PTFE, PVDF, SS 316, SS 304, Aluminium, FEP (6)
Rated B, good resistance
ECTFE/ETFE (1)
Rated C, limited resistance
PP, Viton (FPM), Nylon (PA), Acetal (POM), PMP (5)
Rated D, not resistant
HDPE, PVC Rigid, EPDM, NBR, LDPE, Polycarbonate, PVC Flexible, Polystyrene, Polysulfone, PETG, SAN (11)
No data in the source
Silicone
Rated lower at 50 °C than at 20 °C
PP (C → D), PVDF (A → C), Nylon (PA) (C → D), PMP (C → D)
Risk of pitting or stress-corrosion cracking
SS 316, SS 304

Rating profile by material family

Dichloromethane: Rating profile by material familyThermoplastics: 4 C, 9 D. Fluoropolymers: 3 A, 1 B. Elastomers: 1 C, 2 D, 1 no data. Metals: 3 A.Thermoplastics (13)Thermoplastics: 4 × C, limited resistance (PP, PMP, Acetal (POM), Nylon (PA))C 4Thermoplastics: 9 × D, not resistant (HDPE, LDPE, PVC Rigid, PVC Flexible, Polystyrene, SAN, Polycarbonate, PETG, Polysulfone)D 9Fluoropolymers (4)Fluoropolymers: 3 × A, very good resistance (PTFE, FEP, PVDF)A 3Fluoropolymers: 1 × B, good resistance (ECTFE/ETFE)B 1Elastomers (4)Elastomers: 1 × C, limited resistance (Viton (FPM))C 1Elastomers: 2 × D, not resistant (EPDM, NBR)D 2Elastomers: 1 × no data (Silicone)– 1Metals (3)Metals: 3 × A, very good resistance (SS 316, SS 304, Aluminium)A 3
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Number of materials in each family with each rating at 20 °C.

Effect of temperature, 20 °C to 50 °C

Dichloromethane: Effect of temperature, 20 °C to 50 °CPP C → D; PMP C → D; Nylon (PA) C → D; PVDF A → C.ABCDPP: C at 20 °C, D at 50 °CPPPMP: C at 20 °C, D at 50 °CPMPNylon (PA): C at 20 °C, D at 50 °CNylon (PA)PVDF: A at 20 °C, C at 50 °CPVDF
20 °C50 °C
Materials whose rating differs between 20 °C and 50 °C. Materials not shown keep their rating or have no 50 °C value.

Substance

CAS number
75-09-2
Formula
CH2Cl2
Hazard symbols in the source
Xn (harmful) (pre-GHS European symbols; check the current safety data sheet)
Also listed as
Methylen(di)chloride
Name in the source (German)
Dichlormethan

Resistance table

Material20 °C50 °CRemark
Thermoplastics
HDPEDD
LDPEDD
PPCD
PVC RigidDD
PVC FlexibleDD
PMPCD
PolystyreneDD
SANDD
PolycarbonateDD
PETGDD
Acetal (POM)C–
Nylon (PA)CD
PolysulfoneDD
Fluoropolymers
PTFEAA
FEPAA
PVDFAC
ECTFE/ETFEBB
Elastomers
EPDMDD
Viton (FPM)CC
NBRDD
Metals
SS 316AApitting risk
SS 304AApitting risk
AluminiumA–disputed, see below

Not rated in the source, so not in the table: Silicone

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

Corrected and disputed values

Source values use the scale 1 (very good) to 4 (not resistant); 1 = A, 4 = D.

Frequently Asked Questions

Which materials resist Dichloromethane at high concentrations?

The materials with an A rating (resistant) for Dichloromethane at 20 °C are: PTFE, PVDF, SS 316, SS 304, Aluminium, FEP. These can generally be used in direct contact.

Which materials should be avoided with Dichloromethane?

Materials rated D (not resistant) for Dichloromethane are: HDPE, PVC Rigid, EPDM, NBR, LDPE, Polycarbonate, PVC Flexible, Polystyrene. These should not be used in contact with Dichloromethane.

Does temperature affect chemical resistance to Dichloromethane?

Yes. 4 of 21 tested materials show a worse rating at 50 °C than at 20 °C for Dichloromethane. Materials affected include: PP, PVDF, Nylon (PA), PMP.

Is PTFE safe for Dichloromethane?

PTFE is rated A for Dichloromethane at 20 °C. A rating of A means resistant, B means limited resistance, C means partly resistant, and D means not resistant.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.

Chemicals with a similar resistance profile

Same 20 °C rating on the share of materials shown.