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Dioxane Chemical Resistance

Resistance ratings for 24 plastics, elastomers and metals at 20 °C and 50 °C.

At a glance

Ratings at 20 °C.

Rated A, very good resistance
PTFE, SS 316, SS 304, Aluminium, FEP, ECTFE/ETFE, Nylon (PA), Acetal (POM), PETG (9)
Rated B, good resistance
HDPE, EPDM, LDPE, Polysulfone, PMP (5)
Rated C, limited resistance
PP, PVDF, PVC Rigid (3)
Rated D, not resistant
Viton (FPM), NBR, Polycarbonate, PVC Flexible, Polystyrene, SAN (6)
No data in the source
Silicone
Rated lower at 50 °C than at 20 °C
PVC Rigid (C → D), LDPE (B → C), ECTFE/ETFE (A → C), Acetal (POM) (A → B), Polysulfone (B → C), PMP (B → C)

Rating profile by material family

Dioxane: Rating profile by material familyThermoplastics: 3 A, 4 B, 2 C, 4 D. Fluoropolymers: 3 A, 1 C. Elastomers: 1 B, 2 D, 1 no data. Metals: 3 A.Thermoplastics (13)Thermoplastics: 3 × A, very good resistance (PETG, Acetal (POM), Nylon (PA))A 3Thermoplastics: 4 × B, good resistance (HDPE, LDPE, PMP, Polysulfone)B 4Thermoplastics: 2 × C, limited resistance (PP, PVC Rigid)C 2Thermoplastics: 4 × D, not resistant (PVC Flexible, Polystyrene, SAN, Polycarbonate)D 4Fluoropolymers (4)Fluoropolymers: 3 × A, very good resistance (PTFE, FEP, ECTFE/ETFE)A 3Fluoropolymers: 1 × C, limited resistance (PVDF)C 1Elastomers (4)Elastomers: 1 × B, good resistance (EPDM)B 1Elastomers: 2 × D, not resistant (Viton (FPM), NBR)D 2Elastomers: 1 × no data (Silicone)– 1Metals (3)Metals: 3 × A, very good resistance (SS 316, SS 304, Aluminium)A 3
A very good resistanceB good resistanceC limited resistanceD not resistantno data
Number of materials in each family with each rating at 20 °C.

Effect of temperature, 20 °C to 50 °C

Dioxane: Effect of temperature, 20 °C to 50 °CLDPE B → C; PVC Rigid C → D; PMP B → C; Acetal (POM) A → B; Polysulfone B → C; ECTFE/ETFE A → C.ABCDLDPE: B at 20 °C, C at 50 °CLDPEPVC Rigid: C at 20 °C, D at 50 °CPVC RigidPMP: B at 20 °C, C at 50 °CPMPAcetal (POM): A at 20 °C, B at 50 °CAcetal (POM)Polysulfone: B at 20 °C, C at 50 °CPolysulfoneECTFE/ETFE: A at 20 °C, C at 50 °CECTFE/ETFE
20 °C50 °C
Materials whose rating differs between 20 °C and 50 °C. Materials not shown keep their rating or have no 50 °C value.

Substance

CAS number
123-91-1
Formula
C4H8O2
Hazard symbols in the source
F (flammable), Xn (harmful) (pre-GHS European symbols; check the current safety data sheet)
Flammable
yes
Also listed as
1,4-Dioxane
Name in the source (German)
Dioxan

Resistance table

Material20 °C50 °CRemark
Thermoplastics
HDPEBB
LDPEBC
PPCC
PVC RigidCD
PVC FlexibleDD
PMPBC
PolystyreneDD
SANDD
PolycarbonateDD
PETGA–
Acetal (POM)AB
Nylon (PA)A–
PolysulfoneBC
Fluoropolymers
PTFEAA
FEPAA
PVDFCC
ECTFE/ETFEAC
Elastomers
EPDMB–
Viton (FPM)DD
NBRDD
Metals
SS 316A–
SS 304A–
AluminiumAA

Not rated in the source, so not in the table: Silicone

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

Frequently Asked Questions

Which materials resist Dioxane at high concentrations?

The materials with an A rating (resistant) for Dioxane at 20 °C are: PTFE, SS 316, SS 304, Aluminium, FEP, ECTFE/ETFE, Nylon (PA), Acetal (POM). These can generally be used in direct contact.

Which materials should be avoided with Dioxane?

Materials rated D (not resistant) for Dioxane are: Viton (FPM), NBR, Polycarbonate, PVC Flexible, Polystyrene, SAN. These should not be used in contact with Dioxane.

Does temperature affect chemical resistance to Dioxane?

Yes. 6 of 18 tested materials show a worse rating at 50 °C than at 20 °C for Dioxane. Materials affected include: PVC Rigid, LDPE, ECTFE/ETFE, Acetal (POM), Polysulfone, PMP.

Is PTFE safe for Dioxane?

PTFE is rated A for Dioxane at 20 °C. A rating of A means resistant, B means limited resistance, C means partly resistant, and D means not resistant.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.

Chemicals with a similar resistance profile

Same 20 °C rating on the share of materials shown.