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LDPE vs PVC Rigid: Chemical Resistance Compared

Of 504 source rows rated for both materials at 20 °C, 327 (65 %) have the same rating. LDPE is rated better in 134 rows and PVC Rigid in 43. A row is one chemical at one concentration.

Summary

LDPE is rated better with
Amines and nitrogen compounds (+72 points); Esters and ethers (+63 points); Ketones and aldehydes (+52 points); Phenols (+29 points); Aromatic hydrocarbons (+20 points)
PVC Rigid is rated better with
Fuels, mineral oils and aliphatic hydrocarbons (+18 points); Mineral acids (+11 points)
Within 10 points of each other
Organic acids; Alkalis; Salts and salt solutions; Oxidising agents and halogens; Alcohols and glycols; Vegetable and animal oils, fats, essential oils; Halogenated hydrocarbons; Foods and beverages

Points are the difference in the share of rows rated A or B.

The two materials

LDPE

Low-density polyethylene

Low-density polyethylene has a similar profile to HDPE but is softer and more permeable, so solvents swell it sooner. Continuous service is usually limited to about 60 °C.

Rated rows: 678. A 78 %, B 4 %, C 11 %, D 8 %

All chemicals for LDPE

PVC Rigid

Rigid (unplasticised) polyvinyl chloride

Rigid PVC resists acids, alkalis and salt solutions well. Ketones, esters, aromatic and chlorinated solvents dissolve or swell it. Service temperature is limited to about 60 °C.

Rated rows: 569. A 62 %, B 8 %, C 9 %, D 21 %

All chemicals for PVC Rigid

Share of rows rated A or B, by chemical class

LDPE, PVC Rigid: Share of rows rated A or B, by chemical classMineral acids: LDPE 71 %, PVC Rigid 82 %. Organic acids: LDPE 93 %, PVC Rigid 87 %. Alkalis: LDPE 100 %, PVC Rigid 100 %. Salts and salt solutions: LDPE 99 %, PVC Rigid 100 %. Oxidising agents and halogens: LDPE 76 %, PVC Rigid 85 %. Alcohols and glycols: LDPE 89 %, PVC Rigid 79 %. Phenols: LDPE 67 %, PVC Rigid 38 %. Ketones and aldehydes: LDPE 63 %, PVC Rigid 11 %. Esters and ethers: LDPE 68 %, PVC Rigid 5 %. Amines and nitrogen compounds: LDPE 95 %, PVC Rigid 23 %. Aromatic hydrocarbons: LDPE 20 %, PVC Rigid 0 %. Fuels, mineral oils and aliphatic hydrocarbons: LDPE 66 %, PVC Rigid 84 %. Vegetable and animal oils, fats, essential oils: LDPE 63 %, PVC Rigid 59 %. Halogenated hydrocarbons: LDPE 11 %, PVC Rigid 8 %. Foods and beverages: LDPE 100 %, PVC Rigid 100 %.Mineral acidsMineral acids, LDPE: 71 % (48)71 %Mineral acids, PVC Rigid: 82 % (56)82 %Organic acidsOrganic acids, LDPE: 93 % (59)93 %Organic acids, PVC Rigid: 87 % (45)87 %AlkalisAlkalis, LDPE: 100 % (22)100 %Alkalis, PVC Rigid: 100 % (16)100 %Salts and salt solutionsSalts and salt solutions, LDPE: 99 % (187)99 %Salts and salt solutions, PVC Rigid: 100 % (111)100 %Oxidising agents and halogensOxidising agents and halogens, LDPE: 76 % (38)76 %Oxidising agents and halogens, PVC Rigid: 85 % (39)85 %Alcohols and glycolsAlcohols and glycols, LDPE: 89 % (46)89 %Alcohols and glycols, PVC Rigid: 79 % (43)79 %PhenolsPhenols, LDPE: 67 % (9)67 %Phenols, PVC Rigid: 38 % (8)38 %Ketones and aldehydesKetones and aldehydes, LDPE: 63 % (19)63 %Ketones and aldehydes, PVC Rigid: 11 % (18)11 %Esters and ethersEsters and ethers, LDPE: 68 % (41)68 %Esters and ethers, PVC Rigid: 5 % (39)5 %Amines and nitrogen compoundsAmines and nitrogen compounds, LDPE: 95 % (19)95 %Amines and nitrogen compounds, PVC Rigid: 23 % (22)23 %Aromatic hydrocarbonsAromatic hydrocarbons, LDPE: 20 % (10)20 %Aromatic hydrocarbons, PVC Rigid: 0 % (9)0 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, LDPE: 66 % (41)66 %Fuels, mineral oils and aliphatic hydrocarbons, PVC Rigid: 84 % (38)84 %Vegetable and animal oils, fats, essential oilsVegetable and animal oils, fats, essential oils, LDPE: 63 % (19)63 %Vegetable and animal oils, fats, essential oils, PVC Rigid: 59 % (17)59 %Halogenated hydrocarbonsHalogenated hydrocarbons, LDPE: 11 % (36)11 %Halogenated hydrocarbons, PVC Rigid: 8 % (36)8 %Foods and beveragesFoods and beverages, LDPE: 100 % (30)100 %Foods and beverages, PVC Rigid: 100 % (23)100 %
LDPEPVC Rigid
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

LDPE, PVC Rigid: How often the two ratings agreeLDPE A, PVC Rigid A: 282; LDPE A, PVC Rigid B: 28; LDPE A, PVC Rigid C: 25; LDPE A, PVC Rigid D: 33; LDPE B, PVC Rigid A: 8; LDPE B, PVC Rigid B: 1; LDPE B, PVC Rigid C: 5; LDPE B, PVC Rigid D: 12; LDPE C, PVC Rigid A: 14; LDPE C, PVC Rigid B: 10; LDPE C, PVC Rigid C: 8; LDPE C, PVC Rigid D: 31; LDPE D, PVC Rigid A: 2; LDPE D, PVC Rigid B: 4; LDPE D, PVC Rigid C: 5; LDPE D, PVC Rigid D: 36.PVC RigidABCDLDPEALDPE A, PVC Rigid A: 282282LDPE A, PVC Rigid B: 2828LDPE A, PVC Rigid C: 2525LDPE A, PVC Rigid D: 3333BLDPE B, PVC Rigid A: 88LDPE B, PVC Rigid B: 11LDPE B, PVC Rigid C: 55LDPE B, PVC Rigid D: 1212CLDPE C, PVC Rigid A: 1414LDPE C, PVC Rigid B: 1010LDPE C, PVC Rigid C: 88LDPE C, PVC Rigid D: 3131DLDPE D, PVC Rigid A: 22LDPE D, PVC Rigid B: 44LDPE D, PVC Rigid C: 55LDPE D, PVC Rigid D: 3636
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classLDPE: rated A or BPVC Rigid: rated A or B
Mineral acids71 % (48 rows)82 % (56 rows)
Organic acids93 % (59 rows)87 % (45 rows)
Alkalis100 % (22 rows)100 % (16 rows)
Salts and salt solutions99 % (187 rows)100 % (111 rows)
Oxidising agents and halogens76 % (38 rows)85 % (39 rows)
Alcohols and glycols89 % (46 rows)79 % (43 rows)
Phenols67 % (9 rows)38 % (8 rows)
Ketones and aldehydes63 % (19 rows)11 % (18 rows)
Esters and ethers68 % (41 rows)5 % (39 rows)
Amines and nitrogen compounds95 % (19 rows)23 % (22 rows)
Aromatic hydrocarbons20 % (10 rows)0 % (9 rows)
Fuels, mineral oils and aliphatic hydrocarbons66 % (41 rows)84 % (38 rows)
Vegetable and animal oils, fats, essential oils63 % (19 rows)59 % (17 rows)
Halogenated hydrocarbons11 % (36 rows)8 % (36 rows)
Foods and beverages100 % (30 rows)100 % (23 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 90 in total, the first 40 shown.

ChemicalConcentrationLDPEPVC Rigid
AcetamidesaturatedAD
AcetonitrileAD
AcetophenoneAD
AcrylonitrileAD
AlanineAD
AnilineAD
Benzyl AcetateAD
Butyl Glycol100 %AD
CarbazoleAD
Dibutyl Ethertechnical gradeAD
Dibutyl Sebacatetechnical gradeAD
Diisobutyl Ketonetechnical gradeAD
Dimethyl Phthalate (DMP)100 %AD
Dimethyl Sulfoxide (DMSO)AD
Epichlorohydrin100 %AD
FluorineDA
Formamidetechnical gradeAD
Furfuryl Alcoholtechnical gradeAD
Iodine TinctureAD
Methoxyethyl OleateAD
Methyl Acetatetechnical gradeAD
Morpholinetechnical gradeAD
Naphthalene100 %AD
Nitrotoluenetechnical gradeAD
p-ChloroacetophenoneAD
Phosphorus OxychlorideAD
Phosphorus Oxychloride100 %AD
Phosphorus PentachlorideAD
PropanegaseousDA
Propionic AcidAD
Tributyl Phosphatetechnical gradeAD
Trichloroacetaldehyde100 %AD
Tricresyl Phosphate (TCP)technical gradeAD
Trioctyl Phosphatetechnical gradeAD
Vinyl Acetatetechnical gradeAD
Acetaldehyde40 %BD
Acetaldehydetechnical gradeBD
Amyl AcetateBD
Benzyl AlcoholDB
BromineDB

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is LDPE or PVC Rigid more chemical-resistant?

Of 504 chemicals rated for both materials at 20 °C, LDPE and PVC Rigid share the same rating in 327 rows (65 %). LDPE is rated better in 134 rows and PVC Rigid in 43 rows.

How do LDPE and PVC Rigid compare for chemical resistance?

Based on 504 chemicals tested for both: LDPE is rated better with Amines and nitrogen compounds, Esters and ethers, Ketones and aldehydes, Phenols. PVC Rigid is rated better with Fuels, mineral oils and aliphatic hydrocarbons, Mineral acids. They perform similarly with Organic acids, Alkalis, Salts and salt solutions, Oxidising agents and halogens.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.