ChemicalResistance
ChemicalResistance.org

LDPE vs FEP: Chemical Resistance Compared

Of 653 source rows rated for both materials at 20 °C, 515 (79 %) have the same rating. LDPE is rated better in 0 rows and FEP in 138. A row is one chemical at one concentration.

Summary

FEP is rated better with
Aromatic hydrocarbons (+80 points); Halogenated hydrocarbons (+79 points); Vegetable and animal oils, fats, essential oils (+37 points); Ketones and aldehydes (+37 points); Fuels, mineral oils and aliphatic hydrocarbons (+34 points); Phenols (+33 points); Esters and ethers (+32 points); Mineral acids (+29 points); Oxidising agents and halogens (+24 points); Alcohols and glycols (+11 points)
Within 10 points of each other
Organic acids; Alkalis; Salts and salt solutions; Amines and nitrogen compounds; Foods and beverages

Points are the difference in the share of rows rated A or B.

The two materials

LDPE

Low-density polyethylene

Low-density polyethylene has a similar profile to HDPE but is softer and more permeable, so solvents swell it sooner. Continuous service is usually limited to about 60 °C.

Rated rows: 678. A 78 %, B 4 %, C 11 %, D 8 %

All chemicals for LDPE

FEP

Fluorinated ethylene propylene

FEP has nearly the chemical resistance of PTFE and can be melt-processed. Its service temperature, about 200 °C, is lower than that of PTFE.

Rated rows: 908. A 99 %, B 0 %, C 1 %, D 0 %

All chemicals for FEP

Share of rows rated A or B, by chemical class

LDPE, FEP: Share of rows rated A or B, by chemical classMineral acids: LDPE 71 %, FEP 100 %. Organic acids: LDPE 93 %, FEP 100 %. Alkalis: LDPE 100 %, FEP 100 %. Salts and salt solutions: LDPE 99 %, FEP 100 %. Oxidising agents and halogens: LDPE 76 %, FEP 100 %. Alcohols and glycols: LDPE 89 %, FEP 100 %. Phenols: LDPE 67 %, FEP 100 %. Ketones and aldehydes: LDPE 63 %, FEP 100 %. Esters and ethers: LDPE 68 %, FEP 100 %. Amines and nitrogen compounds: LDPE 95 %, FEP 100 %. Aromatic hydrocarbons: LDPE 20 %, FEP 100 %. Fuels, mineral oils and aliphatic hydrocarbons: LDPE 66 %, FEP 100 %. Vegetable and animal oils, fats, essential oils: LDPE 63 %, FEP 100 %. Halogenated hydrocarbons: LDPE 11 %, FEP 90 %. Foods and beverages: LDPE 100 %, FEP 100 %.Mineral acidsMineral acids, LDPE: 71 % (48)71 %Mineral acids, FEP: 100 % (55)100 %Organic acidsOrganic acids, LDPE: 93 % (59)93 %Organic acids, FEP: 100 % (64)100 %AlkalisAlkalis, LDPE: 100 % (22)100 %Alkalis, FEP: 100 % (18)100 %Salts and salt solutionsSalts and salt solutions, LDPE: 99 % (187)99 %Salts and salt solutions, FEP: 100 % (197)100 %Oxidising agents and halogensOxidising agents and halogens, LDPE: 76 % (38)76 %Oxidising agents and halogens, FEP: 100 % (52)100 %Alcohols and glycolsAlcohols and glycols, LDPE: 89 % (46)89 %Alcohols and glycols, FEP: 100 % (57)100 %PhenolsPhenols, LDPE: 67 % (9)67 %Phenols, FEP: 100 % (14)100 %Ketones and aldehydesKetones and aldehydes, LDPE: 63 % (19)63 %Ketones and aldehydes, FEP: 100 % (33)100 %Esters and ethersEsters and ethers, LDPE: 68 % (41)68 %Esters and ethers, FEP: 100 % (69)100 %Amines and nitrogen compoundsAmines and nitrogen compounds, LDPE: 95 % (19)95 %Amines and nitrogen compounds, FEP: 100 % (38)100 %Aromatic hydrocarbonsAromatic hydrocarbons, LDPE: 20 % (10)20 %Aromatic hydrocarbons, FEP: 100 % (14)100 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, LDPE: 66 % (41)66 %Fuels, mineral oils and aliphatic hydrocarbons, FEP: 100 % (74)100 %Vegetable and animal oils, fats, essential oilsVegetable and animal oils, fats, essential oils, LDPE: 63 % (19)63 %Vegetable and animal oils, fats, essential oils, FEP: 100 % (47)100 %Halogenated hydrocarbonsHalogenated hydrocarbons, LDPE: 11 % (36)11 %Halogenated hydrocarbons, FEP: 90 % (49)90 %Foods and beveragesFoods and beverages, LDPE: 100 % (30)100 %Foods and beverages, FEP: 100 % (46)100 %
LDPEFEP
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

LDPE, FEP: How often the two ratings agreeLDPE A, FEP A: 511; LDPE B, FEP A: 26; LDPE C, FEP A: 66; LDPE C, FEP C: 4; LDPE D, FEP A: 44; LDPE D, FEP B: 2.FEPABCDLDPEALDPE A, FEP A: 511511LDPE A, FEP B: 00LDPE A, FEP C: 00LDPE A, FEP D: 00BLDPE B, FEP A: 2626LDPE B, FEP B: 00LDPE B, FEP C: 00LDPE B, FEP D: 00CLDPE C, FEP A: 6666LDPE C, FEP B: 00LDPE C, FEP C: 44LDPE C, FEP D: 00DLDPE D, FEP A: 4444LDPE D, FEP B: 22LDPE D, FEP C: 00LDPE D, FEP D: 00
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classLDPE: rated A or BFEP: rated A or B
Mineral acids71 % (48 rows)100 % (55 rows)
Organic acids93 % (59 rows)100 % (64 rows)
Alkalis100 % (22 rows)100 % (18 rows)
Salts and salt solutions99 % (187 rows)100 % (197 rows)
Oxidising agents and halogens76 % (38 rows)100 % (52 rows)
Alcohols and glycols89 % (46 rows)100 % (57 rows)
Phenols67 % (9 rows)100 % (14 rows)
Ketones and aldehydes63 % (19 rows)100 % (33 rows)
Esters and ethers68 % (41 rows)100 % (69 rows)
Amines and nitrogen compounds95 % (19 rows)100 % (38 rows)
Aromatic hydrocarbons20 % (10 rows)100 % (14 rows)
Fuels, mineral oils and aliphatic hydrocarbons66 % (41 rows)100 % (74 rows)
Vegetable and animal oils, fats, essential oils63 % (19 rows)100 % (47 rows)
Halogenated hydrocarbons11 % (36 rows)90 % (49 rows)
Foods and beverages100 % (30 rows)100 % (46 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 112 in total, the first 40 shown.

ChemicalConcentrationLDPEFEP
1,2-DibromoethaneDA
1,3-ButadieneDA
Amyl ChlorideDA
Benzyl AlcoholDA
Benzyl Chloride100 %DA
BromineDA
Bromine VaporsDA
BromobenzeneDA
Bromochloromethane100 %DA
BromoformDA
Bromomethanetechnical gradeDA
Butyric AcidDA
Camphor OilDA
Carbon DisulfideDA
Carbon TetrachlorideDA
Cedar OilDA
Chlorine97 %DA
Chlorine GasDA
Chloroform100 %DA
Cinnamon OilDA
CresolDA
Dichloroethylenetechnical gradeDA
Dichloroisopropyl EtherDA
DichloromethaneDA
Diethyl Ethertechnical gradeDA
DiethylbenzeneDA
Diisooctyl Phthalate (DOP)technical gradeDA
Ethyl Acrylate100 %DA
Ethyl Glycol100 %DA
FluorineDA
n-HexaneDA
NitrobenzeneDA
Oleum (Fuming Sulfuric Acid)10 % SO3DA
Perchloroethylene (PCE)DA
PropanegaseousDA
Sulfur DioxideliquidDA
Sulfuric AcidfumingDA
Tetrahydrofuran (THF)DA
Tetrahydronaphthalenetechnical gradeDA
Thionyl Chloridetechnical gradeDA

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is LDPE or FEP more chemical-resistant?

Of 653 chemicals rated for both materials at 20 °C, LDPE and FEP share the same rating in 515 rows (79 %). LDPE is rated better in 0 rows and FEP in 138 rows.

How do LDPE and FEP compare for chemical resistance?

Based on 653 chemicals tested for both: LDPE is rated better with –. FEP is rated better with Aromatic hydrocarbons, Halogenated hydrocarbons, Vegetable and animal oils, fats, essential oils, Ketones and aldehydes. They perform similarly with Organic acids, Alkalis, Salts and salt solutions, Amines and nitrogen compounds.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.