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LDPE vs PMP: Chemical Resistance Compared

Of 349 source rows rated for both materials at 20 °C, 269 (77 %) have the same rating. LDPE is rated better in 46 rows and PMP in 34. A row is one chemical at one concentration.

Summary

LDPE is rated better with
Amines and nitrogen compounds (+45 points); Fuels, mineral oils and aliphatic hydrocarbons (+36 points); Vegetable and animal oils, fats, essential oils (+34 points); Esters and ethers (+32 points); Ketones and aldehydes (+26 points)
Within 10 points of each other
Mineral acids; Organic acids; Alkalis; Salts and salt solutions; Oxidising agents and halogens; Alcohols and glycols; Aromatic hydrocarbons; Halogenated hydrocarbons; Foods and beverages

Points are the difference in the share of rows rated A or B.

The two materials

LDPE

Low-density polyethylene

Low-density polyethylene has a similar profile to HDPE but is softer and more permeable, so solvents swell it sooner. Continuous service is usually limited to about 60 °C.

Rated rows: 678. A 78 %, B 4 %, C 11 %, D 8 %

All chemicals for LDPE

PMP

Polymethylpentene (TPX)

Polymethylpentene (TPX) is a transparent polyolefin used for labware. It resists many acids and alkalis, while aromatic and chlorinated solvents and strong oxidisers attack it.

Rated rows: 416. A 55 %, B 6 %, C 7 %, D 32 %

All chemicals for PMP

Share of rows rated A or B, by chemical class

LDPE, PMP: Share of rows rated A or B, by chemical classMineral acids: LDPE 71 %, PMP 71 %. Organic acids: LDPE 93 %, PMP 85 %. Alkalis: LDPE 100 %, PMP 100 %. Salts and salt solutions: LDPE 99 %, PMP 100 %. Oxidising agents and halogens: LDPE 76 %, PMP 67 %. Alcohols and glycols: LDPE 89 %, PMP 96 %. Ketones and aldehydes: LDPE 63 %, PMP 37 %. Esters and ethers: LDPE 68 %, PMP 36 %. Amines and nitrogen compounds: LDPE 95 %, PMP 50 %. Aromatic hydrocarbons: LDPE 20 %, PMP 10 %. Fuels, mineral oils and aliphatic hydrocarbons: LDPE 66 %, PMP 30 %. Vegetable and animal oils, fats, essential oils: LDPE 63 %, PMP 29 %. Halogenated hydrocarbons: LDPE 11 %, PMP 3 %. Foods and beverages: LDPE 100 %, PMP 100 %.Mineral acidsMineral acids, LDPE: 71 % (48)71 %Mineral acids, PMP: 71 % (35)71 %Organic acidsOrganic acids, LDPE: 93 % (59)93 %Organic acids, PMP: 85 % (26)85 %AlkalisAlkalis, LDPE: 100 % (22)100 %Alkalis, PMP: 100 % (17)100 %Salts and salt solutionsSalts and salt solutions, LDPE: 99 % (187)99 %Salts and salt solutions, PMP: 100 % (67)100 %Oxidising agents and halogensOxidising agents and halogens, LDPE: 76 % (38)76 %Oxidising agents and halogens, PMP: 67 % (30)67 %Alcohols and glycolsAlcohols and glycols, LDPE: 89 % (46)89 %Alcohols and glycols, PMP: 96 % (28)96 %Ketones and aldehydesKetones and aldehydes, LDPE: 63 % (19)63 %Ketones and aldehydes, PMP: 37 % (27)37 %Esters and ethersEsters and ethers, LDPE: 68 % (41)68 %Esters and ethers, PMP: 36 % (42)36 %Amines and nitrogen compoundsAmines and nitrogen compounds, LDPE: 95 % (19)95 %Amines and nitrogen compounds, PMP: 50 % (10)50 %Aromatic hydrocarbonsAromatic hydrocarbons, LDPE: 20 % (10)20 %Aromatic hydrocarbons, PMP: 10 % (10)10 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, LDPE: 66 % (41)66 %Fuels, mineral oils and aliphatic hydrocarbons, PMP: 30 % (37)30 %Vegetable and animal oils, fats, essential oilsVegetable and animal oils, fats, essential oils, LDPE: 63 % (19)63 %Vegetable and animal oils, fats, essential oils, PMP: 29 % (14)29 %Halogenated hydrocarbonsHalogenated hydrocarbons, LDPE: 11 % (36)11 %Halogenated hydrocarbons, PMP: 3 % (33)3 %Foods and beveragesFoods and beverages, LDPE: 100 % (30)100 %Foods and beverages, PMP: 100 % (13)100 %
LDPEPMP
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

LDPE, PMP: How often the two ratings agreeLDPE A, PMP A: 211; LDPE A, PMP B: 2; LDPE A, PMP C: 5; LDPE A, PMP D: 16; LDPE B, PMP A: 6; LDPE B, PMP B: 9; LDPE B, PMP C: 4; LDPE B, PMP D: 2; LDPE C, PMP A: 7; LDPE C, PMP B: 15; LDPE C, PMP C: 10; LDPE C, PMP D: 17; LDPE D, PMP A: 1; LDPE D, PMP C: 5; LDPE D, PMP D: 39.PMPABCDLDPEALDPE A, PMP A: 211211LDPE A, PMP B: 22LDPE A, PMP C: 55LDPE A, PMP D: 1616BLDPE B, PMP A: 66LDPE B, PMP B: 99LDPE B, PMP C: 44LDPE B, PMP D: 22CLDPE C, PMP A: 77LDPE C, PMP B: 1515LDPE C, PMP C: 1010LDPE C, PMP D: 1717DLDPE D, PMP A: 11LDPE D, PMP B: 00LDPE D, PMP C: 55LDPE D, PMP D: 3939
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classLDPE: rated A or BPMP: rated A or B
Mineral acids71 % (48 rows)71 % (35 rows)
Organic acids93 % (59 rows)85 % (26 rows)
Alkalis100 % (22 rows)100 % (17 rows)
Salts and salt solutions99 % (187 rows)100 % (67 rows)
Oxidising agents and halogens76 % (38 rows)67 % (30 rows)
Alcohols and glycols89 % (46 rows)96 % (28 rows)
Phenols67 % (9 rows)–
Ketones and aldehydes63 % (19 rows)37 % (27 rows)
Esters and ethers68 % (41 rows)36 % (42 rows)
Amines and nitrogen compounds95 % (19 rows)50 % (10 rows)
Aromatic hydrocarbons20 % (10 rows)10 % (10 rows)
Fuels, mineral oils and aliphatic hydrocarbons66 % (41 rows)30 % (37 rows)
Vegetable and animal oils, fats, essential oils63 % (19 rows)29 % (14 rows)
Halogenated hydrocarbons11 % (36 rows)3 % (33 rows)
Foods and beverages100 % (30 rows)100 % (13 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 31 in total.

ChemicalConcentrationLDPEPMP
AcetophenoneAD
Allyl Acetate100 %AD
Dibutyl Ethertechnical gradeAD
Diisobutyl Ketonetechnical gradeAD
Diisooctyl Phthalate (DOP)technical gradeDA
Epichlorohydrin100 %AD
Ethyl Chloroacetatetechnical gradeAD
Hydrobromic Acid40 %AD
Hydrobromic Acid50 %AD
Hydrobromic AciddiluteAD
Hydrocyanic Acid (Hydrogen Cyanide)aqueousAD
Isooctanetechnical gradeAD
Methyl Acetatetechnical gradeAD
Nitrotoluenetechnical gradeAD
Tetraethyl Leadtechnical gradeAD
Vinyl Acetatetechnical gradeAD
White SpiritAD
Acetic Acid10 %AC
AcetonitrileAC
AcrylonitrileAC
Allyl Alcohol96 %CA
BenzaldehydeCA
Bitter Almond OilCA
Butylphenol100 %AC
Ethylene DichlorideBD
NaphthaCA
OzoneCA
PentaneAC
Phenol100 %CA
Transformer OilCA
White SpiritliquidBD

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is LDPE or PMP more chemical-resistant?

Of 349 chemicals rated for both materials at 20 °C, LDPE and PMP share the same rating in 269 rows (77 %). LDPE is rated better in 46 rows and PMP in 34 rows.

How do LDPE and PMP compare for chemical resistance?

Based on 349 chemicals tested for both: LDPE is rated better with Amines and nitrogen compounds, Fuels, mineral oils and aliphatic hydrocarbons, Vegetable and animal oils, fats, essential oils, Esters and ethers. PMP is rated better with –. They perform similarly with Mineral acids, Organic acids, Alkalis, Salts and salt solutions.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.