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PTFE vs PVDF: Chemical Resistance Compared

Of 941 source rows rated for both materials at 20 °C, 686 (73 %) have the same rating. PTFE is rated better in 254 rows and PVDF in 1. A row is one chemical at one concentration.

Summary

PTFE is rated better with
Ketones and aldehydes (+38 points); Esters and ethers (+36 points); Alkalis (+36 points); Phenols (+29 points); Halogenated hydrocarbons (+28 points); Amines and nitrogen compounds (+24 points); Oxidising agents and halogens (+13 points); Mineral acids (+13 points); Vegetable and animal oils, fats, essential oils (+12 points)
Within 10 points of each other
Organic acids; Salts and salt solutions; Alcohols and glycols; Aromatic hydrocarbons; Fuels, mineral oils and aliphatic hydrocarbons; Foods and beverages

Points are the difference in the share of rows rated A or B.

The two materials

PTFE

Polytetrafluoroethylene

PTFE is resistant to almost every chemical in this list. The known exceptions are molten alkali metals, elemental fluorine and some fluorinating agents at elevated temperature.

Rated rows: 981. A 98 %, B 2 %, C 0 %, D 0 %

All chemicals for PTFE

PVDF

Polyvinylidene fluoride

PVDF resists acids, halogens and hydrocarbons. Strong bases, amines, ketones and esters attack it. Service temperature is up to about 150 °C.

Rated rows: 944. A 73 %, B 15 %, C 10 %, D 2 %

All chemicals for PVDF

Share of rows rated A or B, by chemical class

PTFE, PVDF: Share of rows rated A or B, by chemical classMineral acids: PTFE 100 %, PVDF 87 %. Organic acids: PTFE 100 %, PVDF 94 %. Alkalis: PTFE 100 %, PVDF 64 %. Salts and salt solutions: PTFE 100 %, PVDF 99 %. Oxidising agents and halogens: PTFE 100 %, PVDF 87 %. Alcohols and glycols: PTFE 100 %, PVDF 98 %. Phenols: PTFE 100 %, PVDF 71 %. Ketones and aldehydes: PTFE 100 %, PVDF 62 %. Esters and ethers: PTFE 100 %, PVDF 64 %. Amines and nitrogen compounds: PTFE 100 %, PVDF 76 %. Aromatic hydrocarbons: PTFE 100 %, PVDF 100 %. Fuels, mineral oils and aliphatic hydrocarbons: PTFE 100 %, PVDF 97 %. Vegetable and animal oils, fats, essential oils: PTFE 100 %, PVDF 88 %. Halogenated hydrocarbons: PTFE 100 %, PVDF 72 %. Foods and beverages: PTFE 100 %, PVDF 98 %.Mineral acidsMineral acids, PTFE: 100 % (63)100 %Mineral acids, PVDF: 87 % (61)87 %Organic acidsOrganic acids, PTFE: 100 % (64)100 %Organic acids, PVDF: 94 % (64)94 %AlkalisAlkalis, PTFE: 100 % (22)100 %Alkalis, PVDF: 64 % (22)64 %Salts and salt solutionsSalts and salt solutions, PTFE: 100 % (198)100 %Salts and salt solutions, PVDF: 99 % (198)99 %Oxidising agents and halogensOxidising agents and halogens, PTFE: 100 % (63)100 %Oxidising agents and halogens, PVDF: 87 % (62)87 %Alcohols and glycolsAlcohols and glycols, PTFE: 100 % (58)100 %Alcohols and glycols, PVDF: 98 % (58)98 %PhenolsPhenols, PTFE: 100 % (14)100 %Phenols, PVDF: 71 % (14)71 %Ketones and aldehydesKetones and aldehydes, PTFE: 100 % (35)100 %Ketones and aldehydes, PVDF: 62 % (34)62 %Esters and ethersEsters and ethers, PTFE: 100 % (74)100 %Esters and ethers, PVDF: 64 % (66)64 %Amines and nitrogen compoundsAmines and nitrogen compounds, PTFE: 100 % (39)100 %Amines and nitrogen compounds, PVDF: 76 % (38)76 %Aromatic hydrocarbonsAromatic hydrocarbons, PTFE: 100 % (14)100 %Aromatic hydrocarbons, PVDF: 100 % (14)100 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, PTFE: 100 % (78)100 %Fuels, mineral oils and aliphatic hydrocarbons, PVDF: 97 % (72)97 %Vegetable and animal oils, fats, essential oilsVegetable and animal oils, fats, essential oils, PTFE: 100 % (48)100 %Vegetable and animal oils, fats, essential oils, PVDF: 88 % (48)88 %Halogenated hydrocarbonsHalogenated hydrocarbons, PTFE: 100 % (70)100 %Halogenated hydrocarbons, PVDF: 72 % (54)72 %Foods and beveragesFoods and beverages, PTFE: 100 % (46)100 %Foods and beverages, PVDF: 98 % (46)98 %
PTFEPVDF
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

PTFE, PVDF: How often the two ratings agreePTFE A, PVDF A: 684; PTFE A, PVDF B: 143; PTFE A, PVDF C: 83; PTFE A, PVDF D: 18; PTFE B, PVDF A: 1; PTFE B, PVDF B: 2; PTFE B, PVDF C: 9; PTFE B, PVDF D: 1.PVDFABCDPTFEAPTFE A, PVDF A: 684684PTFE A, PVDF B: 143143PTFE A, PVDF C: 8383PTFE A, PVDF D: 1818BPTFE B, PVDF A: 11PTFE B, PVDF B: 22PTFE B, PVDF C: 99PTFE B, PVDF D: 11CPTFE C, PVDF A: 00PTFE C, PVDF B: 00PTFE C, PVDF C: 00PTFE C, PVDF D: 00DPTFE D, PVDF A: 00PTFE D, PVDF B: 00PTFE D, PVDF C: 00PTFE D, PVDF D: 00
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classPTFE: rated A or BPVDF: rated A or B
Mineral acids100 % (63 rows)87 % (61 rows)
Organic acids100 % (64 rows)94 % (64 rows)
Alkalis100 % (22 rows)64 % (22 rows)
Salts and salt solutions100 % (198 rows)99 % (198 rows)
Oxidising agents and halogens100 % (63 rows)87 % (62 rows)
Alcohols and glycols100 % (58 rows)98 % (58 rows)
Phenols100 % (14 rows)71 % (14 rows)
Ketones and aldehydes100 % (35 rows)62 % (34 rows)
Esters and ethers100 % (74 rows)64 % (66 rows)
Amines and nitrogen compounds100 % (39 rows)76 % (38 rows)
Aromatic hydrocarbons100 % (14 rows)100 % (14 rows)
Fuels, mineral oils and aliphatic hydrocarbons100 % (78 rows)97 % (72 rows)
Vegetable and animal oils, fats, essential oils100 % (48 rows)88 % (48 rows)
Halogenated hydrocarbons100 % (70 rows)72 % (54 rows)
Foods and beverages100 % (46 rows)98 % (46 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 102 in total, the first 40 shown.

ChemicalConcentrationPTFEPVDF
Acetaldehyde40 %AD
Acetaldehydetechnical gradeAD
Acetic Anhydridetechnical gradeAD
Chloral Hydratetechnical gradeAD
Chloroacetic AcidAD
Chromic-Sulfuric AcidconcentratedAD
Dimethylformamide (DMF)AD
FluorineAD
Nitric Acid100 %AD
Oleum (Fuming Sulfuric Acid)10 % SO3AD
Sodium Hydroxide (Caustic Soda)1 %AD
Sodium Hydroxide (Caustic Soda)30 %AD
Sodium Hydroxide (Caustic Soda)45 %AD
Sodium Hydroxide (Caustic Soda)50 %AD
Sodium Hydroxide (Caustic Soda)60 %AD
Sodium Hydroxide (Caustic Soda)concentratedAD
Sulfur DioxideliquidAD
Sulfuric AcidfumingAD
5-HydroxymethylfurfuralAC
AcetoneAC
AcrylonitrileAC
Anise OilAC
Anisole100 %AC
Aqua RegiaAC
Benzyl AcetateAC
Benzyl Chloride100 %AC
Brake FluidAC
Bromochloromethane100 %AC
CamphorAC
Chloramine-TdiluteAC
Chlorine TrifluorideBD
ChlorodifluoromethaneAC
Chlorofluorocarbons (CFCs)AC
Chlorosulfonic Acidtechnical gradeAC
CreosoteAC
Dichlorodifluoromethane (R-12)AC
Dichlorodifluoromethane (R-12)technical gradeAC
Dichlorofluoromethane100 %AC
Dichloroisopropyl EtherAC
Diethyl KetoneAC

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.