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HDPE vs PMP: Chemical Resistance Compared

Of 344 source rows rated for both materials at 20 °C, 256 (74 %) have the same rating. HDPE is rated better in 71 rows and PMP in 17. A row is one chemical at one concentration.

Summary

HDPE is rated better with
Fuels, mineral oils and aliphatic hydrocarbons (+49 points); Ketones and aldehydes (+47 points); Vegetable and animal oils, fats, essential oils (+42 points); Amines and nitrogen compounds (+40 points); Esters and ethers (+37 points); Aromatic hydrocarbons (+23 points); Oxidising agents and halogens (+11 points)
Within 10 points of each other
Mineral acids; Organic acids; Alkalis; Salts and salt solutions; Alcohols and glycols; Halogenated hydrocarbons; Foods and beverages

Points are the difference in the share of rows rated A or B.

The two materials

HDPE

High-density polyethylene

High-density polyethylene resists most aqueous acids, alkalis and salt solutions. Strong oxidising acids, chlorinated solvents and aromatic hydrocarbons attack or swell it. Continuous service is usually limited to about 80 °C.

Rated rows: 686. A 82 %, B 3 %, C 9 %, D 6 %

All chemicals for HDPE

PMP

Polymethylpentene (TPX)

Polymethylpentene (TPX) is a transparent polyolefin used for labware. It resists many acids and alkalis, while aromatic and chlorinated solvents and strong oxidisers attack it.

Rated rows: 416. A 55 %, B 6 %, C 7 %, D 32 %

All chemicals for PMP

Share of rows rated A or B, by chemical class

HDPE, PMP: Share of rows rated A or B, by chemical classMineral acids: HDPE 79 %, PMP 71 %. Organic acids: HDPE 95 %, PMP 85 %. Alkalis: HDPE 100 %, PMP 100 %. Salts and salt solutions: HDPE 100 %, PMP 100 %. Oxidising agents and halogens: HDPE 78 %, PMP 67 %. Alcohols and glycols: HDPE 93 %, PMP 96 %. Ketones and aldehydes: HDPE 84 %, PMP 37 %. Esters and ethers: HDPE 73 %, PMP 36 %. Amines and nitrogen compounds: HDPE 90 %, PMP 50 %. Aromatic hydrocarbons: HDPE 33 %, PMP 10 %. Fuels, mineral oils and aliphatic hydrocarbons: HDPE 79 %, PMP 30 %. Vegetable and animal oils, fats, essential oils: HDPE 71 %, PMP 29 %. Halogenated hydrocarbons: HDPE 10 %, PMP 3 %. Foods and beverages: HDPE 100 %, PMP 100 %.Mineral acidsMineral acids, HDPE: 79 % (56)79 %Mineral acids, PMP: 71 % (35)71 %Organic acidsOrganic acids, HDPE: 95 % (58)95 %Organic acids, PMP: 85 % (26)85 %AlkalisAlkalis, HDPE: 100 % (22)100 %Alkalis, PMP: 100 % (17)100 %Salts and salt solutionsSalts and salt solutions, HDPE: 100 % (193)100 %Salts and salt solutions, PMP: 100 % (67)100 %Oxidising agents and halogensOxidising agents and halogens, HDPE: 78 % (40)78 %Oxidising agents and halogens, PMP: 67 % (30)67 %Alcohols and glycolsAlcohols and glycols, HDPE: 93 % (43)93 %Alcohols and glycols, PMP: 96 % (28)96 %Ketones and aldehydesKetones and aldehydes, HDPE: 84 % (19)84 %Ketones and aldehydes, PMP: 37 % (27)37 %Esters and ethersEsters and ethers, HDPE: 73 % (37)73 %Esters and ethers, PMP: 36 % (42)36 %Amines and nitrogen compoundsAmines and nitrogen compounds, HDPE: 90 % (21)90 %Amines and nitrogen compounds, PMP: 50 % (10)50 %Aromatic hydrocarbonsAromatic hydrocarbons, HDPE: 33 % (9)33 %Aromatic hydrocarbons, PMP: 10 % (10)10 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, HDPE: 79 % (38)79 %Fuels, mineral oils and aliphatic hydrocarbons, PMP: 30 % (37)30 %Vegetable and animal oils, fats, essential oilsVegetable and animal oils, fats, essential oils, HDPE: 71 % (21)71 %Vegetable and animal oils, fats, essential oils, PMP: 29 % (14)29 %Halogenated hydrocarbonsHalogenated hydrocarbons, HDPE: 10 % (31)10 %Halogenated hydrocarbons, PMP: 3 % (33)3 %Foods and beveragesFoods and beverages, HDPE: 100 % (32)100 %Foods and beverages, PMP: 100 % (13)100 %
HDPEPMP
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

HDPE, PMP: How often the two ratings agreeHDPE A, PMP A: 216; HDPE A, PMP B: 9; HDPE A, PMP C: 7; HDPE A, PMP D: 18; HDPE B, PMP A: 5; HDPE B, PMP B: 10; HDPE B, PMP C: 8; HDPE B, PMP D: 1; HDPE C, PMP A: 1; HDPE C, PMP B: 7; HDPE C, PMP C: 6; HDPE C, PMP D: 28; HDPE D, PMP A: 1; HDPE D, PMP C: 3; HDPE D, PMP D: 24.PMPABCDHDPEAHDPE A, PMP A: 216216HDPE A, PMP B: 99HDPE A, PMP C: 77HDPE A, PMP D: 1818BHDPE B, PMP A: 55HDPE B, PMP B: 1010HDPE B, PMP C: 88HDPE B, PMP D: 11CHDPE C, PMP A: 11HDPE C, PMP B: 77HDPE C, PMP C: 66HDPE C, PMP D: 2828DHDPE D, PMP A: 11HDPE D, PMP B: 00HDPE D, PMP C: 33HDPE D, PMP D: 2424
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classHDPE: rated A or BPMP: rated A or B
Mineral acids79 % (56 rows)71 % (35 rows)
Organic acids95 % (58 rows)85 % (26 rows)
Alkalis100 % (22 rows)100 % (17 rows)
Salts and salt solutions100 % (193 rows)100 % (67 rows)
Oxidising agents and halogens78 % (40 rows)67 % (30 rows)
Alcohols and glycols93 % (43 rows)96 % (28 rows)
Phenols62 % (8 rows)–
Ketones and aldehydes84 % (19 rows)37 % (27 rows)
Esters and ethers73 % (37 rows)36 % (42 rows)
Amines and nitrogen compounds90 % (21 rows)50 % (10 rows)
Aromatic hydrocarbons33 % (9 rows)10 % (10 rows)
Fuels, mineral oils and aliphatic hydrocarbons79 % (38 rows)30 % (37 rows)
Vegetable and animal oils, fats, essential oils71 % (21 rows)29 % (14 rows)
Halogenated hydrocarbons10 % (31 rows)3 % (33 rows)
Foods and beverages100 % (32 rows)100 % (13 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 28 in total.

ChemicalConcentrationHDPEPMP
Crotonaldehydetechnical gradeAD
DecahydronaphthaleneAD
Diisobutyl Ketonetechnical gradeAD
Diisooctyl Phthalate (DOP)technical gradeDA
Epichlorohydrin100 %AD
Ethyl Acetate100 %AD
Ethyl Chloroacetatetechnical gradeAD
Hydrobromic Acid40 %AD
Hydrobromic Acid50 %AD
Hydrobromic AciddiluteAD
Hydrocyanic Acid (Hydrogen Cyanide)aqueousAD
Isooctanetechnical gradeAD
Methyl Acetatetechnical gradeAD
Methyl Chloroacetatetechnical gradeAD
Methyl DichloroacetateAD
Methyl Ethyl Ketone (MEK)AD
Nitrotoluenetechnical gradeAD
Tetraethyl Leadtechnical gradeAD
White SpiritAD
Acetic Acid10 %AC
AcetonitrileAC
AcrylonitrileAC
CumeneBD
Cyclohexanonetechnical gradeAC
Methyl Isobutyl Ketone (MIBK)AC
Methyl Propyl Ketone (2-Pentanone)AC
OzoneCA
PentaneAC

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is HDPE or PMP more chemical-resistant?

Of 344 chemicals rated for both materials at 20 °C, HDPE and PMP share the same rating in 256 rows (74 %). HDPE is rated better in 71 rows and PMP in 17 rows.

How do HDPE and PMP compare for chemical resistance?

Based on 344 chemicals tested for both: HDPE is rated better with Fuels, mineral oils and aliphatic hydrocarbons, Ketones and aldehydes, Vegetable and animal oils, fats, essential oils, Amines and nitrogen compounds. PMP is rated better with –. They perform similarly with Mineral acids, Organic acids, Alkalis, Salts and salt solutions.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.