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HDPE vs PVC Rigid: Chemical Resistance Compared

Of 525 source rows rated for both materials at 20 °C, 351 (67 %) have the same rating. HDPE is rated better in 146 rows and PVC Rigid in 28. A row is one chemical at one concentration.

Summary

HDPE is rated better with
Ketones and aldehydes (+73 points); Esters and ethers (+68 points); Amines and nitrogen compounds (+67 points); Aromatic hydrocarbons (+33 points); Phenols (+24 points); Alcohols and glycols (+14 points); Vegetable and animal oils, fats, essential oils (+12 points)
Within 10 points of each other
Mineral acids; Organic acids; Alkalis; Salts and salt solutions; Oxidising agents and halogens; Fuels, mineral oils and aliphatic hydrocarbons; Halogenated hydrocarbons; Foods and beverages

Points are the difference in the share of rows rated A or B.

The two materials

HDPE

High-density polyethylene

High-density polyethylene resists most aqueous acids, alkalis and salt solutions. Strong oxidising acids, chlorinated solvents and aromatic hydrocarbons attack or swell it. Continuous service is usually limited to about 80 °C.

Rated rows: 686. A 82 %, B 3 %, C 9 %, D 6 %

All chemicals for HDPE

PVC Rigid

Rigid (unplasticised) polyvinyl chloride

Rigid PVC resists acids, alkalis and salt solutions well. Ketones, esters, aromatic and chlorinated solvents dissolve or swell it. Service temperature is limited to about 60 °C.

Rated rows: 569. A 62 %, B 8 %, C 9 %, D 21 %

All chemicals for PVC Rigid

Share of rows rated A or B, by chemical class

HDPE, PVC Rigid: Share of rows rated A or B, by chemical classMineral acids: HDPE 79 %, PVC Rigid 82 %. Organic acids: HDPE 95 %, PVC Rigid 87 %. Alkalis: HDPE 100 %, PVC Rigid 100 %. Salts and salt solutions: HDPE 100 %, PVC Rigid 100 %. Oxidising agents and halogens: HDPE 78 %, PVC Rigid 85 %. Alcohols and glycols: HDPE 93 %, PVC Rigid 79 %. Phenols: HDPE 62 %, PVC Rigid 38 %. Ketones and aldehydes: HDPE 84 %, PVC Rigid 11 %. Esters and ethers: HDPE 73 %, PVC Rigid 5 %. Amines and nitrogen compounds: HDPE 90 %, PVC Rigid 23 %. Aromatic hydrocarbons: HDPE 33 %, PVC Rigid 0 %. Fuels, mineral oils and aliphatic hydrocarbons: HDPE 79 %, PVC Rigid 84 %. Vegetable and animal oils, fats, essential oils: HDPE 71 %, PVC Rigid 59 %. Halogenated hydrocarbons: HDPE 10 %, PVC Rigid 8 %. Foods and beverages: HDPE 100 %, PVC Rigid 100 %.Mineral acidsMineral acids, HDPE: 79 % (56)79 %Mineral acids, PVC Rigid: 82 % (56)82 %Organic acidsOrganic acids, HDPE: 95 % (58)95 %Organic acids, PVC Rigid: 87 % (45)87 %AlkalisAlkalis, HDPE: 100 % (22)100 %Alkalis, PVC Rigid: 100 % (16)100 %Salts and salt solutionsSalts and salt solutions, HDPE: 100 % (193)100 %Salts and salt solutions, PVC Rigid: 100 % (111)100 %Oxidising agents and halogensOxidising agents and halogens, HDPE: 78 % (40)78 %Oxidising agents and halogens, PVC Rigid: 85 % (39)85 %Alcohols and glycolsAlcohols and glycols, HDPE: 93 % (43)93 %Alcohols and glycols, PVC Rigid: 79 % (43)79 %PhenolsPhenols, HDPE: 62 % (8)62 %Phenols, PVC Rigid: 38 % (8)38 %Ketones and aldehydesKetones and aldehydes, HDPE: 84 % (19)84 %Ketones and aldehydes, PVC Rigid: 11 % (18)11 %Esters and ethersEsters and ethers, HDPE: 73 % (37)73 %Esters and ethers, PVC Rigid: 5 % (39)5 %Amines and nitrogen compoundsAmines and nitrogen compounds, HDPE: 90 % (21)90 %Amines and nitrogen compounds, PVC Rigid: 23 % (22)23 %Aromatic hydrocarbonsAromatic hydrocarbons, HDPE: 33 % (9)33 %Aromatic hydrocarbons, PVC Rigid: 0 % (9)0 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, HDPE: 79 % (38)79 %Fuels, mineral oils and aliphatic hydrocarbons, PVC Rigid: 84 % (38)84 %Vegetable and animal oils, fats, essential oilsVegetable and animal oils, fats, essential oils, HDPE: 71 % (21)71 %Vegetable and animal oils, fats, essential oils, PVC Rigid: 59 % (17)59 %Halogenated hydrocarbonsHalogenated hydrocarbons, HDPE: 10 % (31)10 %Halogenated hydrocarbons, PVC Rigid: 8 % (36)8 %Foods and beveragesFoods and beverages, HDPE: 100 % (32)100 %Foods and beverages, PVC Rigid: 100 % (23)100 %
HDPEPVC Rigid
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

HDPE, PVC Rigid: How often the two ratings agreeHDPE A, PVC Rigid A: 313; HDPE A, PVC Rigid B: 30; HDPE A, PVC Rigid C: 28; HDPE A, PVC Rigid D: 40; HDPE B, PVC Rigid A: 5; HDPE B, PVC Rigid B: 5; HDPE B, PVC Rigid C: 6; HDPE B, PVC Rigid D: 8; HDPE C, PVC Rigid A: 9; HDPE C, PVC Rigid B: 4; HDPE C, PVC Rigid C: 8; HDPE C, PVC Rigid D: 34; HDPE D, PVC Rigid A: 3; HDPE D, PVC Rigid B: 3; HDPE D, PVC Rigid C: 4; HDPE D, PVC Rigid D: 25.PVC RigidABCDHDPEAHDPE A, PVC Rigid A: 313313HDPE A, PVC Rigid B: 3030HDPE A, PVC Rigid C: 2828HDPE A, PVC Rigid D: 4040BHDPE B, PVC Rigid A: 55HDPE B, PVC Rigid B: 55HDPE B, PVC Rigid C: 66HDPE B, PVC Rigid D: 88CHDPE C, PVC Rigid A: 99HDPE C, PVC Rigid B: 44HDPE C, PVC Rigid C: 88HDPE C, PVC Rigid D: 3434DHDPE D, PVC Rigid A: 33HDPE D, PVC Rigid B: 33HDPE D, PVC Rigid C: 44HDPE D, PVC Rigid D: 2525
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classHDPE: rated A or BPVC Rigid: rated A or B
Mineral acids79 % (56 rows)82 % (56 rows)
Organic acids95 % (58 rows)87 % (45 rows)
Alkalis100 % (22 rows)100 % (16 rows)
Salts and salt solutions100 % (193 rows)100 % (111 rows)
Oxidising agents and halogens78 % (40 rows)85 % (39 rows)
Alcohols and glycols93 % (43 rows)79 % (43 rows)
Phenols62 % (8 rows)38 % (8 rows)
Ketones and aldehydes84 % (19 rows)11 % (18 rows)
Esters and ethers73 % (37 rows)5 % (39 rows)
Amines and nitrogen compounds90 % (21 rows)23 % (22 rows)
Aromatic hydrocarbons33 % (9 rows)0 % (9 rows)
Fuels, mineral oils and aliphatic hydrocarbons79 % (38 rows)84 % (38 rows)
Vegetable and animal oils, fats, essential oils71 % (21 rows)59 % (17 rows)
Halogenated hydrocarbons10 % (31 rows)8 % (36 rows)
Foods and beverages100 % (32 rows)100 % (23 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 91 in total, the first 40 shown.

ChemicalConcentrationHDPEPVC Rigid
AcetamidesaturatedAD
AcetoneAD
AcetonitrileAD
AcrylonitrileAD
AlanineAD
Amyl AcetateAD
AnilineAD
BenzaldehydeAD
Benzyl AcetateAD
Bitter Almond OilAD
Butenetechnical gradeDA
Butyl Acrylate100 %AD
CarbazoleAD
Chloroethanoltechnical gradeAD
Crotonaldehydetechnical gradeAD
Cyclohexanonetechnical gradeAD
Dibutyl Phthalate (DBP)AD
Dibutyl Sebacatetechnical gradeAD
Diisobutyl Ketonetechnical gradeAD
Dimethyl Sulfoxide (DMSO)AD
Epichlorohydrin100 %AD
Ethyl Acetate100 %AD
FluorineDA
Formamidetechnical gradeAD
Furfuryl Alcoholtechnical gradeAD
Iodine TinctureAD
Methyl Isobutyl Ketone (MIBK)AD
Isopropyl AcetateAD
Methoxyethyl OleateAD
Methyl Acetatetechnical gradeAD
Methyl DichloroacetateAD
Methyl Ethyl Ketone (MEK)AD
Methyl Propyl Ketone (2-Pentanone)AD
Morpholinetechnical gradeAD
Nitrotoluenetechnical gradeAD
Oleum Vaporslow concentrationDA
p-ChloroacetophenoneAD
Propionic AcidAD
PyridineAD
Tributyl Phosphatetechnical gradeAD

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is HDPE or PVC Rigid more chemical-resistant?

Of 525 chemicals rated for both materials at 20 °C, HDPE and PVC Rigid share the same rating in 351 rows (67 %). HDPE is rated better in 146 rows and PVC Rigid in 28 rows.

How do HDPE and PVC Rigid compare for chemical resistance?

Based on 525 chemicals tested for both: HDPE is rated better with Ketones and aldehydes, Esters and ethers, Amines and nitrogen compounds, Aromatic hydrocarbons. PVC Rigid is rated better with –. They perform similarly with Mineral acids, Organic acids, Alkalis, Salts and salt solutions.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.