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HDPE vs FEP: Chemical Resistance Compared

Of 667 source rows rated for both materials at 20 °C, 548 (82 %) have the same rating. HDPE is rated better in 2 rows and FEP in 117. A row is one chemical at one concentration.

Summary

FEP is rated better with
Halogenated hydrocarbons (+80 points); Aromatic hydrocarbons (+67 points); Phenols (+38 points); Vegetable and animal oils, fats, essential oils (+29 points); Esters and ethers (+27 points); Oxidising agents and halogens (+22 points); Mineral acids (+21 points); Fuels, mineral oils and aliphatic hydrocarbons (+21 points); Ketones and aldehydes (+16 points)
Within 10 points of each other
Organic acids; Alkalis; Salts and salt solutions; Alcohols and glycols; Amines and nitrogen compounds; Foods and beverages

Points are the difference in the share of rows rated A or B.

The two materials

HDPE

High-density polyethylene

High-density polyethylene resists most aqueous acids, alkalis and salt solutions. Strong oxidising acids, chlorinated solvents and aromatic hydrocarbons attack or swell it. Continuous service is usually limited to about 80 °C.

Rated rows: 686. A 82 %, B 3 %, C 9 %, D 6 %

All chemicals for HDPE

FEP

Fluorinated ethylene propylene

FEP has nearly the chemical resistance of PTFE and can be melt-processed. Its service temperature, about 200 °C, is lower than that of PTFE.

Rated rows: 908. A 99 %, B 0 %, C 1 %, D 0 %

All chemicals for FEP

Share of rows rated A or B, by chemical class

HDPE, FEP: Share of rows rated A or B, by chemical classMineral acids: HDPE 79 %, FEP 100 %. Organic acids: HDPE 95 %, FEP 100 %. Alkalis: HDPE 100 %, FEP 100 %. Salts and salt solutions: HDPE 100 %, FEP 100 %. Oxidising agents and halogens: HDPE 78 %, FEP 100 %. Alcohols and glycols: HDPE 93 %, FEP 100 %. Phenols: HDPE 62 %, FEP 100 %. Ketones and aldehydes: HDPE 84 %, FEP 100 %. Esters and ethers: HDPE 73 %, FEP 100 %. Amines and nitrogen compounds: HDPE 90 %, FEP 100 %. Aromatic hydrocarbons: HDPE 33 %, FEP 100 %. Fuels, mineral oils and aliphatic hydrocarbons: HDPE 79 %, FEP 100 %. Vegetable and animal oils, fats, essential oils: HDPE 71 %, FEP 100 %. Halogenated hydrocarbons: HDPE 10 %, FEP 90 %. Foods and beverages: HDPE 100 %, FEP 100 %.Mineral acidsMineral acids, HDPE: 79 % (56)79 %Mineral acids, FEP: 100 % (55)100 %Organic acidsOrganic acids, HDPE: 95 % (58)95 %Organic acids, FEP: 100 % (64)100 %AlkalisAlkalis, HDPE: 100 % (22)100 %Alkalis, FEP: 100 % (18)100 %Salts and salt solutionsSalts and salt solutions, HDPE: 100 % (193)100 %Salts and salt solutions, FEP: 100 % (197)100 %Oxidising agents and halogensOxidising agents and halogens, HDPE: 78 % (40)78 %Oxidising agents and halogens, FEP: 100 % (52)100 %Alcohols and glycolsAlcohols and glycols, HDPE: 93 % (43)93 %Alcohols and glycols, FEP: 100 % (57)100 %PhenolsPhenols, HDPE: 62 % (8)62 %Phenols, FEP: 100 % (14)100 %Ketones and aldehydesKetones and aldehydes, HDPE: 84 % (19)84 %Ketones and aldehydes, FEP: 100 % (33)100 %Esters and ethersEsters and ethers, HDPE: 73 % (37)73 %Esters and ethers, FEP: 100 % (69)100 %Amines and nitrogen compoundsAmines and nitrogen compounds, HDPE: 90 % (21)90 %Amines and nitrogen compounds, FEP: 100 % (38)100 %Aromatic hydrocarbonsAromatic hydrocarbons, HDPE: 33 % (9)33 %Aromatic hydrocarbons, FEP: 100 % (14)100 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, HDPE: 79 % (38)79 %Fuels, mineral oils and aliphatic hydrocarbons, FEP: 100 % (74)100 %Vegetable and animal oils, fats, essential oilsVegetable and animal oils, fats, essential oils, HDPE: 71 % (21)71 %Vegetable and animal oils, fats, essential oils, FEP: 100 % (47)100 %Halogenated hydrocarbonsHalogenated hydrocarbons, HDPE: 10 % (31)10 %Halogenated hydrocarbons, FEP: 90 % (49)90 %Foods and beveragesFoods and beverages, HDPE: 100 % (32)100 %Foods and beverages, FEP: 100 % (46)100 %
HDPEFEP
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

HDPE, FEP: How often the two ratings agreeHDPE A, FEP A: 548; HDPE A, FEP B: 2; HDPE B, FEP A: 24; HDPE C, FEP A: 59; HDPE D, FEP A: 30; HDPE D, FEP B: 2; HDPE D, FEP C: 2.FEPABCDHDPEAHDPE A, FEP A: 548548HDPE A, FEP B: 22HDPE A, FEP C: 00HDPE A, FEP D: 00BHDPE B, FEP A: 2424HDPE B, FEP B: 00HDPE B, FEP C: 00HDPE B, FEP D: 00CHDPE C, FEP A: 5959HDPE C, FEP B: 00HDPE C, FEP C: 00HDPE C, FEP D: 00DHDPE D, FEP A: 3030HDPE D, FEP B: 22HDPE D, FEP C: 22HDPE D, FEP D: 00
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classHDPE: rated A or BFEP: rated A or B
Mineral acids79 % (56 rows)100 % (55 rows)
Organic acids95 % (58 rows)100 % (64 rows)
Alkalis100 % (22 rows)100 % (18 rows)
Salts and salt solutions100 % (193 rows)100 % (197 rows)
Oxidising agents and halogens78 % (40 rows)100 % (52 rows)
Alcohols and glycols93 % (43 rows)100 % (57 rows)
Phenols62 % (8 rows)100 % (14 rows)
Ketones and aldehydes84 % (19 rows)100 % (33 rows)
Esters and ethers73 % (37 rows)100 % (69 rows)
Amines and nitrogen compounds90 % (21 rows)100 % (38 rows)
Aromatic hydrocarbons33 % (9 rows)100 % (14 rows)
Fuels, mineral oils and aliphatic hydrocarbons79 % (38 rows)100 % (74 rows)
Vegetable and animal oils, fats, essential oils71 % (21 rows)100 % (47 rows)
Halogenated hydrocarbons10 % (31 rows)90 % (49 rows)
Foods and beverages100 % (32 rows)100 % (46 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 91 in total, the first 40 shown.

ChemicalConcentrationHDPEFEP
1,2-DibromoethaneDA
Acetic Anhydridetechnical gradeDA
BromineDA
Bromine VaporsDA
Bromochloromethane100 %DA
BromoformDA
Butanetriol100 %DA
Butenetechnical gradeDA
Camphor OilDA
Carbon DisulfideDA
Carbon TetrachlorideDA
Chlorine97 %DA
Chlorine GasDA
Dichloroethylenetechnical gradeDA
Dichloroisopropyl EtherDA
DichloromethaneDA
Diisooctyl Phthalate (DOP)technical gradeDA
Dimethyl Phthalate (DMP)100 %DA
Essential OilsDA
Ethyl Acrylate100 %DA
FluorineDA
Oleum (Fuming Sulfuric Acid)10 % SO3DA
Oleum Vaporslow concentrationDA
Perchloroethylene (PCE)DA
Styrene100 %DA
Sulfuric AcidfumingDA
Tetrabromoethane100 %DA
Thionyl Chloridetechnical gradeDA
Trichlorobenzene100 %DA
Vinylidene ChlorideDA
1,2-DichlorobenzeneCA
1,3-ButadieneCA
Acetaldehyde40 %CA
Acetaldehydetechnical gradeCA
Allyl Chloride100 %CA
Amyl ChlorideCA
Aqua RegiaDB
BenzeneCA
Benzyl AlcoholCA
BromobenzeneCA

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is HDPE or FEP more chemical-resistant?

Of 667 chemicals rated for both materials at 20 °C, HDPE and FEP share the same rating in 548 rows (82 %). HDPE is rated better in 2 rows and FEP in 117 rows.

How do HDPE and FEP compare for chemical resistance?

Based on 667 chemicals tested for both: HDPE is rated better with –. FEP is rated better with Halogenated hydrocarbons, Aromatic hydrocarbons, Phenols, Vegetable and animal oils, fats, essential oils. They perform similarly with Organic acids, Alkalis, Salts and salt solutions, Alcohols and glycols.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.