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PP vs ECTFE/ETFE: Chemical Resistance Compared

Of 374 source rows rated for both materials at 20 °C, 287 (77 %) have the same rating. PP is rated better in 8 rows and ECTFE/ETFE in 79. A row is one chemical at one concentration.

Summary

ECTFE/ETFE is rated better with
Halogenated hydrocarbons (+96 points); Fuels, mineral oils and aliphatic hydrocarbons (+37 points); Esters and ethers (+32 points); Ketones and aldehydes (+31 points); Mineral acids (+30 points); Oxidising agents and halogens (+28 points); Amines and nitrogen compounds (+21 points)
Within 10 points of each other
Organic acids; Alkalis; Salts and salt solutions; Alcohols and glycols; Foods and beverages

Points are the difference in the share of rows rated A or B.

The two materials

PP

Polypropylene

Polypropylene resists most acids, alkalis and salt solutions. Concentrated oxidising acids, chlorinated solvents and aromatic hydrocarbons attack it, and it turns brittle below about 0 °C.

Rated rows: 978. A 66 %, B 11 %, C 15 %, D 8 %

All chemicals for PP

ECTFE/ETFE

Ethylene chlorotrifluoroethylene / ethylene tetrafluoroethylene

ECTFE and ETFE are tough fluoropolymers with broad resistance. Hot amines and some chlorinated solvents at elevated temperature are their main limits.

Rated rows: 374. A 94 %, B 6 %, C 0 %, D 0 %

All chemicals for ECTFE/ETFE

Share of rows rated A or B, by chemical class

PP, ECTFE/ETFE: Share of rows rated A or B, by chemical classMineral acids: PP 70 %, ECTFE/ETFE 100 %. Organic acids: PP 97 %, ECTFE/ETFE 100 %. Alkalis: PP 100 %, ECTFE/ETFE 100 %. Salts and salt solutions: PP 99 %, ECTFE/ETFE 100 %. Oxidising agents and halogens: PP 72 %, ECTFE/ETFE 100 %. Alcohols and glycols: PP 93 %, ECTFE/ETFE 100 %. Ketones and aldehydes: PP 69 %, ECTFE/ETFE 100 %. Esters and ethers: PP 63 %, ECTFE/ETFE 95 %. Amines and nitrogen compounds: PP 79 %, ECTFE/ETFE 100 %. Fuels, mineral oils and aliphatic hydrocarbons: PP 63 %, ECTFE/ETFE 100 %. Halogenated hydrocarbons: PP 4 %, ECTFE/ETFE 100 %. Foods and beverages: PP 100 %, ECTFE/ETFE 100 %.Mineral acidsMineral acids, PP: 70 % (63)70 %Mineral acids, ECTFE/ETFE: 100 % (37)100 %Organic acidsOrganic acids, PP: 97 % (64)97 %Organic acids, ECTFE/ETFE: 100 % (33)100 %AlkalisAlkalis, PP: 100 % (22)100 %Alkalis, ECTFE/ETFE: 100 % (14)100 %Salts and salt solutionsSalts and salt solutions, PP: 99 % (198)99 %Salts and salt solutions, ECTFE/ETFE: 100 % (114)100 %Oxidising agents and halogensOxidising agents and halogens, PP: 72 % (61)72 %Oxidising agents and halogens, ECTFE/ETFE: 100 % (17)100 %Alcohols and glycolsAlcohols and glycols, PP: 93 % (59)93 %Alcohols and glycols, ECTFE/ETFE: 100 % (25)100 %Ketones and aldehydesKetones and aldehydes, PP: 69 % (35)69 %Ketones and aldehydes, ECTFE/ETFE: 100 % (14)100 %Esters and ethersEsters and ethers, PP: 63 % (71)63 %Esters and ethers, ECTFE/ETFE: 95 % (20)95 %Amines and nitrogen compoundsAmines and nitrogen compounds, PP: 79 % (39)79 %Amines and nitrogen compounds, ECTFE/ETFE: 100 % (9)100 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, PP: 63 % (78)63 %Fuels, mineral oils and aliphatic hydrocarbons, ECTFE/ETFE: 100 % (13)100 %Halogenated hydrocarbonsHalogenated hydrocarbons, PP: 4 % (70)4 %Halogenated hydrocarbons, ECTFE/ETFE: 100 % (16)100 %Foods and beveragesFoods and beverages, PP: 100 % (46)100 %Foods and beverages, ECTFE/ETFE: 100 % (26)100 %
PPECTFE/ETFE
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

PP, ECTFE/ETFE: How often the two ratings agreePP A, ECTFE/ETFE A: 284; PP A, ECTFE/ETFE B: 7; PP A, ECTFE/ETFE C: 1; PP B, ECTFE/ETFE A: 17; PP B, ECTFE/ETFE B: 3; PP C, ECTFE/ETFE A: 26; PP C, ECTFE/ETFE B: 7; PP D, ECTFE/ETFE A: 25; PP D, ECTFE/ETFE B: 4.ECTFE/ETFEABCDPPAPP A, ECTFE/ETFE A: 284284PP A, ECTFE/ETFE B: 77PP A, ECTFE/ETFE C: 11PP A, ECTFE/ETFE D: 00BPP B, ECTFE/ETFE A: 1717PP B, ECTFE/ETFE B: 33PP B, ECTFE/ETFE C: 00PP B, ECTFE/ETFE D: 00CPP C, ECTFE/ETFE A: 2626PP C, ECTFE/ETFE B: 77PP C, ECTFE/ETFE C: 00PP C, ECTFE/ETFE D: 00DPP D, ECTFE/ETFE A: 2525PP D, ECTFE/ETFE B: 44PP D, ECTFE/ETFE C: 00PP D, ECTFE/ETFE D: 00
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classPP: rated A or BECTFE/ETFE: rated A or B
Mineral acids70 % (63 rows)100 % (37 rows)
Organic acids97 % (64 rows)100 % (33 rows)
Alkalis100 % (22 rows)100 % (14 rows)
Salts and salt solutions99 % (198 rows)100 % (114 rows)
Oxidising agents and halogens72 % (61 rows)100 % (17 rows)
Alcohols and glycols93 % (59 rows)100 % (25 rows)
Phenols79 % (14 rows)–
Ketones and aldehydes69 % (35 rows)100 % (14 rows)
Esters and ethers63 % (71 rows)95 % (20 rows)
Amines and nitrogen compounds79 % (39 rows)100 % (9 rows)
Aromatic hydrocarbons14 % (14 rows)–
Fuels, mineral oils and aliphatic hydrocarbons63 % (78 rows)100 % (13 rows)
Vegetable and animal oils, fats, essential oils75 % (48 rows)–
Halogenated hydrocarbons4 % (70 rows)100 % (16 rows)
Foods and beverages100 % (46 rows)100 % (26 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 56 in total, the first 40 shown.

ChemicalConcentrationPPECTFE/ETFE
1,3-ButadieneDA
Amyl ChlorideDA
Aqua RegiaDA
Benzyl AlcoholDA
BromineDA
Butyric AcidDA
Carbon DisulfideDA
Carbon TetrachlorideDA
Cedar OilDA
Chlorine10 % wetDA
Chromic-Sulfuric AcidconcentratedDA
Cinnamon OilDA
Diethyl Ethertechnical gradeDA
DiethylbenzeneDA
FluorineDA
Nitric Acid66 %DA
Nitric Acid70 %DA
Perchloric Acid70 %DA
Perchloroethylene (PCE)DA
Sulfur DioxideliquidDA
Thionyl Chloridetechnical gradeDA
TrichloroethaneDA
Trichloroethylene (TCE)100 %DA
Turpentine OilDA
XyleneDA
1,2-DichlorobenzeneCA
1,4-DichlorobenzeneCA
AcetonitrileCA
AcrylonitrileCA
Amyl AcetateCA
BenzeneCA
BromobenzeneDB
BromoformDB
Butyl Acetate100 %CA
Butyl Acrylate100 %CA
Chlorine WaterCA
ChlorobenzeneCA
Chloroethane (Ethyl Chloride)CA
Chromic Acid50 %CA
CumeneCA

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is PP or ECTFE/ETFE more chemical-resistant?

Of 374 chemicals rated for both materials at 20 °C, PP and ECTFE/ETFE share the same rating in 287 rows (77 %). PP is rated better in 8 rows and ECTFE/ETFE in 79 rows.

How do PP and ECTFE/ETFE compare for chemical resistance?

Based on 374 chemicals tested for both: PP is rated better with –. ECTFE/ETFE is rated better with Halogenated hydrocarbons, Fuels, mineral oils and aliphatic hydrocarbons, Esters and ethers, Ketones and aldehydes. They perform similarly with Organic acids, Alkalis, Salts and salt solutions, Alcohols and glycols.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.