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PP vs FEP: Chemical Resistance Compared

Of 904 source rows rated for both materials at 20 °C, 621 (69 %) have the same rating. PP is rated better in 0 rows and FEP in 283. A row is one chemical at one concentration.

Summary

FEP is rated better with
Halogenated hydrocarbons (+86 points); Aromatic hydrocarbons (+86 points); Fuels, mineral oils and aliphatic hydrocarbons (+37 points); Esters and ethers (+37 points); Ketones and aldehydes (+31 points); Mineral acids (+30 points); Oxidising agents and halogens (+28 points); Vegetable and animal oils, fats, essential oils (+25 points); Phenols (+21 points); Amines and nitrogen compounds (+21 points)
Within 10 points of each other
Organic acids; Alkalis; Salts and salt solutions; Alcohols and glycols; Foods and beverages

Points are the difference in the share of rows rated A or B.

The two materials

PP

Polypropylene

Polypropylene resists most acids, alkalis and salt solutions. Concentrated oxidising acids, chlorinated solvents and aromatic hydrocarbons attack it, and it turns brittle below about 0 °C.

Rated rows: 978. A 66 %, B 11 %, C 15 %, D 8 %

All chemicals for PP

FEP

Fluorinated ethylene propylene

FEP has nearly the chemical resistance of PTFE and can be melt-processed. Its service temperature, about 200 °C, is lower than that of PTFE.

Rated rows: 908. A 99 %, B 0 %, C 1 %, D 0 %

All chemicals for FEP

Share of rows rated A or B, by chemical class

PP, FEP: Share of rows rated A or B, by chemical classMineral acids: PP 70 %, FEP 100 %. Organic acids: PP 97 %, FEP 100 %. Alkalis: PP 100 %, FEP 100 %. Salts and salt solutions: PP 99 %, FEP 100 %. Oxidising agents and halogens: PP 72 %, FEP 100 %. Alcohols and glycols: PP 93 %, FEP 100 %. Phenols: PP 79 %, FEP 100 %. Ketones and aldehydes: PP 69 %, FEP 100 %. Esters and ethers: PP 63 %, FEP 100 %. Amines and nitrogen compounds: PP 79 %, FEP 100 %. Aromatic hydrocarbons: PP 14 %, FEP 100 %. Fuels, mineral oils and aliphatic hydrocarbons: PP 63 %, FEP 100 %. Vegetable and animal oils, fats, essential oils: PP 75 %, FEP 100 %. Halogenated hydrocarbons: PP 4 %, FEP 90 %. Foods and beverages: PP 100 %, FEP 100 %.Mineral acidsMineral acids, PP: 70 % (63)70 %Mineral acids, FEP: 100 % (55)100 %Organic acidsOrganic acids, PP: 97 % (64)97 %Organic acids, FEP: 100 % (64)100 %AlkalisAlkalis, PP: 100 % (22)100 %Alkalis, FEP: 100 % (18)100 %Salts and salt solutionsSalts and salt solutions, PP: 99 % (198)99 %Salts and salt solutions, FEP: 100 % (197)100 %Oxidising agents and halogensOxidising agents and halogens, PP: 72 % (61)72 %Oxidising agents and halogens, FEP: 100 % (52)100 %Alcohols and glycolsAlcohols and glycols, PP: 93 % (59)93 %Alcohols and glycols, FEP: 100 % (57)100 %PhenolsPhenols, PP: 79 % (14)79 %Phenols, FEP: 100 % (14)100 %Ketones and aldehydesKetones and aldehydes, PP: 69 % (35)69 %Ketones and aldehydes, FEP: 100 % (33)100 %Esters and ethersEsters and ethers, PP: 63 % (71)63 %Esters and ethers, FEP: 100 % (69)100 %Amines and nitrogen compoundsAmines and nitrogen compounds, PP: 79 % (39)79 %Amines and nitrogen compounds, FEP: 100 % (38)100 %Aromatic hydrocarbonsAromatic hydrocarbons, PP: 14 % (14)14 %Aromatic hydrocarbons, FEP: 100 % (14)100 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, PP: 63 % (78)63 %Fuels, mineral oils and aliphatic hydrocarbons, FEP: 100 % (74)100 %Vegetable and animal oils, fats, essential oilsVegetable and animal oils, fats, essential oils, PP: 75 % (48)75 %Vegetable and animal oils, fats, essential oils, FEP: 100 % (47)100 %Halogenated hydrocarbonsHalogenated hydrocarbons, PP: 4 % (70)4 %Halogenated hydrocarbons, FEP: 90 % (49)90 %Foods and beveragesFoods and beverages, PP: 100 % (46)100 %Foods and beverages, FEP: 100 % (46)100 %
PPFEP
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

PP, FEP: How often the two ratings agreePP A, FEP A: 620; PP B, FEP A: 106; PP C, FEP A: 114; PP C, FEP B: 1; PP C, FEP C: 1; PP D, FEP A: 55; PP D, FEP B: 3; PP D, FEP C: 4.FEPABCDPPAPP A, FEP A: 620620PP A, FEP B: 00PP A, FEP C: 00PP A, FEP D: 00BPP B, FEP A: 106106PP B, FEP B: 00PP B, FEP C: 00PP B, FEP D: 00CPP C, FEP A: 114114PP C, FEP B: 11PP C, FEP C: 11PP C, FEP D: 00DPP D, FEP A: 5555PP D, FEP B: 33PP D, FEP C: 44PP D, FEP D: 00
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classPP: rated A or BFEP: rated A or B
Mineral acids70 % (63 rows)100 % (55 rows)
Organic acids97 % (64 rows)100 % (64 rows)
Alkalis100 % (22 rows)100 % (18 rows)
Salts and salt solutions99 % (198 rows)100 % (197 rows)
Oxidising agents and halogens72 % (61 rows)100 % (52 rows)
Alcohols and glycols93 % (59 rows)100 % (57 rows)
Phenols79 % (14 rows)100 % (14 rows)
Ketones and aldehydes69 % (35 rows)100 % (33 rows)
Esters and ethers63 % (71 rows)100 % (69 rows)
Amines and nitrogen compounds79 % (39 rows)100 % (38 rows)
Aromatic hydrocarbons14 % (14 rows)100 % (14 rows)
Fuels, mineral oils and aliphatic hydrocarbons63 % (78 rows)100 % (74 rows)
Vegetable and animal oils, fats, essential oils75 % (48 rows)100 % (47 rows)
Halogenated hydrocarbons4 % (70 rows)90 % (49 rows)
Foods and beverages100 % (46 rows)100 % (46 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 172 in total, the first 40 shown.

ChemicalConcentrationPPFEP
1,2-DibromoethaneDA
1,3-ButadieneDA
1-ChloronaphthaleneDA
Allyl Chloride100 %DA
Amyl ChlorideDA
Benzyl AlcoholDA
Benzyl Chloride100 %DA
BromineDA
Bromine VaporsDA
BromobenzeneDA
Bromochloromethane100 %DA
BromoformDA
Bromomethanetechnical gradeDA
Butenetechnical gradeDA
Butyric AcidDA
Camphor OilDA
Carbon DisulfideDA
Carbon TetrachlorideDA
Cedar OilDA
Chlorine10 % wetDA
Chlorine97 %DA
Chlorine GasDA
Chloroethanoltechnical gradeDA
Chloromethane (Methyl Chloride)technical gradeDA
Cinnamon OilDA
Dichloropropane100 %DA
Diethyl Ethertechnical gradeDA
DiethylbenzeneDA
Diisooctyl Phthalate (DOP)technical gradeDA
DimethylanilineDA
Dioctyl AdipateDA
Diphenyl EtherDA
DiphylDA
Ethyl Acrylate100 %DA
FluorineDA
FurfuralDA
Hydrogen Peroxide100 %DA
Nitric Acid66 %DA
Nitric Acid70 %DA
Oleum (Fuming Sulfuric Acid)10 % SO3DA

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is PP or FEP more chemical-resistant?

Of 904 chemicals rated for both materials at 20 °C, PP and FEP share the same rating in 621 rows (69 %). PP is rated better in 0 rows and FEP in 283 rows.

How do PP and FEP compare for chemical resistance?

Based on 904 chemicals tested for both: PP is rated better with –. FEP is rated better with Halogenated hydrocarbons, Aromatic hydrocarbons, Fuels, mineral oils and aliphatic hydrocarbons, Esters and ethers. They perform similarly with Organic acids, Alkalis, Salts and salt solutions, Alcohols and glycols.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.