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HDPE vs ECTFE/ETFE: Chemical Resistance Compared

Of 366 source rows rated for both materials at 20 °C, 292 (80 %) have the same rating. HDPE is rated better in 11 rows and ECTFE/ETFE in 63. A row is one chemical at one concentration.

Summary

ECTFE/ETFE is rated better with
Halogenated hydrocarbons (+90 points); Oxidising agents and halogens (+22 points); Esters and ethers (+22 points); Mineral acids (+21 points); Fuels, mineral oils and aliphatic hydrocarbons (+21 points); Ketones and aldehydes (+16 points)
Within 10 points of each other
Organic acids; Alkalis; Salts and salt solutions; Alcohols and glycols; Amines and nitrogen compounds; Foods and beverages

Points are the difference in the share of rows rated A or B.

The two materials

HDPE

High-density polyethylene

High-density polyethylene resists most aqueous acids, alkalis and salt solutions. Strong oxidising acids, chlorinated solvents and aromatic hydrocarbons attack or swell it. Continuous service is usually limited to about 80 °C.

Rated rows: 686. A 82 %, B 3 %, C 9 %, D 6 %

All chemicals for HDPE

ECTFE/ETFE

Ethylene chlorotrifluoroethylene / ethylene tetrafluoroethylene

ECTFE and ETFE are tough fluoropolymers with broad resistance. Hot amines and some chlorinated solvents at elevated temperature are their main limits.

Rated rows: 374. A 94 %, B 6 %, C 0 %, D 0 %

All chemicals for ECTFE/ETFE

Share of rows rated A or B, by chemical class

HDPE, ECTFE/ETFE: Share of rows rated A or B, by chemical classMineral acids: HDPE 79 %, ECTFE/ETFE 100 %. Organic acids: HDPE 95 %, ECTFE/ETFE 100 %. Alkalis: HDPE 100 %, ECTFE/ETFE 100 %. Salts and salt solutions: HDPE 100 %, ECTFE/ETFE 100 %. Oxidising agents and halogens: HDPE 78 %, ECTFE/ETFE 100 %. Alcohols and glycols: HDPE 93 %, ECTFE/ETFE 100 %. Ketones and aldehydes: HDPE 84 %, ECTFE/ETFE 100 %. Esters and ethers: HDPE 73 %, ECTFE/ETFE 95 %. Amines and nitrogen compounds: HDPE 90 %, ECTFE/ETFE 100 %. Fuels, mineral oils and aliphatic hydrocarbons: HDPE 79 %, ECTFE/ETFE 100 %. Halogenated hydrocarbons: HDPE 10 %, ECTFE/ETFE 100 %. Foods and beverages: HDPE 100 %, ECTFE/ETFE 100 %.Mineral acidsMineral acids, HDPE: 79 % (56)79 %Mineral acids, ECTFE/ETFE: 100 % (37)100 %Organic acidsOrganic acids, HDPE: 95 % (58)95 %Organic acids, ECTFE/ETFE: 100 % (33)100 %AlkalisAlkalis, HDPE: 100 % (22)100 %Alkalis, ECTFE/ETFE: 100 % (14)100 %Salts and salt solutionsSalts and salt solutions, HDPE: 100 % (193)100 %Salts and salt solutions, ECTFE/ETFE: 100 % (114)100 %Oxidising agents and halogensOxidising agents and halogens, HDPE: 78 % (40)78 %Oxidising agents and halogens, ECTFE/ETFE: 100 % (17)100 %Alcohols and glycolsAlcohols and glycols, HDPE: 93 % (43)93 %Alcohols and glycols, ECTFE/ETFE: 100 % (25)100 %Ketones and aldehydesKetones and aldehydes, HDPE: 84 % (19)84 %Ketones and aldehydes, ECTFE/ETFE: 100 % (14)100 %Esters and ethersEsters and ethers, HDPE: 73 % (37)73 %Esters and ethers, ECTFE/ETFE: 95 % (20)95 %Amines and nitrogen compoundsAmines and nitrogen compounds, HDPE: 90 % (21)90 %Amines and nitrogen compounds, ECTFE/ETFE: 100 % (9)100 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, HDPE: 79 % (38)79 %Fuels, mineral oils and aliphatic hydrocarbons, ECTFE/ETFE: 100 % (13)100 %Halogenated hydrocarbonsHalogenated hydrocarbons, HDPE: 10 % (31)10 %Halogenated hydrocarbons, ECTFE/ETFE: 100 % (16)100 %Foods and beveragesFoods and beverages, HDPE: 100 % (32)100 %Foods and beverages, ECTFE/ETFE: 100 % (26)100 %
HDPEECTFE/ETFE
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

HDPE, ECTFE/ETFE: How often the two ratings agreeHDPE A, ECTFE/ETFE A: 289; HDPE A, ECTFE/ETFE B: 10; HDPE A, ECTFE/ETFE C: 1; HDPE B, ECTFE/ETFE A: 19; HDPE B, ECTFE/ETFE B: 3; HDPE C, ECTFE/ETFE A: 28; HDPE C, ECTFE/ETFE B: 5; HDPE D, ECTFE/ETFE A: 8; HDPE D, ECTFE/ETFE B: 3.ECTFE/ETFEABCDHDPEAHDPE A, ECTFE/ETFE A: 289289HDPE A, ECTFE/ETFE B: 1010HDPE A, ECTFE/ETFE C: 11HDPE A, ECTFE/ETFE D: 00BHDPE B, ECTFE/ETFE A: 1919HDPE B, ECTFE/ETFE B: 33HDPE B, ECTFE/ETFE C: 00HDPE B, ECTFE/ETFE D: 00CHDPE C, ECTFE/ETFE A: 2828HDPE C, ECTFE/ETFE B: 55HDPE C, ECTFE/ETFE C: 00HDPE C, ECTFE/ETFE D: 00DHDPE D, ECTFE/ETFE A: 88HDPE D, ECTFE/ETFE B: 33HDPE D, ECTFE/ETFE C: 00HDPE D, ECTFE/ETFE D: 00
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classHDPE: rated A or BECTFE/ETFE: rated A or B
Mineral acids79 % (56 rows)100 % (37 rows)
Organic acids95 % (58 rows)100 % (33 rows)
Alkalis100 % (22 rows)100 % (14 rows)
Salts and salt solutions100 % (193 rows)100 % (114 rows)
Oxidising agents and halogens78 % (40 rows)100 % (17 rows)
Alcohols and glycols93 % (43 rows)100 % (25 rows)
Phenols62 % (8 rows)–
Ketones and aldehydes84 % (19 rows)100 % (14 rows)
Esters and ethers73 % (37 rows)95 % (20 rows)
Amines and nitrogen compounds90 % (21 rows)100 % (9 rows)
Aromatic hydrocarbons33 % (9 rows)–
Fuels, mineral oils and aliphatic hydrocarbons79 % (38 rows)100 % (13 rows)
Vegetable and animal oils, fats, essential oils71 % (21 rows)–
Halogenated hydrocarbons10 % (31 rows)100 % (16 rows)
Foods and beverages100 % (32 rows)100 % (26 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 40 in total.

ChemicalConcentrationHDPEECTFE/ETFE
Aqua RegiaDA
BromineDA
Carbon DisulfideDA
Carbon TetrachlorideDA
Chromic-Sulfuric AcidconcentratedDA
FluorineDA
Perchloroethylene (PCE)DA
Thionyl Chloridetechnical gradeDA
1,2-DichlorobenzeneCA
1,3-ButadieneCA
Amyl ChlorideCA
BenzeneCA
Benzyl AlcoholCA
BromoformDB
Butyric AcidCA
Cedar OilCA
Chlorine10 % wetCA
Chlorine WaterCA
ChlorobenzeneCA
Chloroethane (Ethyl Chloride)CA
Chromic Acid50 %CA
Cinnamon OilCA
CresolCA
CyclohexaneCA
DichloromethaneDB
Diethyl Ethertechnical gradeCA
DiethylbenzeneCA
Ethylene DichlorideCA
Heating OilCA
NitrobenzeneCA
OzoneCA
PropanegaseousCA
Propylene OxideAC
Sulfur DioxideliquidCA
Sulfuric Acid95 %CA
TolueneCA
TrichloroethaneCA
Trichloroethylene (TCE)100 %CA
Vinylidene ChlorideDB
XyleneCA

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is HDPE or ECTFE/ETFE more chemical-resistant?

Of 366 chemicals rated for both materials at 20 °C, HDPE and ECTFE/ETFE share the same rating in 292 rows (80 %). HDPE is rated better in 11 rows and ECTFE/ETFE in 63 rows.

How do HDPE and ECTFE/ETFE compare for chemical resistance?

Based on 366 chemicals tested for both: HDPE is rated better with –. ECTFE/ETFE is rated better with Halogenated hydrocarbons, Oxidising agents and halogens, Esters and ethers, Mineral acids. They perform similarly with Organic acids, Alkalis, Salts and salt solutions, Alcohols and glycols.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.