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HDPE vs SAN: Chemical Resistance Compared

Of 290 source rows rated for both materials at 20 °C, 206 (71 %) have the same rating. HDPE is rated better in 65 rows and SAN in 19. A row is one chemical at one concentration.

Summary

HDPE is rated better with
Esters and ethers (+73 points); Ketones and aldehydes (+63 points); Phenols (+37 points); Amines and nitrogen compounds (+34 points); Alcohols and glycols (+23 points); Mineral acids (+18 points); Foods and beverages (+18 points); Organic acids (+16 points)
Within 10 points of each other
Alkalis; Salts and salt solutions; Oxidising agents and halogens; Fuels, mineral oils and aliphatic hydrocarbons; Vegetable and animal oils, fats, essential oils; Halogenated hydrocarbons

Points are the difference in the share of rows rated A or B.

The two materials

HDPE

High-density polyethylene

High-density polyethylene resists most aqueous acids, alkalis and salt solutions. Strong oxidising acids, chlorinated solvents and aromatic hydrocarbons attack or swell it. Continuous service is usually limited to about 80 °C.

Rated rows: 686. A 82 %, B 3 %, C 9 %, D 6 %

All chemicals for HDPE

SAN

Styrene-acrylonitrile

Styrene-acrylonitrile resists oils and dilute acids better than polystyrene, but ketones, esters and aromatic and chlorinated solvents still attack it.

Rated rows: 364. A 67 %, B 0 %, C 9 %, D 24 %

All chemicals for SAN

Share of rows rated A or B, by chemical class

HDPE, SAN: Share of rows rated A or B, by chemical classMineral acids: HDPE 79 %, SAN 61 %. Organic acids: HDPE 95 %, SAN 79 %. Alkalis: HDPE 100 %, SAN 100 %. Salts and salt solutions: HDPE 100 %, SAN 100 %. Oxidising agents and halogens: HDPE 78 %, SAN 73 %. Alcohols and glycols: HDPE 93 %, SAN 70 %. Phenols: HDPE 62 %, SAN 25 %. Ketones and aldehydes: HDPE 84 %, SAN 21 %. Esters and ethers: HDPE 73 %, SAN 0 %. Amines and nitrogen compounds: HDPE 90 %, SAN 56 %. Fuels, mineral oils and aliphatic hydrocarbons: HDPE 79 %, SAN 79 %. Vegetable and animal oils, fats, essential oils: HDPE 71 %, SAN 68 %. Halogenated hydrocarbons: HDPE 10 %, SAN 5 %. Foods and beverages: HDPE 100 %, SAN 82 %.Mineral acidsMineral acids, HDPE: 79 % (56)79 %Mineral acids, SAN: 61 % (18)61 %Organic acidsOrganic acids, HDPE: 95 % (58)95 %Organic acids, SAN: 79 % (24)79 %AlkalisAlkalis, HDPE: 100 % (22)100 %Alkalis, SAN: 100 % (8)100 %Salts and salt solutionsSalts and salt solutions, HDPE: 100 % (193)100 %Salts and salt solutions, SAN: 100 % (80)100 %Oxidising agents and halogensOxidising agents and halogens, HDPE: 78 % (40)78 %Oxidising agents and halogens, SAN: 73 % (26)73 %Alcohols and glycolsAlcohols and glycols, HDPE: 93 % (43)93 %Alcohols and glycols, SAN: 70 % (33)70 %PhenolsPhenols, HDPE: 62 % (8)62 %Phenols, SAN: 25 % (8)25 %Ketones and aldehydesKetones and aldehydes, HDPE: 84 % (19)84 %Ketones and aldehydes, SAN: 21 % (19)21 %Esters and ethersEsters and ethers, HDPE: 73 % (37)73 %Esters and ethers, SAN: 0 % (19)0 %Amines and nitrogen compoundsAmines and nitrogen compounds, HDPE: 90 % (21)90 %Amines and nitrogen compounds, SAN: 56 % (9)56 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, HDPE: 79 % (38)79 %Fuels, mineral oils and aliphatic hydrocarbons, SAN: 79 % (24)79 %Vegetable and animal oils, fats, essential oilsVegetable and animal oils, fats, essential oils, HDPE: 71 % (21)71 %Vegetable and animal oils, fats, essential oils, SAN: 68 % (22)68 %Halogenated hydrocarbonsHalogenated hydrocarbons, HDPE: 10 % (31)10 %Halogenated hydrocarbons, SAN: 5 % (20)5 %Foods and beveragesFoods and beverages, HDPE: 100 % (32)100 %Foods and beverages, SAN: 82 % (22)82 %
HDPESAN
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

HDPE, SAN: How often the two ratings agreeHDPE A, SAN A: 189; HDPE A, SAN B: 1; HDPE A, SAN C: 17; HDPE A, SAN D: 20; HDPE B, SAN A: 6; HDPE B, SAN C: 1; HDPE B, SAN D: 6; HDPE C, SAN A: 8; HDPE C, SAN C: 3; HDPE C, SAN D: 20; HDPE D, SAN C: 5; HDPE D, SAN D: 14.SANABCDHDPEAHDPE A, SAN A: 189189HDPE A, SAN B: 11HDPE A, SAN C: 1717HDPE A, SAN D: 2020BHDPE B, SAN A: 66HDPE B, SAN B: 00HDPE B, SAN C: 11HDPE B, SAN D: 66CHDPE C, SAN A: 88HDPE C, SAN B: 00HDPE C, SAN C: 33HDPE C, SAN D: 2020DHDPE D, SAN A: 00HDPE D, SAN B: 00HDPE D, SAN C: 55HDPE D, SAN D: 1414
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classHDPE: rated A or BSAN: rated A or B
Mineral acids79 % (56 rows)61 % (18 rows)
Organic acids95 % (58 rows)79 % (24 rows)
Alkalis100 % (22 rows)100 % (8 rows)
Salts and salt solutions100 % (193 rows)100 % (80 rows)
Oxidising agents and halogens78 % (40 rows)73 % (26 rows)
Alcohols and glycols93 % (43 rows)70 % (33 rows)
Phenols62 % (8 rows)25 % (8 rows)
Ketones and aldehydes84 % (19 rows)21 % (19 rows)
Esters and ethers73 % (37 rows)0 % (19 rows)
Amines and nitrogen compounds90 % (21 rows)56 % (9 rows)
Aromatic hydrocarbons33 % (9 rows)–
Fuels, mineral oils and aliphatic hydrocarbons79 % (38 rows)79 % (24 rows)
Vegetable and animal oils, fats, essential oils71 % (21 rows)68 % (22 rows)
Halogenated hydrocarbons10 % (31 rows)5 % (20 rows)
Foods and beverages100 % (32 rows)82 % (22 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 51 in total, the first 40 shown.

ChemicalConcentrationHDPESAN
Acetic Acid90 %AD
AcetoneAD
Allyl Alcohol96 %AD
Amyl AcetateAD
Benzyl AcetateAD
Brake FluidAD
Butyl Acrylate100 %AD
CarbazoleAD
Cyclohexanonetechnical gradeAD
Dibutyl Sebacatetechnical gradeAD
Dimethylformamide (DMF)AD
Ethyl Acetate100 %AD
FurfuralAD
Methyl Isobutyl Ketone (MIBK)AD
Methyl Acetatetechnical gradeAD
Methyl Ethyl Ketone (MEK)AD
Methyl Propyl Ketone (2-Pentanone)AD
Propylene OxideAD
PyridineAD
Tricresyl Phosphate (TCP)technical gradeAD
Acetylene100 %AC
Butyl Acetate100 %BD
CamphorCA
Chloroacetic AcidAC
Chloroacetic Acid50 %AC
CyclohexaneCA
DecahydronaphthaleneAC
Diethyl KetoneBD
DioxaneBD
Ethyl BenzoateBD
EthylbenzeneBD
Formic Acid98-100 %AC
Furfuryl Alcoholtechnical gradeAC
Heating OilCA
Hydrofluoric Acid50 %AC
Iodine TinctureAC
IsobutanolAC
Lanolintechnical gradeCA
MethanolAC
MethylcyclohexaneCA

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is HDPE or SAN more chemical-resistant?

Of 290 chemicals rated for both materials at 20 °C, HDPE and SAN share the same rating in 206 rows (71 %). HDPE is rated better in 65 rows and SAN in 19 rows.

How do HDPE and SAN compare for chemical resistance?

Based on 290 chemicals tested for both: HDPE is rated better with Esters and ethers, Ketones and aldehydes, Phenols, Amines and nitrogen compounds. SAN is rated better with –. They perform similarly with Alkalis, Salts and salt solutions, Oxidising agents and halogens, Fuels, mineral oils and aliphatic hydrocarbons.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.