ChemicalResistance
ChemicalResistance.org

HDPE vs Polystyrene: Chemical Resistance Compared

Of 415 source rows rated for both materials at 20 °C, 230 (55 %) have the same rating. HDPE is rated better in 176 rows and Polystyrene in 9. A row is one chemical at one concentration.

Summary

HDPE is rated better with
Ketones and aldehydes (+79 points); Esters and ethers (+70 points); Fuels, mineral oils and aliphatic hydrocarbons (+55 points); Amines and nitrogen compounds (+43 points); Phenols (+40 points); Aromatic hydrocarbons (+33 points); Foods and beverages (+31 points); Alcohols and glycols (+29 points); Mineral acids (+28 points); Vegetable and animal oils, fats, essential oils (+23 points); Organic acids (+21 points)
Within 10 points of each other
Alkalis; Salts and salt solutions; Oxidising agents and halogens; Halogenated hydrocarbons

Points are the difference in the share of rows rated A or B.

The two materials

HDPE

High-density polyethylene

High-density polyethylene resists most aqueous acids, alkalis and salt solutions. Strong oxidising acids, chlorinated solvents and aromatic hydrocarbons attack or swell it. Continuous service is usually limited to about 80 °C.

Rated rows: 686. A 82 %, B 3 %, C 9 %, D 6 %

All chemicals for HDPE

Polystyrene

Polystyrene

Polystyrene is attacked by most organic solvents, including ketones, esters, aromatic and chlorinated hydrocarbons. It is used for dilute aqueous solutions.

Rated rows: 504. A 45 %, B 8 %, C 8 %, D 39 %

All chemicals for Polystyrene

Share of rows rated A or B, by chemical class

HDPE, Polystyrene: Share of rows rated A or B, by chemical classMineral acids: HDPE 79 %, Polystyrene 51 %. Organic acids: HDPE 95 %, Polystyrene 74 %. Alkalis: HDPE 100 %, Polystyrene 100 %. Salts and salt solutions: HDPE 100 %, Polystyrene 100 %. Oxidising agents and halogens: HDPE 78 %, Polystyrene 71 %. Alcohols and glycols: HDPE 93 %, Polystyrene 64 %. Phenols: HDPE 62 %, Polystyrene 22 %. Ketones and aldehydes: HDPE 84 %, Polystyrene 5 %. Esters and ethers: HDPE 73 %, Polystyrene 3 %. Amines and nitrogen compounds: HDPE 90 %, Polystyrene 47 %. Aromatic hydrocarbons: HDPE 33 %, Polystyrene 0 %. Fuels, mineral oils and aliphatic hydrocarbons: HDPE 79 %, Polystyrene 24 %. Vegetable and animal oils, fats, essential oils: HDPE 71 %, Polystyrene 48 %. Halogenated hydrocarbons: HDPE 10 %, Polystyrene 0 %. Foods and beverages: HDPE 100 %, Polystyrene 69 %.Mineral acidsMineral acids, HDPE: 79 % (56)79 %Mineral acids, Polystyrene: 51 % (41)51 %Organic acidsOrganic acids, HDPE: 95 % (58)95 %Organic acids, Polystyrene: 74 % (34)74 %AlkalisAlkalis, HDPE: 100 % (22)100 %Alkalis, Polystyrene: 100 % (17)100 %Salts and salt solutionsSalts and salt solutions, HDPE: 100 % (193)100 %Salts and salt solutions, Polystyrene: 100 % (88)100 %Oxidising agents and halogensOxidising agents and halogens, HDPE: 78 % (40)78 %Oxidising agents and halogens, Polystyrene: 71 % (34)71 %Alcohols and glycolsAlcohols and glycols, HDPE: 93 % (43)93 %Alcohols and glycols, Polystyrene: 64 % (36)64 %PhenolsPhenols, HDPE: 62 % (8)62 %Phenols, Polystyrene: 22 % (9)22 %Ketones and aldehydesKetones and aldehydes, HDPE: 84 % (19)84 %Ketones and aldehydes, Polystyrene: 5 % (21)5 %Esters and ethersEsters and ethers, HDPE: 73 % (37)73 %Esters and ethers, Polystyrene: 3 % (38)3 %Amines and nitrogen compoundsAmines and nitrogen compounds, HDPE: 90 % (21)90 %Amines and nitrogen compounds, Polystyrene: 47 % (15)47 %Aromatic hydrocarbonsAromatic hydrocarbons, HDPE: 33 % (9)33 %Aromatic hydrocarbons, Polystyrene: 0 % (13)0 %Fuels, mineral oils and aliphatic hydrocarbonsFuels, mineral oils and aliphatic hydrocarbons, HDPE: 79 % (38)79 %Fuels, mineral oils and aliphatic hydrocarbons, Polystyrene: 24 % (38)24 %Vegetable and animal oils, fats, essential oilsVegetable and animal oils, fats, essential oils, HDPE: 71 % (21)71 %Vegetable and animal oils, fats, essential oils, Polystyrene: 48 % (27)48 %Halogenated hydrocarbonsHalogenated hydrocarbons, HDPE: 10 % (31)10 %Halogenated hydrocarbons, Polystyrene: 0 % (36)0 %Foods and beveragesFoods and beverages, HDPE: 100 % (32)100 %Foods and beverages, Polystyrene: 69 % (32)69 %
HDPEPolystyrene
Rating at 20 °C. Only classes with at least 8 rated rows for both materials are shown.

How often the two ratings agree

HDPE, Polystyrene: How often the two ratings agreeHDPE A, Polystyrene A: 198; HDPE A, Polystyrene B: 36; HDPE A, Polystyrene C: 28; HDPE A, Polystyrene D: 55; HDPE B, Polystyrene A: 4; HDPE B, Polystyrene B: 1; HDPE B, Polystyrene D: 19; HDPE C, Polystyrene A: 4; HDPE C, Polystyrene B: 1; HDPE C, Polystyrene C: 3; HDPE C, Polystyrene D: 38; HDPE D, Polystyrene D: 28.PolystyreneABCDHDPEAHDPE A, Polystyrene A: 198198HDPE A, Polystyrene B: 3636HDPE A, Polystyrene C: 2828HDPE A, Polystyrene D: 5555BHDPE B, Polystyrene A: 44HDPE B, Polystyrene B: 11HDPE B, Polystyrene C: 00HDPE B, Polystyrene D: 1919CHDPE C, Polystyrene A: 44HDPE C, Polystyrene B: 11HDPE C, Polystyrene C: 33HDPE C, Polystyrene D: 3838DHDPE D, Polystyrene A: 00HDPE D, Polystyrene B: 00HDPE D, Polystyrene C: 00HDPE D, Polystyrene D: 2828
Number of source rows for each pair of ratings at 20 °C. Outlined cells are rows where both materials have the same rating.

Chemical classes were assigned by this site, not by the source. Mixtures and trade products without a clear class are not counted.

By chemical class

Chemical classHDPE: rated A or BPolystyrene: rated A or B
Mineral acids79 % (56 rows)51 % (41 rows)
Organic acids95 % (58 rows)74 % (34 rows)
Alkalis100 % (22 rows)100 % (17 rows)
Salts and salt solutions100 % (193 rows)100 % (88 rows)
Oxidising agents and halogens78 % (40 rows)71 % (34 rows)
Alcohols and glycols93 % (43 rows)64 % (36 rows)
Phenols62 % (8 rows)22 % (9 rows)
Ketones and aldehydes84 % (19 rows)5 % (21 rows)
Esters and ethers73 % (37 rows)3 % (38 rows)
Amines and nitrogen compounds90 % (21 rows)47 % (15 rows)
Aromatic hydrocarbons33 % (9 rows)0 % (13 rows)
Fuels, mineral oils and aliphatic hydrocarbons79 % (38 rows)24 % (38 rows)
Vegetable and animal oils, fats, essential oils71 % (21 rows)48 % (27 rows)
Halogenated hydrocarbons10 % (31 rows)0 % (36 rows)
Foods and beverages100 % (32 rows)69 % (32 rows)

Where the ratings differ most

Rows where the two ratings at 20 °C are at least two grades apart: 106 in total, the first 40 shown.

ChemicalConcentrationHDPEPolystyrene
Acetic Acid90 %AD
AcetoneAD
AcetonitrileAD
AcrylonitrileAD
Amyl AcetateAD
AnilineAD
Anisole100 %AD
BenzaldehydeAD
Benzyl AcetateAD
Bitter Almond OilAD
Butanetechnical gradeAD
Butyl Acrylate100 %AD
Cyclohexanonetechnical gradeAD
DecahydronaphthaleneAD
Dibutyl Phthalate (DBP)AD
Dibutyl Sebacatetechnical gradeAD
Diethyl MalonateAD
Diethylene Glycol EtherAD
Dimethylformamide (DMF)AD
Ethyl Acetate100 %AD
Ethyl Chloroacetatetechnical gradeAD
Ethylene Glycol Monoethyl Ether AcetateAD
Formaldehyde Solution30 %AD
Formaldehyde Solution40 %AD
Hydrobromic Acid40 %AD
Hydrobromic Acid50 %AD
Hydrobromic AciddiluteAD
Hydrofluoric Acid50 %AD
Hydrogen Peroxide100 %AD
Methyl Isobutyl Ketone (MIBK)AD
Isopropyl AcetateAD
MentholsolidAD
Methoxyethyl OleateAD
Methyl Acetatetechnical gradeAD
Methyl Chloroacetatetechnical gradeAD
Methyl Ethyl Ketone (MEK)AD
Methyl Glycol100 %AD
Methyl Propyl Ketone (2-Pentanone)AD
Nitrotoluenetechnical gradeAD
n-OctaneAD

Rating scale

A rating marked * is an estimate in the source, not a test result. An estimate is given as one value without a temperature.

More comparisons

Frequently Asked Questions

Is HDPE or Polystyrene more chemical-resistant?

Of 415 chemicals rated for both materials at 20 °C, HDPE and Polystyrene share the same rating in 230 rows (55 %). HDPE is rated better in 176 rows and Polystyrene in 9 rows.

How do HDPE and Polystyrene compare for chemical resistance?

Based on 415 chemicals tested for both: HDPE is rated better with Ketones and aldehydes, Esters and ethers, Fuels, mineral oils and aliphatic hydrocarbons, Amines and nitrogen compounds. Polystyrene is rated better with –. They perform similarly with Alkalis, Salts and salt solutions, Oxidising agents and halogens, Halogenated hydrocarbons.

About this data

The ratings come from the chemical resistance list published by Bürkle GmbH, which compiled them from raw-material manufacturers’ data. They describe laboratory tests on the raw material at 20 °C and 50 °C.

A finished part also sees pressure, mechanical stress, welds and mixtures that a laboratory test does not. Treat the rating as a first filter and test under your own conditions before relying on it.